Method for manufacturing precursor fiber bundle, method for manufacturing carbon fiber bundle, and carbon fiber bundle

Patent metadata

Field	Value
Publication number	US-12435451-B2
Application number	US-201917282441-A
Country	US
Kind code	B2
Filing date	Oct 2, 2019
Priority date	Oct 5, 2018
Publication date	Oct 7, 2025
Grant date	Oct 7, 2025

Abstract

A method for manufacturing a precursor fiber bundle provides precursor fiber bundles used in manufacturing carbon fiber bundles allowing high productivity and having high tensile strength with less yarn bundle divides in the fiber bundles. The method for manufacturing a precursor fiber bundle includes spinning by extruding a spinning solution through a spinneret to produce a coagulated fiber bundle, and interlacing the coagulated fiber bundle by applying a fluid onto the coagulated fiber bundle. The interlacing includes applying the fluid ( 18 ) under a pressure in a range of 0.01 to 0.05 MPa onto the coagulated fiber bundle ( 14 ) with a moisture content in a range of 25 to 50% under a tension of 0.02 g/dtex or less.

First claim

The invention claimed is:

1. A method for manufacturing a precursor fiber bundle, the method comprising:
spinning by extruding a spinning solution through a spinneret to produce a coagulated fiber bundle;
applying an oil agent to the coagulated fiber bundle to produce an oiled coagulated fiber bundle;
drying and densifying the oiled coagulated fiber bundle to produce a dried and densified coagulated fiber bundle;
steam stretching the dried and densified coagulated fiber bundle to produce a steam-stretched coagulated fiber bundle;
applying water to the steam-stretched coagulated fiber bundle to obtain a water-applied coagulated fiber bundle having a moisture content in a range of 25˜50%; and
interlacing the water-applied coagulated fiber bundle by applying a fluid onto the water-applied coagulated fiber bundle.

2. The method according to claim 1 , wherein
the interlacing includes applying the fluid under a pressure in a range of 0.01 to 0.05 MPa onto the coagulated fiber bundle under a tension of 0.001 to 0.015 g/dtex.

3. The method according to claim 1 , wherein
the coagulated fiber bundle includes at least 30,000 coagulated fibers.

4. The method according to claim 2 , wherein
the coagulated fiber bundle includes at least 36,000 coagulated fibers.

5. The method according to claim 3 , wherein
the spinning includes extruding the coagulated fiber bundle through one spinneret.

6. A method for manufacturing a carbon fiber bundle from a precursor fiber bundle, comprising:
oxidizing a precursor carbon fiber bundle to form an oxidized carbon fiber bundle, and
carbonizing the oxidized carbon fiber bundle,
wherein
the precursor fiber bundle is manufactured with the method according to claim 1 .

7. A carbon fiber bundle, comprising:
a fiber bundle including at least 48,000 filaments,
wherein the filaments each have a roundness of at least 0.9, a diameter in a range of 4.8 to 6.5 μm, and a tensile strength of at least 5,600 MPa.

8. The carbon fiber bundle according to claim 7 , wherein
when the carbon fiber bundle is run at a rate of 50 ft/min for 2 minutes between urethane sheets on which a 125-g weight is placed, a quantity of carbon fibers left on the urethane sheets is 40 μg/ft or less.

9. The carbon fiber bundle according to claim 8 , wherein
the carbon fiber bundle has a yarn bundle divided rate of 2% or less as determined by passing a 13 mm-diameter round metal bar through a U-shaped carbon fiber bundle having a 300-g weight attached to lower ends thereof, repeating a 140-mm drop test three times, subjecting the carbon fiber bundle after the drop test, excluding a part contacted with the round metal bar, to image analysis to measure an area of a slit formed due to yarn bundle divides and an area of a strand portion, and taking a percentage of the area of the slit due to the yarn bundle divides in the area of the strand portion as the yarn bundle divided rate.

10. The carbon fiber bundle according to claim 9 , wherein
the carbon fiber bundle allows a composite material comprising the carbon fiber bundle and a resin material to have a tensile strength of 90% or more of a tensile strength of a strand.

11. The carbon fiber bundle according to claim 7 , wherein
the carbon fiber bundle has a tensile modulus of at least 285 to no more than 290 GPa.

Assignees

• Teijin Ltd

Inventors

• Nakamura Yosuke
• Nishida Atsumi
• Yoshikawa Hidekazu

Classifications

• D01F6/38 Primary

  comprising unsaturated nitriles as the major constituent · CPC title

• D01D5/06

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title

• D02J1/22

  Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch (stretch spinning D01D5/12) · CPC title

• D02J13/005

  by contact with at least one rotating roll · CPC title

• D02J1/08

  Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams · CPC title