Particle processing

Patent metadata

Field	Value
Publication number	US-12453948-B2
Application number	US-202118248609-A
Country	US
Kind code	B2
Filing date	Oct 11, 2021
Priority date	Oct 13, 2020
Publication date	Oct 28, 2025
Grant date	Oct 28, 2025

Abstract

A method of operating a gas-solid fluidized bed ( 130 ) includes-flowing a pulsating gas flow upwards through a bed of solid particles from a distributor ( 104 ) to cause a dynamically structured bubble flow ( 130 ), and processing particles using the fluidized bed.

First claim

What is claimed is:

1. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
wherein processing particles using the fluidized bed comprises setting up a compartmentalized flow regime, in which a plurality of mixing compartments are defined between adjacent bubbles arranged in a triangular tessellation, and particles are mixed by a combination of i) recirculating axial mixing within the compartment with a residence time between 0.1 and 200 s and ii) the controlled advection of particles between compartments at a time averaged rate between 0.01-250 litres solid particles/m 2 s.

2. The method of claim 1 , wherein the mixing locally within a compartment comprises mixing with a quasi-static granular flow region in the wake of each bubble defining the mixing compartment.

3. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
wherein processing the particles comprises controlling gas-solid contact time by adjusting the spacing and size of gas bubbles, so that the linear span of the area-based distributions of the bubble size and the horizontal spacing between adjacent bubbles in the fluidized bed may be less than 1.5 and 1.75, respectively.

4. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
wherein a time averaged exchange rate between an emulsion phase of the bed and a bubble phase of the bed is between 0.1 and 500 litres solid particles /m2s.

5. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
wherein processing the particles comprises controlling the stress experienced by each particle by adjusting the spacing between and size of gas bubbles, so that the standard deviation of stress experienced by each particle in the bed is less than 50% of the median stress.

6. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
wherein the bed is provided with one or more baffles that divide the bed into a plurality of vertical particle bed portions, wherein each bed portion has a thickness, normal to the baffle and less than twice the horizontal spacing between bubbles.

7. The method of claim 6 , wherein a lateral extent, normal to the thickness and along the horizontal direction, of the quasi two-dimensional particle bed portion is at least five times the thickness of the bed portion and/or a depth of the quasi two-dimensional particle bed portion is at least five times the thickness of the bed portion.

8. The method of claim 6 , wherein at least one of:
i) the baffles are curved or flat;
ii) the baffles extend through only part of the depth of the bed; and
iii) the baffles extend downwards from the top surface of the bed.

9. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
introducing solid particles to the bed while the bed is fluidized, and/or recovering processed particles from the bed while the bed is fluidized,
wherein the fluidized bed is rectangular, and solid particles are added in a central region of the fluidized bed, and/or lateral positions following the advection of particles from the centre outwards and/or processed particles are recovered at an edge region of the fluidized bed.

10. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
wherein processing particles comprises adjusting a gas flow to manipulate the flow regime of bubbles in the fluidized bed to vary the conditions of particle processing;
and wherein processing particles further comprises a first phase with a first set of process parameters that cause a first configuration of the fluidized bed, and a subsequent second phase with a second set of process parameters that cause a second configuration of the fluidized bed that is different from the first configuration.

11. The method of claim 10 , further comprising adding a liquid to the fluidized bed, and wherein the particle processing further comprises contacting the particles with the liquid, wherein adding the liquid comprises spraying the liquid onto the fluidized bed.

12. The method of claim 11 , wherein the liquid comprises a binder or a coating material.

13. The method of claim 10 , wherein the first and second configuration differ in at least one of: a bubble size, a bubble spacing, a mean frictional stress experienced by the particles; a mixing rate; and a gas flow rate.

14. The method of claim 10 , wherein the first and/or second configuration comprise one of:
i) a gas flow without pulsation, sufficient to form an unstructured fluidized bed;
ii) a pulsed gas flow sufficient to configure an homogeneous bubble flow within the fluidized bed in which the bubbles are not spatially periodic; and
iii) a pulsed gas flow configured to cause a dynamically structured bubble flow within the fluidized bed.

15. A method of operating a gas-solid fluidized bed, comprising:
flowing a pulsating gas flow upwards through a bed of solid particles from a distributor to cause a dynamically structured bubble flow; and
processing particles using the fluidized bed,
wherein the gas flow is pulsed at a frequency f between 1.5 and 5 times the natural frequency f n of the bed, and the pulsed gas flow has a minimum superficial gas velocity that is below the minimum fluidization velocity, and a maximum superficial gas velocity that is above the minimum fluidization velocity.

16. The method of claim 15 , wherein processing the particles further comprises one or more of: particle coating, particle agglomeration, particle transformation, particle drying, and use in catalysis.

Assignees

• Ucl Business Ltd

Inventors

• Francia Victor
• Coppens Marc-Olivier

Classifications

• B01J2208/00938

  Flow distribution elements · CPC title

• B01J2208/0084

  inside the bed, e.g. baffles · CPC title

• B01J2208/00566

  Pulsated flow · CPC title

• B01J2/006

  Coating of the granules without description of the process or the device by which the granules are obtained (to prevent the granules sticking together B01J2/30) · CPC title

• B01J10/002

  carried out in foam, aerosol or bubbles · CPC title