Sensitive conjugated polymer structure color and sensor using same

Patent metadata

Field	Value
Publication number	US-12454601-B2
Application number	US-202218060009-A
Country	US
Kind code	B2
Filing date	Nov 30, 2022
Priority date	Jul 16, 2020
Publication date	Oct 28, 2025
Grant date	Oct 28, 2025

Abstract

The present disclosure relates to a responsive polymer film, a method of preparing the responsive polymer film, and a sensor using the polymer film.

First claim

We claim:

1. A chemically responsive polymer film, comprising:
at least one of a polaronic conjugated homopolymer including a monomer represented by the following Chemical Formula 1 and a polaronic conjugated block copolymer including the monomer represented by the following Chemical Formula 1 and a monomer represented by the following Chemical Formula 2:

wherein in the above Chemical Formula 1,
R 1 is a linear or branched alkyl group having 1 to 8 carbon atoms,
wherein the chemically responsive polymer film is configured to exhibit different structural colors depending on a redox state and/or a thickness, and
wherein the chemically responsive polymer film is configured to exhibit a change in structural color depending on a standard reduction potential, basicity, vapor pressure of a reducing gas, a reducing solution, an oxidizing gas, an oxidizing solution, or surface properties of a substrate.

2. The chemically responsive polymer film of claim 1 ,
wherein R 1 is selected from the group consisting of a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group and all possible isomers thereof.

3. The chemically responsive polymer film of claim 1 , further comprising:
metal nanoparticles uniformly embedded within the chemically responsive polymer film.

4. The chemically responsive polymer film of claim 1 ,
wherein a thickness of the chemically responsive polymer film is 20 nm to 400 nm.

5. A method of preparing a chemically responsive polymer film, comprising:
obtaining a chemically responsive polymer film including at least one of a polaronic conjugated homopolymer including a monomer represented by the following Chemical Formula 1 and a polaronic conjugated block copolymer including the monomer represented by the following Chemical Formula 1 and a monomer represented by the following Chemical Formula 2:

wherein in the above Chemical Formula 1,
R 1 is a linear or branched alkyl group having 1 to 8 carbon atoms,
wherein the chemically responsive polymer film exhibits different structural colors depending on a redox state and/or a thickness, and
wherein the chemically responsive polymer film exhibits a change in structural color depending on a standard reduction potential, basicity, vapor pressure of a reducing gas, a reducing solution, an oxidizing gas, an oxidizing solution, or surface properties of a substrate..

6. The method of claim 5 ,
wherein the method of preparing a chemically responsive film polymer film includes spin-coating or liquid-liquid interfacial self-assembly.

7. The method of claim 6 ,
wherein when the chemically responsive polymer film is prepared by the liquid-liquid interfacial self-assembly,
wherein the chemically responsive polymer film is prepared at the interface between a reactive solution including at least one of the homopolymer and the block copolymer and an aqueous solution including at least one metal ion(s) selected from the group consisting of gold, silver, iron, copper, nickel, and manganese.

8. The method of claim 7 ,
wherein the reactive solution is prepared by dissolving at least one of the homopolymer and the block copolymer in an organic solvent, and
wherein the organic solvent is at least one selected from the group consisting of toluene, dichlorobenzene, tetrahydrofuran, and chloroform.

9. The method of claim 7 ,
wherein the chemically responsive polymer film is in-situ oxidized by the metal ions included in the aqueous solution.

10. A sensor, comprising a chemically responsive polymer film of claim 1 .

11. The sensor of claim 10 ,
wherein the sensor is that the responsive polymer film is transferred onto a substrate.

12. The sensor of claim 10 ,
wherein the sensor is used in an artificial olfactory system.

Assignees

• Univ Ewha Ind Collaboration

Inventors

• Park So-Jung
• Hyun Jerome Kartham
• Park Ji-Eun
• Moon Cheon Woo

Classifications

• G01N33/0001 Primary

  by organoleptic means · CPC title

• G01N21/783

  for analysing gases · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C08K2003/0831

  Gold · CPC title

• C08K3/08

  Metals · CPC title