Ionically conductive glass preform

Patent metadata

Field	Value
Publication number	US-12454478-B2
Application number	US-202318463206-A
Country	US
Kind code	B2
Filing date	Sep 7, 2023
Priority date	Sep 9, 2022
Publication date	Oct 28, 2025
Grant date	Oct 28, 2025

Abstract

An ionically conductive glass (or glassy) monolithic preform having a certain shape, size, and dimension may be made from a monolithic precursor material (e.g., an ingot or boule of ion conductive glass), generally of a different shape and size.

First claim

What is claimed is:

1. A method of making an ionically conductive glass preform, the method comprising:
a. providing an inorganic ion conductive glass monolith as a precursor material, the glass precursor monolith having a precursor shape, size, dimension, glass transition temperature (Tg), and glass melting temperature (T m );
b. providing a collapsible hollow structure having a wall with an inner and outer surface;
c. disposing the glass precursor monolith inside the collapsible hollow structure; and
d. pressing and heating the glass precursor monolith while it is inside the collapsible hollow structure, wherein the temperature of the glass precursor monolith during pressing is at or above the precursor Tg, wherein the pressing and heating operation uniformly collapses the hollow structure and thereby transforms the glass precursor monolith into a monolithic glass preform having a preform shape and dimension different than that of the glass precursor monolith;
wherein an inner liner material is disposed inside the collapsible hollow structure and thereby serves as an interlayer between the glass precursor monolith and the inner wall surface of the collapsible hollow structure.

2. The method of claim 1 wherein the glass precursor monolith is a glass boule.

3. The method of claim 2 wherein the glass boule has a cylindrical shape, with a substantially round cross section and further wherein the preform shape of the monolithic glass preform has a substantially rectangular cross section.

4. The method of claim 3 wherein the collapsible hollow structure is in the form of a tube having a substantially circular cross section, with a cross-sectional diameter sufficient to accommodate the glass boule.

5. The method of claim 4 wherein the collapsible hollow structure is a flattenable tube.

6. The method of claims 1 or 5 wherein the collapsible hollow structure is an organic polymeric material.

7. The method of claim 6 wherein the organic polymeric material is a fluorinated polymer.

8. The method of claim 6 where the organic polymeric material is a not a fluorinated polymer and chemically incompatible with the glass precursor monolith at or near the precursor Tg.

9. The method of claim 6 wherein the inner liner is a fluorinated polymeric material.

10. The method of claim 6 wherein the wall of the collapsible hollow structure has a thickness that is selected to maintain a hollow shape at room temperature sufficient to accommodate the glass precursor monolith and to allow the collapsible hollow structure to uniformly collapse to the preform shape of the monolithic glass preform when heated to a temperature above the precursor Tg.

Assignees

• Polyplus Battery Co Inc

Inventors

• Visco Steven J
• Nimon Vitaliy
• Petrov Alexei
• Nimon Yevgeniy S
• Katz Bruce D

Classifications

• H01M4/628

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title

• H01M2300/0071

  Oxides · CPC title

• H01M10/0562

  Solid materials · CPC title

• C03B13/04

  Rolling non-patterned sheets continuously · CPC title