Rotomolding composition

Patent metadata

Field	Value
Publication number	US-12441872-B2
Application number	US-202117799117-A
Country	US
Kind code	B2
Filing date	Feb 10, 2021
Priority date	Feb 17, 2020
Publication date	Oct 14, 2025
Grant date	Oct 14, 2025

Abstract

A rotomolding composition comprises a blend of two polyethylenes: 1) a well stabilized polyethylene; and 2) a poorly stabilized polyethylene having a very low flow rate. The poorly stabilized polyethylene is further characterized by having a large particle size (from 500 to 3000 microns). Rotomolded parts prepared from the composition have a rough inner surface. Polyurethane foam adheres well to this rough surface.

First claim

The invention claimed is:

1. A polyethylene composition comprising:
1) From 85 to 99 weight % of a stabilized polyethylene having a melt index, I 2 , as measured by ASTM D 1238 at 190° C. using a 2.16 kg lead, of from 0.5 to 10 grams/10 minutes; a density as measured by ASTM D792 of from 0.920 to 0.950 g/cc; and
2) From 15 to 1 weight % of a substantially non-stabilized polyethylene having (i) a high load melt index, I 21 , as measured by ASTM D1238 at 190° C. using a 21.6 kg load, of from 2 to 20 grams/10 minutes; (ii) a density of from 0.950 to 0.965 g/cc as measured by ASTM D792; and (iii) an average particle size of from 500 to 3000 microns;
wherein:
the stabilized polyethylene contains a stabilizer package comprising a primary antioxidant and a secondary antioxidant;
the substantially non-stabilized polyethylene contains less than 100 ppm of primary antioxidant and/or secondary antioxidant; and
an average particle size of said stabilized polyethylene is smaller than the average particle size of said substantially non-stabilized polyethylene.

2. The polyethylene composition of claim 1 wherein said average particle size of the substantially non-stabilized polyethylene is from 500 to 1000 microns.

3. The polyethylene composition of claim 1 wherein said substantially non-stabilized polyethylene has a high load melt index, I 21 , as measured by ASTM D1238 at 190° C. using a 21.6 kg load, of form 3 to 6 grams per 10 minutes.

4. The polyethylene composition of claim 1 wherein said stabilized polyethylene contains a stabilizer package comprising:
1.1) the primary antioxidant in an amount of from 250 to 1500 parts per million by weight, and
1.2) the secondary antioxidant in an amount of from 250 to 1500 parts per million by weight.

5. A process to prepare a rotomolded part comprising:
a) preparing a polymer composition according to claim 1 ; and
b) subjecting said blend to rotational molding.

6. The process of claim 5 wherein said rotational molding is undertaken at a temperature of from 250° C. to 400° C.

7. The process of claim 5 wherein the rotomolded part has an interior surface with a surface roughness of from 10 microns to 30 microns.

8. The process of claim 7 wherein said surface roughness is from 12 to 20 microns.

9. The process of claim 7 wherein said interior surface is further characterized by having carbonyl functional groups that are detectable by a Fourier Transform Infra Red instrument.

Assignees

• Nova Chemicals International Sa

Inventors

• D'Agostino Carmine
• Arnould Gilbert
• Bellehumeur Celine
• Hay Henry
• Dang Van

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• B29C41/06 Primary

  about two or more axes · CPC title

• B29C41/003

  characterised by the choice of material · CPC title