Phosphorus oxide and phosphoric acid production processes

Patent metadata

Field	Value
Publication number	US-12441616-B2
Application number	US-202217701815-A
Country	US
Kind code	B2
Filing date	Mar 23, 2022
Priority date	Nov 19, 2018
Publication date	Oct 14, 2025
Grant date	Oct 14, 2025

Abstract

The present invention is generally directed to improved processes for the preparation of various phosphorus oxides and phosphoric acid. Phosphorus oxides prepared in accordance with the present invention include phosphorus (III) oxides (e.g., tetraphosphorus hexaoxide (P 4 O 6 )). Phosphorus (III) oxides such as P 4 O 6 are useful products and are also useful as precursors in preparation of other products, including phosphorous acid (H 3 PO 3 ) and other phosphorus-containing chemicals. Certain aspects of this invention are also directed to using various byproducts formed during P 4 O 6 production as precursors for the formation of phosphoric acid (H 3 PO 4 ) and P 2 O 5 . In particular, the present invention is directed to improved processes for the preparation of phosphorus (III) oxides (e.g., P 4 O 6 ) suitable for use in the preparation of phospho-herbicides such N-(phosphonomethyl)glycine (glyphosate) and precursors thereof (e.g., N-(phosphonomethyl)iminodiacetic acid (PMIDA)). The present invention is thus further directed to preparation of these compounds.

First claim

What is claimed is:

1. A process for the manufacture of phosphorus (III) oxide, the process comprising:
in a reactor unit, reacting phosphorus with oxygen, thereby forming an intermediate reaction product stream comprising P 2 O 3 and one or more byproducts;
in a quenching unit, quenching the intermediate reaction product stream by contacting with a quenching liquid, thereby forming a reaction product slurry comprising P 4 O 6 and one or more byproducts;
recovering a first byproduct stream from the reaction product slurry;
introducing an oxygen-containing gas, phosphorus (P 4 ), and the first byproduct stream into a vaporizer unit, wherein the components of the first byproduct stream are vaporized to form a vaporized recycle stream comprising one or more oxides of phosphorus of the general formula P x O y where x is from 1-4, y is from 1-10;
introducing at least a portion of the vaporized recycle stream into the reactor unit,
recovering a second byproduct stream from the reaction product slurry, the second byproduct stream comprising phosphorus (III), phosphorus (V) and/or phosphorus (III and V) oxides;
introducing the second byproduct stream and oxygen into a vaporizer unit, thereby oxidizing phosphorus oxides present in the second byproduct stream to produce a vapor product stream comprising P 2 O 5 and/or P 4 O 10 ; and
contacting the vapor product stream with water, thereby forming a liquid product stream comprising H 3 PO 4 .

2. The process as set forth in claim 1 , wherein P 2 O 3 constitutes at least about 60% by weight of the intermediate reaction product stream.

3. The process as set forth in claim 1 , wherein the quenching liquid comprises liquid P 4 O 6 .

4. The process as set forth in claim 3 , wherein the quenching liquid comprises liquid P 4 O 6 recovered from the reaction product slurry.

5. The process as set forth in claim 1 , wherein the temperature of the quenching liquid is at least about 293K.

6. The process as set forth in claim 1 , wherein the temperature of the quenching liquid is from about 293K to about 423K.

7. The process as set forth in claim 1 , wherein the reaction product slurry has a P 4 O 6 content of at least about 70% by weight of the reaction product slurry.

8. The process as set forth in claim 1 , wherein the temperature of the vaporized recycle stream is at least 1100K.

9. The process as set forth in claim 1 , wherein the temperature of the vaporized recycle stream is from about 1200K to about 2000K.

10. The process as set forth in claim 1 , wherein the vaporized recycle stream has a solids content of less than about 5 weight %.

11. A process for the manufacture of phosphorus (III) oxide, the process comprising:
in a reactor unit, reacting phosphorus with oxygen, thereby forming an intermediate reaction product stream comprising P 2 O 3 and one or more byproducts;
in a quenching unit, quenching the intermediate reaction product stream by contacting with a quenching liquid, thereby forming a reaction product slurry comprising P 4 O 6 and one or more byproducts;
recovering a first byproduct stream from the reaction product slurry;
introducing an oxygen-containing gas, phosphorus (P 4 ), and the first byproduct stream into a vaporizer unit, wherein the components of the first byproduct stream are vaporized to form a vaporized recycle stream comprising one or more oxides of phosphorus of the general formula P x O y where x is from 1-4, y is from 1-10;
introducing at least a portion of the vaporized recycle stream into the reactor unit,
recovering a second byproduct stream from the reaction product slurry, the second byproduct stream comprising phosphorus (III), phosphorus (V) and/or phosphorus (III and V) oxides;
introducing the second byproduct stream and oxygen into a vaporizer unit, thereby oxidizing phosphorus oxides present in the second byproduct stream to produce a vapor product stream comprising P 2 O 5 and/or P 4 O 10 , and
condensing the vapor product stream with water, thereby forming a product stream comprising solid P 2 O 5 .

12. The process as set forth in claim 11 , wherein P 2 O 3 constitutes at least about 60% by weight of the intermediate reaction product stream.

13. The process as set forth in claim 11 , wherein the quenching liquid comprises liquid P 4 O 6 .

14. The process as set forth in claim 13 , wherein the quenching liquid comprises liquid P 4 O 6 recovered from the reaction product slurry.

15. The process as set forth in claim 11 , wherein the temperature of the quenching liquid is at least about 293K.

16. The process as set forth in claim 11 , wherein the temperature of the quenching liquid is from about 293K to about 423K.

17. The process as set forth in claim 11 , wherein the reaction product slurry has a P 4 O 6 content of at least about 70% by weight of the reaction product slurry.

18. The process as set forth in claim 11 , wherein the temperature of the vaporized recycle stream is at least 1100K.

19. The process as set forth in claim 11 , wherein the temperature of the vaporized recycle stream is from about 1200K to about 2000K.

20. The process as set forth in claim 11 , wherein the vaporized recycle stream has a solids content of less than about 5 weight %.

Assignees

• Monsanto Technology Llc

Inventors

• Casanova Eduardo Aurelio
• Fan Peng
• Struble Justin Robert
• Xu Jian

Classifications

• C01B25/20

  Preparation from elemental phosphorus or phosphoric anhydride · CPC title

• C01B25/12 Primary

  Oxides of phosphorus · CPC title