Partial oxidation reactor with warm-up burner for production of synthesis gas

Patent metadata

Field	Value
Publication number	US-12459812-B2
Application number	US-202217975050-A
Country	US
Kind code	B2
Filing date	Oct 27, 2022
Priority date	Oct 27, 2021
Publication date	Nov 4, 2025
Grant date	Nov 4, 2025

Abstract

The invention relates to a partial oxidation reactor (POX reactor) having a warm-up burner for producing synthesis gas by partial oxidation of fluid carbon-containing fuels in the presence of an oxygen-containing oxidant and to a process for startup of the partial oxidation reactor According to the invention the preheating of the partial oxidation reactor is carried out via a dedicated warm-up burner which is introduced via one of the media channels of the POX burner without any need to deinstall the entire POX burner.

First claim

What is claimed is:

1 . A partial oxidation reactor having a warm-up burner for producing synthesis gas by partial oxidation of fluid carbon-containing fuels in the presence of an oxygen-containing oxidant, comprising:
(a) a partial oxidation burner, (b) a reactor vessel gastightly connectable to the partial oxidation burner, (c) a warm-up burner gastightly connectable to the partial oxidation burner,
wherein the partial oxidation burner comprises:
(a1) conduits for separately supplying a fluid carbon-containing fuel, the oxygen-containing oxidant and a moderator,
(a2) a central first feed channel which has a circular cross section,
(a3) a second feed channel coaxially and concentrically surrounding the first feed channel, wherein an annular gap is formed between the outer wall of the first feed channel and the inner wall of the second feed channel, and
(a4) at least one further feed channel coaxially and concentrically surrounding the first feed channel, wherein an annular gap is formed between the outer wall of the second feed channel and the inner wall of the further feed channel,
(a5) wherein the outer wall of the outermost feed channel forms the burner outer wall of the partial oxidation burner,
(a6) a first detachable connecting device for gastightly connecting the partial oxidation burner to the reactor vessel,

wherein the warm-up burner comprises:
(c1) conduits for separately supplying the carbon-containing fuel or a further fuel gas and the oxygen-containing oxidant,
(c2) a burner outer wall of the warm-up burner having a second detachable connecting device for gastightly connecting the warm-up burner to a feed channel of the partial oxidation burner, and
(c3) an ignition apparatus,

wherein the first detachable connecting device and the second detachable connecting device are configured as flanges which each comprise at least one sealing element and a multiplicity of detachable securing elements, wherein:
the at least one sealing element of the second detachable connecting device is smaller than the at least one sealing element of the first detachable connecting device, and
the multiplicity of detachable connecting elements for the second detachable connecting device is smaller than the multiplicity of connecting elements for the first detachable connecting device.

2 . The partial oxidation reactor according to claim 1 wherein the warm-up burner comprises an electrical ignition apparatus.

3 . The partial oxidation reactor according to claim 1 , wherein the warm-up burner comprises a flame detector.

4 . The partial oxidation reactor according to claim 1 , wherein the reactor vessel comprises a temperature measuring apparatus for determining the internal temperature of the reactor vessel.

5 . The partial oxidation reactor according to claim 1 , wherein at least one of the feed channels of the partial oxidation burner is provided with a turbulizing means.

6 . The partial oxidation reactor according to claim 1 , wherein at least two of the feed channels are provided with turbulizing means, wherein the directions of rotation with which the media flowing through the at least two feed channels are endowed are opposed relative to the longitudinal axis of the burner.

7 . The partial oxidation reactor according to claim 1 , wherein the feed channels of the partial oxidation burner are configured such that a mixing of the fuel, the moderator and the oxidant occurs only outside the burner.

8 . The partial oxidation reactor according to claim 1 , wherein the reactor vessel is provided with a refractory liner or lining.

9 . The partial oxidation reactor according to claim 1 , wherein the partial oxidation burner is operated without separately supplied cooling media.

10 . A process for startup of a partial oxidation reactor for producing synthesis gas by partial oxidation of fluid carbon-containing fuels in the presence of an oxygen-containing oxidant, comprising:
(a) providing a partial oxidation reactor according to claim 1 , b) providing a carbon-containing fuel in fluid form, the oxygen containing oxidant, a moderator and a further fuel gas, (c) gastightly connecting the partial oxidation burner with the reactor vessel by means of the first detachable connecting device, (d) introducing the warm-up burner into a feed channel of the partial oxidation burner and gastightly connecting the partial oxidation burner to the warm-up burner by means of the second detachable connecting device, (e) sealing the conduits of the partial oxidation burner for separately supplying the carbon-containing fuel, the oxygen-containing oxidant and the moderator, (f) supplying the carbon-containing fuel or the further fuel gas and the oxygen-containing oxidant to the warm-up burner, mixing these gases and igniting the gas mixture using the ignition apparatus, (g) repeated or continuous measurement of the internal temperature of the reactor vessel using the temperature measuring apparatus, (h) terminating the supply of the carbon-containing fuel or the further fuel gas and the oxygen-containing oxidant to the warm-up burner when a specified first target internal temperature of the reactor vessel is achieved, (i) detaching the second detachable connecting device, removing the warm-up burner and sealing the resulting opening using a closure device, (j) opening the conduits of the partial oxidation burner for separately supplying the carbon-containing fuel, the oxygen-containing oxidant and the moderator, introducing these media into the partial oxidation reactor and reacting the carbon-containing fuels with the oxygen-containing oxidant under warm-up conditions until a specified second target internal temperature of the reactor vessel has been achieved, and (k) reacting the carbon-containing fuel with the oxygen-containing oxidant under conditions of partial oxidation and discharging a raw synthesis gas from the partial oxidation reactor and optionally passing the raw synthesis gas to further conditioning or processing steps.

11 . The process according to claim 10 , wherein,
the first target internal temperature of the reactor vessel is specified to a temperature between 600° C. and 1000° C., the second target internal temperature of the reactor vessel is specified to a temperature between 800° C. and 1300° C.

Assignees

• Air Liquide

Inventors

• Lehmann Maik
• Roesch Alexander

Classifications

• F23D2207/00

  Ignition devices associated with burner · CPC title

• F23D14/66

  Preheating the combustion air or gas · CPC title

• F23D14/22

  with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other · CPC title

• F23C5/02

  Structural details of mounting · CPC title

• C10J2300/1846

  Partial oxidation, i.e. injection of air or oxygen only · CPC title