Armor plating made of fine-grain boron carbide and silicon carbide

Patent metadata

Field	Value
Publication number	US-12435006-B2
Application number	US-202017787048-A
Country	US
Kind code	B2
Filing date	Dec 18, 2020
Priority date	Dec 20, 2019
Publication date	Oct 7, 2025
Grant date	Oct 7, 2025

Abstract

An antiballistic armor-plating component, includes a ceramic body made of a material comprising, as percentages by volume, between 35% and 55% of silicon carbide, between 20% and 50% of boron carbide, between 15% and 35% of a metallic silicon phase or of a metallic phase including silicon.

First claim

The invention claimed is:

1. An antiballistic armor-plating component, comprising a ceramic body made of a material comprising, as percentages by volume:
between 35% and 55% of silicon carbide,
between 20% and 50% of boron carbide,
between 15% and 35% of a metallic silicon phase or of a metallic phase comprising silicon,

and wherein, as percentages by volume of said material:
the boron carbide grains with an equivalent diameter greater than 30 micrometers represent less than 5%,
the boron carbide grains with an equivalent diameter less than 5 micrometers represent more than 15% and less than 35%,
the silicon carbide grains with an equivalent diameter greater than 30 micrometers represent less than 5%, and
the silicon carbide grains with an equivalent diameter greater than or equal to 5 micrometers and less than or equal to 30 micrometers represent between 35% and 55%.

2. The armor-plating component as claimed in claim 1 , wherein said ceramic body is monolithic and has an impact area greater than 100 cm 2 , a thickness greater than 3 mm and a bulk density less than 3.0 g/cm 3 .

3. The armor-plating component as claimed in claim 1 , wherein the silicon carbide grains with an equivalent diameter greater than or equal to 5 micrometers and less than 30 micrometers represent more than 40% by volume of said material.

4. The armor-plating component as claimed in claim 1 , wherein the boron carbide grains with an equivalent diameter less than 5 micrometers represent between 20% and 30% by volume of said material.

5. The armor-plating component as claimed in claim 1 , wherein the boron carbide grains with an equivalent diameter greater than or equal to 5 micrometers represent less than 10% by volume of said material.

6. The armor-plating component as claimed in claim 1 , wherein the boron carbide grains with an equivalent diameter between 5 and 30 micrometers, limits included, represent less than 10% by volume of said material.

7. The armor-plating component as claimed in claim 1 , wherein the silicon carbide grains with an equivalent diameter less than 5 micrometers represent less than 10% by volume of said material.

8. The armor-plating component as claimed in claim 1 , wherein the free carbon content is less than 1% by volume of said material.

9. The armor-plating component as claimed in claim 1 , comprising:
boron carbide grains and
silicon carbide grains and
a matrix binding said grains,
said matrix comprising at least a metallic silicon phase or a metallic phase comprising silicon.

10. The armor-plating component as claimed in claim 1 , wherein the silicon carbide grains with an equivalent diameter greater than or equal to 5 micrometers are in alpha (α) crystallographic form.

11. The armor-plating component as claimed in claim 1 , wherein the proportion by volume of B 4 C represents less than 20% of the boron carbide content of said material.

12. The armor-plating component as claimed in claim 1 , wherein the boron carbide is present in the form of a B 12 (B,C,Si) 3 phase.

13. The armor-plating component as claimed in claim 1 , wherein the boron carbide, the silicon carbide and the metallic silicon or the metallic phase comprising silicon together represent more than 75%, by volume, of said material.

14. The armor-plating component as claimed in claim 1 , wherein, by volume of said material:
the silicon carbide content of said material is greater than 35% and less than 55%,
the boron carbide content is greater than 20% and less than 50%,
the content of metallic silicon or of the metallic phase comprising silicon is greater than 15% and less than 35%,
the boron carbide grains with an equivalent diameter greater than 30 micrometers represent less than 5%,
the boron carbide grains with an equivalent diameter less than 5 micrometers represent more than 15% and less than 35%,
the silicon carbide grains with an equivalent diameter greater than or equal to 5 micrometers and less than or equal to 30 micrometers represent between 35% and 55%,
the silicon carbide grains with an equivalent diameter greater than 30 micrometers represent less than 5%,
more than 90% of the grains, by volume of said material, have an equivalent diameter less than 30 micrometers,
more than 80% of grains with an equivalent diameter less than 5 micrometers are boron carbide grains,
more than 80% of grains with an equivalent diameter greater than or equal to 5 micrometers are silicon carbide (SiC) grains.

15. The armor-plating component as claimed in claim 1 , wherein the ceramic body has a mass-to-area ratio, or surface density, measured in kg/m 2 , of less than 100.

16. The armor-plating component as claimed in claim 1 , wherein the ceramic body is chosen from a plate, a chest protector, a helmet, a bodywork element of a vehicle, a tube.

17. The armor-plating component as claimed in claim 1 , comprising a ceramic body made of a material, provided on an inner face thereof or face opposite the impact face with an energy-dissipating back coating, made of a material of lower hardness than that of the material constituting the ceramic body, wherein the material constituting the back coating is chosen from polyethylenes PE, glass or carbon fibers, aramids, metals or alloys thereof or steel.

18. The armor-plating component as claimed in claim 17 , wherein the ceramic body-back coating assembly is surrounded by an envelope of a confining material.

19. The armor-plating component as claimed in claim 18 , wherein the material constituting the envelope is chosen from polyethylenes PE, glass or carbon fibers, aramids, metals or steel.

20. A process for manufacturing the ceramic body of the armor-plating component as claimed in claim 1 , the process comprising:
a) preparing a starting feedstock including:
at least one powder of boron carbide particles, of which the median diameter of the particles is between 0.1 and 10 micrometers,
a powder of silicon carbide particles, of which the median diameter of particles is between 5 and 30 micrometers,
a carbon precursor of which the median diameter is less than 1 micrometer,
an aqueous solvent,
optionally shaping additives,

b) shaping the starting feedstock into the form of a preform;
c) removal from the mold after setting or drying;
d) optionally, drying the preform, until a residual moisture content is comprised between 0 and 0.5% by weight;
e) loading the preform, in contact with a source of silicon or a silicon alloy into a furnace;
f) firing the preform under an inert atmosphere or under vacuum so as to infiltrate the preform with the source of molten silicon and consolidate it.

21. A method comprising providing an antiballistic protection for a person or for a land, sea or air vehicle or for a fixed installation manufactured with an antiballistic armor-plating component as claimed in claim 1 .

22. The armor-plating component as claimed in claim 1 , wherein the metallic silicon phase and the metallic phase comprising silicon each comprise more than 80% of silicon atoms.

23. The armor-plating component as claimed in claim 22 , wherein the metallic silicon phase and the metallic phase comprising silicon each comprise more than 90% of silicon atoms.

Assignees

• Saint Gobain Ct Recherches

Inventors

• Sant Jérôme
• Brulin Jérôme

Classifications

• F41H5/0414

  Layered armour containing ceramic material · CPC title

• C04B2235/786

  Micrometer sized grains, i.e. from 1 to 100 micron · CPC title

• C04B2235/77

  Density · CPC title

• C04B2235/6581

  Total pressure below 1 atmosphere, e.g. vacuum · CPC title

• C04B2235/616

  Liquid infiltration of green bodies or pre-forms · CPC title