Separator including binders having different glass transition temperatures and method of manufacturing the same
US-2020152945-A1 · May 14, 2020 · US
US12438237B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12438237-B2 |
| Application number | US-202118008336-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 16, 2021 |
| Priority date | Jul 16, 2020 |
| Publication date | Oct 7, 2025 |
| Grant date | Oct 7, 2025 |
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A battery cell including an electrode assembly present in a battery casing. The electrode assembly includes a positive electrode, a negative electrode and a separator interposed between the positive electrode and the negative electrode. The separator includes a porous polymer substrate, a first organic/inorganic porous coating layer on at least one surface of the porous polymer substrate, and a second organic/inorganic porous coating layer on a surface of the first organic/inorganic porous coating layer. The first organic/inorganic porous coating layer includes first inorganic particles and a first binder polymer, the second organic/inorganic porous coating layer includes second inorganic particles and a second binder polymer, the second organic/inorganic porous coating layer faces the positive electrode, and the second binder polymer has a weight average molecular weight higher than the weight average molecular weight of the first binder polymer.
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What is claimed is: 1. A battery cell, comprising: an electrode assembly present in a battery casing, wherein the electrode assembly comprises a positive electrode, a negative electrode and a separator interposed between the positive electrode and the negative electrode, wherein the separator comprises a porous polymer substrate, a first organic/inorganic porous coating layer on at least one surface of the porous polymer substrate, and a second organic/inorganic porous coating layer on a surface of the first organic/inorganic porous coating layer, wherein the first organic/inorganic porous coating layer comprises first inorganic particles and a first binder polymer, wherein the second organic/inorganic porous coating layer comprises second inorganic particles and a second binder polymer, wherein the second organic/inorganic porous coating layer faces the positive electrode, and wherein the second binder polymer has a weight average molecular weight higher than a weight average molecular weight of the first binder polymer. 2. The battery cell according to claim 1 , wherein the weight average molecular weight of the second binder polymer ranges from 800,000 to 1,500,000. 3. The battery cell according to claim 1 , wherein the weight average molecular weight of the first binder polymer ranges from 300,000 to 600,000. 4. The battery cell according to claim 1 , wherein the first organic/inorganic porous coating layer has a thickness larger than a thickness of the second organic/inorganic porous coating layer. 5. The battery cell according to claim 4 , wherein a ratio of the thickness of the first organic/inorganic porous coating layer to the thickness of the second organic/inorganic porous coating layer is 6:4 to 9:1. 6. The battery cell according to claim 1 , wherein each of the first binder polymer and the second binder polymer is at least one independently selected from the group consisting of polyvinylidene fluoride (PVDF), hexafluoropropylene (HFP), polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethyl methacrylate, polybutyl acrylate, polyacrylonitrile, polyvinyl pyrrolidone, polyvinyl acetate, polyethylene-co-vinyl acetate, polyethylene oxide, polyarylate, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethyl pullulan, cyanoethyl polyvinyl alcohol, cyanoethyl cellulose, cyanoethyl sucrose, pullulan, carboxymethyl cellulose, acrylonitrile-styrene-butadiene copolymer and polyimide. 7. The battery cell according to claim 1 , wherein an adhesion between the separator and the positive electrode is 40 gf/25 mm or more. 8. The battery cell according to claim 1 , wherein the first binder polymer is the same as or different from the second binder polymer. 9. The battery cell according to claim 1 , wherein the first inorganic particles are the same or different from the second inorganic particles.
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