Cryocooler suitable for gas liquefaction applications, gas liquefaction system and method comprising the same

Patent metadata

Field	Value
Publication number	US-12449196-B2
Application number	US-202418636970-A
Country	US
Kind code	B2
Filing date	Apr 16, 2024
Priority date	May 17, 2018
Publication date	Oct 21, 2025
Grant date	Oct 21, 2025

Abstract

The present invention relates to a cryocooler suitable for gas liquefaction applications, that comprises a coldhead with one or more refrigeration stages; further comprising: a refrigerator compressor for distributing compressed gas-phase cryogen inside the coldhead; a heat exchanging coil arranged at least partially around the external region of the coldhead; at least one extraction orifice communicating a gas circulation circuit inside the coldhead with the heat exchanging coil; acting said extraction orifice/s as pass-through port/s which allow the gas inside the coldhead to flow through the inside of the heat exchanger coil for exchanging heat with the exterior thereof, and wherein the heat exchanging coil is adapted to connect and redirect the gas to one return port connected to the gas circulation circuit. Another object of the invention relates to a cryogen-gas liquefaction system and a method for liquefaction of gases that comprises said system.

First claim

The invention claimed is:

1. A cryocooler for gas liquefaction applications, the cryocooler comprising:
a coldhead with one or more refrigeration stages;
a refrigerator compressor for distributing a compressed cryogen gas inside the coldhead, lowering the temperature of the one or more refrigeration stages, wherein said compressed cryogen gas is supplied to and returned from the coldhead through a gas circulation circuit comprising an input gas line and an output gas line, which connect the coldhead with the refrigerator compressor;
at least one extraction orifice communicating the gas circulation circuit inside the coldhead with an external region of the one or more refrigeration stages, acting as a pass-through port which allows the gas inside the coldhead to flow to the exterior thereof; and
an input gas source configured to supply cryogen gas to the refrigerator compressor through the gas circulation circuit, wherein the input gas source comprises a heat exchanging coil arranged around an external region of the coldhead and spaced from said external region such that the heat exchanging coil and the coldhead are at least partially thermally isolated from each other;
wherein the heat exchanging coil is connected at a first end to the gas circulation circuit through the at least one extraction orifice, and at a second end to one return port connected to said gas circulation circuit, such that the compressed cryogen gas flows from the first end of the heat exchanging coil to the second end of the heat exchanging coil, and wherein said return port is arranged at the output gas line between the coldhead and the refrigerator compressor.

2. The cryocooler of claim 1 , wherein the return port is arranged at the coldhead.

3. The cryocooler of claim 1 , wherein the heat exchanging coil and the external region coldhead are spaced by a thermally insulating layer arranged between the heat exchanging coil and the external region of the coldhead.

4. The cryocooler of claim 1 , wherein the heat exchanging coil is connected to the extraction orifice and/or to the return port through one or more of the following elements: one or more cryogenic flow valves, a mass flow controller valve, a control volume, a capillary tube, an insulating seal and/or one or more joints.

5. The cryocooler of claim 1 , wherein the at least one extraction orifice has a diameter of 0.5-5.0 mm.

6. The cryocooler of claim 1 , wherein the at least one extraction orifice is fixed to the one or more refrigeration stages of the coldhead.

7. The cryocooler of claim 1 , wherein the pass-through port comprises a cryogenic flow valve.

8. The cryocooler of claim 1 , wherein the refrigerator compressor is connected to a Programmable Logic Controller (PLC) for controlling the pressure within the coldhead, and/or wherein the compressed cryogen gas is helium.

9. A cryogen-gas liquefaction system comprising:
the cryocooler of claim 1 ;
a storage container comprising a liquid storage portion and a neck portion extending therefrom, the liquid storage portion being adapted to contain a liquefied gas bath at the bottom of the storage container, and wherein said storage container comprises a liquefaction region above said bath, wherein a cryogen is contained in said liquefaction region;
a gas pressure control mechanism for controlling the cryogen gas pressure within the liquefaction region of the storage container; and
a PLC connected to the refrigerator compressor, for controlling the pressure within the coldhead;
wherein the coldhead of the cryocooler is arranged at the neck portion of the storage container, so that the compressed cryogen gas circulating through the inside of the heat exchanging coil of the cryocooler can exchange heat with the cryogen inside the liquefaction region of the storage container, such that the cryocooler is adapted to condense the cryogen contained within the liquefaction region of the storage container from a gas-phase to a liquid-phase.

10. The cryocooler of claim 6 , wherein the fixing of the at least one extraction orifice to the one or more refrigeration stages of the coldhead is combined with insulating seals to prevent undesired gas flow through said fixing.

11. The cryogen-gas liquefaction system of claim 9 , wherein the cryocooler further comprises the input gas source configured to supply cryogen gas to the refrigerator compressor through the gas circulation circuit.

12. The cryogen-gas liquefaction system of claim 9 , further comprising a gas source module containing an amount of gas-phase cryogen for the introduction of said gas-phase cryogen into the liquefaction region of the storage container.

13. The cryogen-gas liquefaction system of claim 9 , wherein the cryogen contained in the liquefaction region of the storage container and/or the compressed cryogen gas is helium, nitrogen, oxygen, hydrogen or neon.

14. A cryogen-gas liquefaction method for use in the cryogen-gas liquefaction system of claim 9 , wherein the cryogen-gas liquefaction method comprises:
(i) providing the cryogen-gas liquefaction system, wherein the coldhead of the cryocooler is at least partially disposed within the neck portion of the storage container, and is adapted to condense the cryogen contained within the liquefaction region of the storage container from a gas-phase to a liquid-phase;
(ii) measuring and controlling the vapor pressure within said liquefaction region of the storage container with the pressure control mechanism and the PLC; and
(iii) maintaining the vapor pressure within said liquefaction region of the storage container with the pressure control mechanism.

15. The cryogen-gas liquefaction system of claim 11 , wherein the input gas source comprises the heat exchanging coil arranged around the external region of the coldhead of the cryocooler, and wherein said heat exchanging coil is connected at the first end to the gas circulation circuit through the at least one extraction orifice, and at the second end to the one return port connected to said gas circulation circuit, such that the compressed cryogen gas flows from the first end of the heat exchanging coil to the second end of the heat exchanging coil, so that the compressed cryogen gas circulating through the inside of the heat exchanging coil can exchange heat with the cryogen inside the liquefaction region of the storage container.

16. The cryogen-gas liquefaction system of claim 12 , wherein the gas source module contains helium gas, recovered and/or purified from a helium-using equipment.

17. The cryogen-gas liquefaction method of claim 14 , wherein step (ii) further comprises measuring the internal pressure within the coldhead and step (iii) further comprises maintaining said pressure of the coldhead with the PLC.

18. The cryogen-gas liquefaction method of claim 14 , further comprising the step of injecting gas into the liquefaction region of the storage container with a gas source module, in collaboration with the gas pressure controller for maintaining the vapor pressure during step (iii).

Assignees

• Consejo Superior Investigacion
• Univ Zaragoza

Inventors

• Sese Monclus Javier
• Rillo Millan Conrado

Classifications

• F25J2290/62

  Details of storing a fluid in a tank · CPC title

• F25J2280/00

  Control of the process or apparatus · CPC title

• F25J2270/912

  Liquefaction cycle of a low-boiling (feed) gas in a cryocooler, i.e. in a closed-loop refrigerator · CPC title

• F25J2215/32

  Neon · CPC title

• F25J1/0254

  controlling particular process parameter, e.g. pressure, temperature · CPC title