Solar thermal aerogel receiver and materials therefor
US-11851334-B2 · Dec 26, 2023 · US
US12437741B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12437741-B2 |
| Application number | US-202318342339-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 27, 2023 |
| Priority date | Apr 25, 2018 |
| Publication date | Oct 7, 2025 |
| Grant date | Oct 7, 2025 |
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Described herein are window retrofits including a monolithic silica aerogel slab having (i) an average haze value of <5% as calculated in accordance with ASTM standard D1003-13 and (ii) a U-factor of <0.5 BTU/sf/hr/° F., and a transparent polymer envelope sealed at an internal pressure of ≤1 atmosphere, wherein the monolithic silica aerogel slab is encapsulated in the transparent polymer envelope. The monolithic aerogel slab can have a transmittance>94% at 8 mm thickness. The window retrofit can be bonded to a glass sheet.
Opening claim text (preview).
What is claimed is: 1. An article, comprising: a first sheet comprising glass; and a slab comprising an aerogel comprising silica, wherein the slab is bonded to the first sheet, and wherein the slab is transmissive to at least some visible light. 2. The article of claim 1 , wherein the article comprises an insulated glass unit (IGU). 3. The article of claim 1 , further comprising a second sheet comprising glass bonded to the slab. 4. The article of claim 1 , further comprising a second sheet comprising glass positioned adjacent to the slab. 5. The article of claim 1 , wherein the slab comprises a mean particle radius of less than or equal to 2 nm. 6. The article of claim 1 , wherein the slab comprises a mean pore radius of less than or equal to 10 nm. 7. The article of claim 1 , wherein the slab has an average haze value of <5% as calculated in accordance with ASTM standard D1003-13. 8. The article of claim 1 , wherein the slab further comprises nanoparticles configured to modify the transmission spectra of solar radiation. 9. The article of claim 1 , wherein the slab has a density greater than or equal to 0.05 g/cm 3 and less than or equal to 0.25 g/cm 3 . 10. The article of claim 1 , wherein the slab has a mean scattering radius of less than or equal to 5 nm. 11. The article of claim 1 , wherein the article has a U-factor less than or equal to 0.5 BTU/sf/hr/° F. at an external temperature of −15° C. 12. The article of claim 1 , wherein the slab has a porosity of greater than or equal to 90%. 13. The article of claim 1 , wherein the slab has a specific surface area greater than or equal to 500 m 2 /g and less than or equal to 1000 m 2 /g. 14. The article of claim 1 , wherein the slab has an average sound transmission loss of greater than or equal to 10 dB at a frequency greater than or equal to 50 Hz and less than or equal to 1600 Hz. 15. An article, comprising: an aerogel portion of the article comprising silica; and a first glass portion of the article, wherein the first glass portion is bonded to the aerogel portion, and the aerogel portion has an average haze value of <5% as calculated in accordance with ASTM standard D1003-13 when measured at an aerogel thickness greater than or equal to 1 mm. 16. A method, comprising: bonding a slab comprising an aerogel comprising silica to a first sheet comprising a transparent material to produce an article, wherein the slab is transmissive to at least some visible light. 17. The method of claim 16 , wherein bonding comprises forming the slab on the first sheet such that the slab and the first sheet are bonded. 18. The method of claim 16 , wherein the transparent material comprises glass. 19. The article of claim 1 , wherein the slab has a transmittance greater than or equal to 70% at at least one wavelength greater than or equal to 360 nm and less than or equal to 780 nm. 20. The article of claim 19 , wherein the slab has a transmittance greater than or equal to 80% at at least one wavelength greater than or equal to 400 nm and less than or equal to 700 nm. 21. The article of claim 1 , wherein the slab has a transmittance greater than or equal to 70% at all wavelengths greater than or equal to 360 nm and less than or equal to 780 nm. 22. The article of claim 21 , wherein the slab has a transmittance greater than or equal to 80% at all wavelengths greater than or equal to 400 nm and less than or equal to 700 nm. 23. The article of claim 1 , wherein the slab has a transmittance greater than or equal to 95% at a wavelength of 600 nm. 24. The method of claim 16 , wherein the slab has a transmittance greater than or equal to 70% at at least one wavelength greater than or equal to 360 nm and less than or equal to 780 nm. 25. The method of claim 24 , wherein the slab has a transmittance greater than or equal to 80% at at least one wavelength greater than or equal to 400 nm and less than or equal to 700 nm. 26. The method of claim 16 , wherein the slab has a transmittance greater than or equal to 70% at all wavelengths greater than or equal to 360 nm and less than or equal to 780 nm. 27. The method of claim 26 , wherein the slab has a transmittance greater than or equal to 80% at all wavelengths greater than or equal to 400 nm and less than or equal to 700 nm. 28. The method of claim 16 , wherein the slab has a transmittance greater than or equal to 95% at a wavelength of 600 nm. 29. An article, comprising: a first sheet comprising glass; and a slab comprising an aerogel comprising silica, wherein the slab is bonded to the first sheet, wherein the slab comprises at least one of the following characteristics: the slab has a transmittance greater than or equal to 70% at at least one wavelength greater than or equal to 360 nm and less than or equal to 780 nm; the slab has an average haze value of <5% as calculated in accordance with ASTM standard D1003-13 when measured at a slab thickness greater than or equal to 1 mm; or the slab has a transmittance of greater than or equal to 70% at all wavelengths greater than or equal to 360 nm and less than or equal to 1100 nm; the slab has a transmittance of greater than or equal to 95% at a wavelength of 600 nm; or the slab has a solar weighted transmittance of greater than or equal to 95% measured at a slab thickness of 8 mm. 30. The article of claim 29 , wherein the slab has a transmittance greater than or equal to 70% at at least one wavelength greater than or equal to 360 nm and less than or equal to 780 nm, the slab has an average haze value of <5% as calculated in accordance with ASTM standard D1003-13 when measured at a slab thickness greater than or equal to 1 mm, and the slab has a transmittance of greater than or equal to 70% at all wavelengths greater than or equal to 360 nm and less than or equal to 1100 nm. 31. The article of claim 29 , wherein the slab has an average haze value of <5% as calculated in accordance with ASTM standard D1003-13 when measured at a slab thickness greater than or equal to 1 mm, the slab has a transmittance of greater than or equal to 70% at all wavelengths greater than or equal to 360 nm and less than or equal to 1100 nm, and the slab has a transmittance of greater than or equal to 95% at a wavelength of 600 nm. 32. The article of claim 29 , wherein the slab has a transmittance of greater than or equal to 70% at all wavelengths greater than or equal to 360 nm and less than or equal to 1100 nm, the slab has a transmittance of greater than or equal to 95% at a wavelength of 600 nm, and the slab has a solar weighted transmittance of greater than or equal to 95% measured at a slab thickness of 8 mm. 33. The article of claim 29 , wherein the slab has a transmittance greater than or equal to 70% at at least one wavelength greater than or equal to 360 nm and less than or equal to 780 nm, the slab has an average haze value of <5% as calculated in accordance with ASTM standard D1003-13 when measured at a slab thickness greater than or equal to 1 mm, and the slab has a transmittance of greater than or equal to 95% at a wavelength of 600 nm. 34. The article of claim 29 , wherein the slab has a transmittance of greater than or equal to 95% at a wavelength of 600 nm, the slab has a solar weighted transmittance of greater th
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