Positive electrode plate and lithium-ion secondary battery containing same

Patent metadata

Field	Value
Publication number	US-12444739-B2
Application number	US-202418644652-A
Country	US
Kind code	B2
Filing date	Apr 24, 2024
Priority date	Oct 25, 2021
Publication date	Oct 14, 2025
Grant date	Oct 14, 2025

Abstract

A positive electrode plate includes a positive electrode current collector and a positive electrode active material layer disposed on at least one surface of the positive electrode current collector. The positive electrode active material layer includes a first positive electrode active material Li 1+x Mn y M 2-y O 4-t A t and a second positive electrode lithiation material Li 1+r Mn 1-p N p O 2-s B s . The positive electrode plate satisfies 1.5≤R·P/Q≤30, where R represents resistance of the positive electrode plate in Ω; P represents compacted density of the positive electrode plate in g/cm 3 ; and Q represents single-sided surface density of the positive electrode plate in g/1540.25 mm 2 .

First claim

What is claimed is:

1. A positive electrode plate, comprising a positive electrode current collector and a positive electrode active material layer disposed on at least one surface of the positive electrode current collector; wherein the positive electrode active material layer comprises a first positive electrode active material and a second positive electrode lithiation material; and the positive electrode plate satisfies 1.5≤R·P/Q≤30, wherein R is a numerical value representing a resistance of the positive electrode plate (in Ω); P is a numerical value representing a compacted density of the positive electrode plate (in g/cm 3 ); and Q is a numerical value representing a single-sided surface density of the positive electrode plate (in g/mm 2 ), wherein Q is calculated according to Q=1540.25×m/Ar, where m is a numerical value representing a mass of the positive active material layer (in g), and Ar is a numerical value representing an area of the positive active material layer (in mm 2 ).

2. The positive electrode plate according to claim 1 , wherein the first positive electrode active material is Li 1+x Mn y M 2-y O 4-t A t , wherein −0.1<x<0.2, 1<y≤2,0≤t<0.5,M is at least one of Ni, Fe, Zn, Mg, Al, Ti, or Zr, and A is at least one of S, N, F, Cl, or Br.

3. The positive electrode plate according to claim 1 , wherein the second positive electrode lithiation material is Li 1+r Mn 1-p N p O 2-s B s , wherein −0.1<r<0.2,0≤p<0.2,0≤s<0.2, N is at least one of Fe, Co, Ni, Ti, Zn, Mg, Al, V, Cr, or Zr, and B is at least one of S, N, F, Cl, or Br.

4. The positive electrode plate according to claim 1 , wherein 3.0≤R·P/Q≤15.

5. The positive electrode plate according to claim 1 , wherein R≤5.

6. The positive electrode plate according to claim 1 , wherein R≤2.

7. The positive electrode plate according to claim 1 , wherein 2.5<P<3.2.

8. The positive electrode plate according to claim 1 , wherein 0.3<Q<0.55.

9. The positive electrode plate according to claim 1 , wherein a weight ratio of the first positive electrode active material to the second positive electrode lithiation material is 5:1-99:1.

10. The positive electrode plate according to claim 5 , wherein the weight ratio of the first positive electrode active material to the second positive electrode lithiation material is 9:1-99:1.

11. The positive electrode plate according to claim 1 , wherein a weight percentage of the first positive electrode active material in the positive electrode active material is 80%-98%.

12. The positive electrode plate according to claim 7 , wherein the weight percentage of the first positive electrode active material in the positive electrode active material is 85%-98%.

13. A lithium-ion secondary battery, comprising a positive electrode plate, a negative electrode plate, a separator, and an electrolyte, wherein the positive electrode plate comprises a positive electrode current collector and a positive electrode active material layer disposed on at least one surface of the positive electrode current collector, wherein the positive electrode active material layer comprises a first positive electrode active material and a second positive electrode lithiation material; and the positive electrode plate satisfies 1.5≤R·P/Q≤30, wherein R is a numerical value representing a resistance of the positive electrode plate (in Ω); P is a numerical value representing a compacted density of the positive electrode plate (in g/cm 3 ); and Q is a numerical value representing a single-sided surface density of the positive electrode plate (in g/mm 2 ), wherein Q is calculated according to Q=1540.25×m/Ar, where m is a numerical value representing a mass of the positive active material layer (in g), and Ar is a numerical value representing an area of the positive active material layer (in mm 2 ).

14. The lithium-ion secondary battery according to claim 13 , wherein the electrolyte comprises in weight percentage: 0.001% to 5% of vinylene carbonate.

15. The lithium-ion secondary battery according to claim 13 , wherein the electrolyte comprises in weight percentage: 0.001% to 5% of 1,3-propane sultone.

16. The lithium-ion secondary battery according to claim 13 , wherein 3.0≤R·P/Q≤15.

17. The lithium-ion secondary battery according to claim 13 , wherein 2.5<P<3.2.

18. The lithium-ion secondary battery according to claim 13 , wherein R≤2.

19. The lithium-ion secondary battery according to claim 13 , wherein a weight ratio of the first positive electrode active material to the second positive electrode lithiation material is 5:1-99:1.

20. An electronic apparatus, comprising the lithium-ion battery according to claim 13 .

Assignees

• Ningde Amperex Technology Ltd

Inventors

• Zhou Molin

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0567

  characterised by the additives · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title