Processes and systems for upgrading a hydrocarbon

Patent metadata

Field	Value
Publication number	US-12435018-B2
Application number	US-202218268463-A
Country	US
Kind code	B2
Filing date	Jan 3, 2022
Priority date	Jan 8, 2021
Publication date	Oct 7, 2025
Grant date	Oct 7, 2025

Abstract

Processes are provided for removing contaminants from a refinery gas. Such process can include recovering a process gas comprising ethylene and propylene from a steam cracker effluent recovered from a stream cracker in a steam cracker facility. A refinery gas can be recovered from a refinery facility. The process gas can be compressed in a plurality of compressor stages. A pressure of the refinery gas can be determined. A compressor stage in the plurality of compressor stages can be selected for introducing the refinery gas using the determined pressure of the refinery gas. The refinery gas can be introduced into the selected compressor stage to produce a combined gas that can include the process gas and the refinery gas. At least a portion of one or more impurities can be removed from the combined gas in the steam cracker facility to produce an upgraded combined gas.

First claim

What is claimed is:

1. A process for removing contaminants from a refinery gas, comprising:
recovering a process gas comprising ethylene and propylene from a steam cracker effluent recovered from a stream cracker in a steam cracker facility;
recovering a refinery gas from a refinery facility;
compressing the process gas in a plurality of compressor stages;
determining a pressure of the refinery gas;
selecting a compressor stage in the plurality of compressor stages for introducing the refinery gas using the determined pressure of the refinery gas, wherein the selected compressor stage is located after a first compressor stage and before a last compressor stage of the plurality of compressor stages;
introducing the refinery gas into the selected compressor stage to produce a combined gas comprising the process gas and the refinery gas; and
removing at least a portion of one or more impurities from the combined gas in the steam cracker facility to produce an upgraded combined gas lean in the one or more impurities.

2. The process of claim 1 , wherein the one or more impurities comprise at least one of: ammonia, methanol, methyl mercaptan, ethyl mercaptan, hydrogen sulfide, carbon dioxide, and acetaldehyde, and wherein removing the at least a portion of the one or more impurities from the combined gas comprises contacting the combined gas with an aqueous amine, an aqueous inorganic base, or a combination thereof to produce a spent aqueous amine, a spent caustic, or a combination thereof and a combined gas lean in the one or more impurities.

3. The process of claim 1 , wherein the one or more impurities comprise carbonyl sulfide, and wherein removing the at least a portion of the one or more impurities from the combined gas comprises contacting the combined gas with a sorbent under conditions sufficient to cause at least a portion of the carbonyl sulfide to sorb onto the sorbent to produce a treated combined gas lean in carbonyl sulfide and a sorbent rich in carbonyl sulfide.

4. The process of claim 3 , further comprising:
contacting the sorbent rich in carbonyl sulfide with a regenerating gas comprising molecular hydrogen, one or more C 1 -C 4 hydrocarbons, or a mixture thereof to produce a regenerated sorbent and a desorb effluent comprising a sulfur-based contaminant; and
introducing at least a portion of the desorb effluent into a pyrolysis zone in the steam cracker.

5. The process of claim 4 , wherein the regenerating gas comprises one or more C 1 -C 4 alkanes, wherein the regenerating gas comprises <5 mol % of any alkenes, and wherein the regenerating gas is recovered from the upgraded combined gas.

6. The process of claim 1 , wherein the combined gas comprises water vapor, and wherein removing the at least a portion of the one or more impurities from the combined gas comprises removing at least a portion of the water vapor to produce a dried combined gas.

7. The process of claim 1 , wherein the refinery gas is recovered from an upgrading process comprising at least one of: fluid catalytic cracking, coking, hydrocracking, hydrotreating, isomerization, reforming, decoking, hydrocarbon combustion, and hydrocarbon distillation.

8. The process of claim 1 , further comprising:
recovering an alkane feed comprising at least one of ethane and propane from the upgraded combined gas; and
introducing at least a portion of the alkane feed to a pyrolysis zone in the steam cracker.

9. The process of claim 1 , further comprising pre-treating the refinery gas to remove at least a portion of one or more impurities comprising at least one of: molecular nitrogen, a nitrogen oxide, and molecular oxygen to produce a pre-treated refinery gas, wherein the pre-treated refinery gas is introduced into the selected compressor stage to produce the combined gas.

10. A process for removing contaminants from a refinery gas, comprising:
recovering a refinery gas from a refinery facility;
pre-treating the refinery gas to remove at least a portion of one or more first impurities comprising at least one of: molecular nitrogen, a nitrogen oxide, and molecular oxygen to produce a pre-treated refinery gas;
recovering a process gas comprising ethylene and propylene from a steam cracker effluent in a steam cracker facility;
compressing the process gas in a plurality of compressor stages to produce a compressed process gas;
determining a pressure, a composition, or a pressure and a composition of the pre-treated refinery gas;
selecting a location in the steam cracker facility for combining at least a portion of the pre-treated refinery gas with the compressed process gas using the pressure, the composition, or the pressure and the composition of the pre-treated refinery gas, wherein the selected location is a compressor stage in the plurality of compressor stages located after a first compressor stage and before a last compressor stage of the plurality of compressor stages;
adding at least a portion of the pre-treated refinery gas to the process gas at the selected location to produce a combined gas comprising the process gas and the refinery gas; and
removing at least a portion of one or more second impurities from the combined gas in the steam cracker facility to produce an upgraded combined gas lean in the one or more second impurities.

11. The process of claim 10 , further comprising recovering a tail gas and a C 2+ gas from the pre-treated refinery gas, wherein the tail gas comprises at least one of molecular hydrogen and methane, and wherein the C 2+ gas is added to the process gas at the selected location.

12. The process of claim 11 , further comprising:
introducing at least a portion of the tail gas and an oxidant into a combustor in a steam cracker located in the steam cracker facility;
combusting the tail gas to produce heat and a combustion effluent; and
transferring at least a portion of the heat to a radiant section of the steam cracker.

13. The process of claim 10 , wherein the one or more first impurities further comprises at least one of: ammonia, water, and mercury, and wherein pre-treating the refinery gas further comprises removing at least a portion any ammonia, at least a portion of any water, and at least a portion of any mercury therefrom to produce the pre-treated refinery gas.

14. The process of claim 10 , wherein the refinery gas comprises at least one of the nitrogen oxide and the molecular oxygen, and wherein pre-treating the refinery gas comprises contacting the refinery gas with a catalyst in the presence of molecular hydrogen under conditions sufficient to convert at least a portion of any nitrogen oxide to ammonia and to convert at least a portion of any molecular oxygen to water.

15. The process of claim 10 , wherein the refinery gas is recovered from an upgrading process comprising at least one of: fluid catalytic cracking, coking, hydrocracking, hydrotreating, isomerization, reforming, decoking, hydrocarbon combustion, and hydrocarbon distillation.

16. A process for removing contaminants from a refinery gas, comprising:
recovering a refinery gas comprising one or more C 1 -C 5 hydrocarbons and carbonyl sulfide from a refinery facility;
contacting the refinery gas with a sorbent under conditions sufficient to cause at least a portion of the carbonyl sulfide to sorb onto the sorbent to produce a pre-treated refinery gas lean in carbonyl sulfide and a sorbent rich in carbonyl sulfide;
contacting the sorbent rich in carbonyl sulfide with a regenerating gas to produce a regenerated sorbent and a desorb effluent comprising a sulfur-based contaminant;
introducing at least a por

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Lawrence Selma S
• Nierode Mark A
• Smith Rodney S

Classifications

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G55/04

  including at least one thermal cracking step · CPC title

• C07C7/12

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title

• C10G9/36

  with heated gases or vapours · CPC title

• C07C7/09 Primary

  by fractional condensation · CPC title