System and method of generating electricity in a body of water

Patent metadata

Field	Value
Publication number	US-12441644-B2
Application number	US-202117558519-A
Country	US
Kind code	B2
Filing date	Dec 21, 2021
Priority date	Dec 21, 2020
Publication date	Oct 14, 2025
Grant date	Oct 14, 2025

Abstract

A method of generating electricity in a body of water includes providing a colony of sulfur-reducing bacteria, a colony of sulfur-oxidizing bacteria, and a colony of denitrifying bacteria submerged in the body of water. The colony of sulfur-reducing bacteria can be used to convert at least a portion of sulfates present in the body of water to hydrogen sulfide. The colony of sulfur-oxidizing bacteria can be used to convert the hydrogen sulfide to sulfuric acid, which can react with manganese to produce hydrogen gas. The colony of denitrifying bacteria can be used to convert at least a portion of nitrogen oxides in the body of water to nitrogen gas, which can be bubbled through a portion of water from the body of water to remove dissolved oxygen gas. The hydrogen gas and oxygen gas can be combined in a fuel cell generator to generate electricity.

First claim

What is claimed is:

1. A method of generating electricity in a body of water, comprising:
providing a colony of sulfur-reducing bacteria, a colony of sulfur-oxidizing bacteria, and a colony of denitrifying bacteria, wherein the colonies are submerged in the body of water;
using the colony of sulfur-reducing bacteria, converting at least a portion of sulfates present in the body of water to hydrogen sulfide;
using the colony of sulfur-oxidizing bacteria, converting the hydrogen sulfide to sulfuric acid;
reacting the sulfuric acid with manganese to produce hydrogen gas and manganese sulfate;
using the colony of denitrifying bacteria, converting at least a portion of nitrogen oxides in the body of water to nitrogen gas;
bubbling the nitrogen gas through a portion of water from the body of water to remove dissolved oxygen from the portion of water, thereby forming a mixture of the nitrogen gas and oxygen gas; and
combining the hydrogen gas and oxygen gas in a fuel cell generator to generate electricity.

2. The method of claim 1 , wherein the colonies are in or on a housing submerged in the body of water.

3. The method of claim 2 , wherein the housing comprises a sulfur-reducing compartment, a sulfur-oxidizing compartment, and a denitrifying compartment, wherein the colony of sulfur-reducing bacteria is in the form of a film on an interior surface of the sulfur-reducing compartment, wherein the colony of sulfur-oxidizing bacteria is in the form of a film on an interior surface of the sulfur-oxidizing compartment, and wherein the colony of denitrifying bacteria is in the form of a film on an interior surface of the denitrifying compartment.

4. The method of claim 3 , further comprising flowing water from the body of water into the sulfur-reducing compartment, flowing water from the sulfur-reducing compartment into the sulfur-oxidizing compartment, and separately flowing water from the body of water into the denitrifying compartment.

5. The method of claim 3 , wherein the housing further comprises a reaction chamber, wherein the sulfuric acid is reacted with the manganese in the reaction chamber.

6. The method of claim 5 , wherein the manganese is in the form of a manganese nodule originating on a seafloor, and wherein the method further comprises collecting the manganese nodule from the seafloor and placing the manganese nodule in the reaction chamber.

7. The method of claim 1 , further comprising storing the hydrogen gas and the oxygen gas such that the hydrogen gas and oxygen gas are combined in the fuel cell generator to produce electricity on demand.

8. The method of claim 1 , wherein the colonies and the fuel cell generator are included in a first underwater unmanned vehicle.

9. The method of claim 8 , further comprising docking a second underwater unmanned vehicle to the first underwater unmanned vehicle and recharging a battery of the second underwater unmanned vehicle using the electricity generated by the fuel cell generator.

10. The method of claim 1 , wherein the colonies are included in a first underwater unmanned vehicle and the fuel cell generator is included in a second underwater unmanned vehicle, wherein the second underwater unmanned vehicle is dockable with the first underwater unmanned vehicle to transfer the hydrogen gas and the oxygen gas from the first underwater unmanned vehicle to the second underwater unmanned vehicle.

11. The method of claim 1 , wherein the sulfur-reducing bacteria comprise Escherichia coli, Pseudomonas spp., Pseudomonas aeruginosa, Vibrio spp., Vibrio natriegens , or a combination thereof; wherein the sulfur-oxidizing bacteria comprise Thiotrix, Thiomonas, Halothiobacillus, Acidothiobacillus thiooxidans, Acidothiobacillus ferrooxidans , or a combination thereof; and wherein the denitrifying bacteria comprise Pseudomonas, Pseudomonas spp., Pseudomonas stutzeri, Pseudomonas aeruginosa , or a combination thereof.

12. The method of claim 1 , wherein the body of water is an ocean and wherein the colonies and the fuel cell generator are submerged at a depth within about 10 meters of a seafloor of the ocean.

13. A system for generating electricity in a body of water, comprising:
a housing submerged or submergible in the body of water;
a colony of sulfur-reducing bacteria in or on the housing to convert sulfates in the body of water to hydrogen sulfide;
a colony of sulfur-oxidizing bacteria in or on the housing to convert the hydrogen sulfide to sulfuric acid;
a reaction chamber at least partially enclosed by the housing to react the sulfuric acid with manganese to produce hydrogen gas and manganese sulfate;
a colony of denitrifying bacteria in or on the housing to convert nitrogen oxides in the body of water to nitrogen gas;
a bubbling chamber at least partially enclosed by the housing to bubble the nitrogen gas through water from the body of water to remove dissolved oxygen from the water, thereby forming a mixture of the nitrogen gas and oxygen gas; and
a fuel cell generator connected to the reaction chamber and the bubbling chamber to combine the hydrogen gas and the oxygen gas, thereby generating electricity.

14. The system of claim 13 , wherein the housing comprises a sulfur-reducing compartment, a sulfur-oxidizing compartment, and a denitrifying compartment, wherein the colony of sulfur-reducing bacteria is in the form of a film on an interior surface of the sulfur-reducing compartment, wherein the colony of sulfur-oxidizing bacteria is in the form of a film on an interior surface of the sulfur-oxidizing compartment, and wherein the colony of denitrifying bacteria is in the form of a film on an interior surface of the denitrifying compartment.

15. The system of claim 14 , wherein the manganese is in the form of a manganese nodule originating on a seafloor, and wherein the system further comprises a robotic collector to collect the manganese nodule from the seafloor and place the manganese nodule in the reaction chamber.

16. The system of claim 15 , wherein the robotic collector comprises an optical sensor to detect the manganese nodule on the seafloor based on a characteristic comprising size, shape, orientation, texture, cluster density, or a combination thereof.

17. The system of claim 13 , wherein the fuel cell generator and the housing are integrated in a first underwater unmanned vehicle.

18. The system of claim 13 , wherein the housing is included in a first underwater unmanned vehicle and the fuel cell generator is included in a second underwater unmanned vehicle, wherein the second underwater unmanned vehicle is dockable with the first underwater unmanned vehicle to transfer the hydrogen gas and the oxygen gas from the first underwater unmanned vehicle to the second underwater unmanned vehicle.

19. The system of claim 13 , wherein the sulfur-reducing bacteria comprise Escherichia coli, Pseudomonas spp., Pseudomonas aeruginosa, Vibrio spp., Vibrio natriegens , or a combination thereof; wherein the sulfur-oxidizing bacteria comprise Thiotrix, Thiomonas, Halothiobacillus, Acidothiobacillus thiooxidans, Acidothiobacillus ferrooxidans , or a combination thereof; and wherein the denitrifying bacteria comprise Pseudomonas, Pseudomonas spp., Pseudomonas stutzeri, Pseudomonas aeruginosa , or a combination thereof.

20. The system of claim 13 , wherein the system is deployed in an ocean and submerged at a depth within about 10 meters of a seafloor of the ocean.

Assignees

• Raytheon Bbn Technologies Corp
• Rtx Bbn Tech Inc

Inventors

• Rosenthal Benjamin Jacob
• Rogers Miles
• Scott Helen

Classifications

• H01M8/0662

  Treatment of gaseous reactants or gaseous residues, e.g. cleaning · CPC title

• H01M8/0631

  Reactor construction specially adapted for combination reactor/fuel cell (hydrogen C01B3/00; reactors for physicochemical processes B01J19/00) · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• C01F5/40

  Magnesium sulfates (double sulfates of magnesium with sodium or potassium C01D5/12, with other alkali metals {C01D15/00}, C01D17/00) · CPC title

• C01B17/508

  by oxidation of sulfur compounds · CPC title