Reducing agent and method for producing gas

Patent metadata

Field	Value
Publication number	US-12434226-B2
Application number	US-202117914042-A
Country	US
Kind code	B2
Filing date	Mar 3, 2021
Priority date	Mar 25, 2020
Publication date	Oct 7, 2025
Grant date	Oct 7, 2025

Abstract

A reducing agent for use in production of a product gas containing carbon monoxide, the reducing agent being brought into contact with a raw material gas containing carbon dioxide to reduce the carbon dioxide to produce the product gas; the reducing agent containing a composite metal oxide represented by Ce 1-x (M) x O y , where M is a metal element with an ionic radius smaller than an ionic radius of Ce with an identical valence number and an identical coordination number, x represents a positive real number, and y represents a real number from 1 to 4. The reducing agent that has a high conversion efficiency of carbon dioxide to carbon monoxide, and can be used, for example, in a chemical looping method, and a method for producing a gas using such a reducing agent.

First claim

The invention claimed is:

1. A reducing agent for use in production of a product gas containing carbon monoxide, the reducing agent being brought into contact with a raw material gas containing carbon dioxide to reduce the carbon dioxide to produce the product gas,
the reducing agent comprising:
a composite metal oxide represented by Ce 1-x (M) x O y , where M is a metal element with an ionic radius smaller than an ionic radius of Ce with an identical valence number and an identical coordination number, x represents a positive real number, and y represents a real number from 1 to 4, and
a support supporting the composite metal oxide, the support having oxygen ionic conductivity and having a function as an oxygen carrier, wherein the support comprises at least one selected from the group consisting of vanadium (V), manganese (Mn), molybdenum (Mo), yttrium (Y), chromium (Cr), lanthanum (La), cobalt (Co), nickel (Ni), copper (Cu), tungsten (W), and niobium (Nb).

2. The reducing agent according to claim 1 , wherein a difference between the ionic radius of Ce and the ionic radius of the metal element M is more than 0 μm and 47 μm or less when the valence number is 3 and the coordination number is 6, and more than 0 μm and 24 μm or less when the valence number is 4 and the coordination number is 8.

3. The reducing agent according to claim 2 , wherein the composite metal oxide has oxygen ionic conductivity and has a function as an oxygen carrier.

4. The reducing agent according to claim 2 , wherein the metal element M is at least one selected from the group consisting of samarium (Sm), hafnium (Hf), yttrium (Y), gadolinium (Gd), niobium (Nb), praseodymium (Pr), titanium (Ti), neodymium (Nd), europium (Eu), silver (Ag), gold (Au), and scandium (Sc).

5. The reducing agent according to claim 2 , wherein the x is from 0.05 to 0.4.

6. The reducing agent according to claim 2 , wherein an amount of the composite metal oxide is 60 parts by mass or greater per 100 parts by mass of the reducing agent.

7. The reducing agent according to claim 1 , wherein the metal element M is at least one selected from the group consisting of samarium (Sm), zirconium (Zr), and hafnium (Hf).

8. The reducing agent according to claim 1 , wherein an amount of the composite metal oxide is 50 parts by mass or less per 100 parts by mass of the reducing agent.

9. The reducing agent according to claim 1 , wherein the reducing agent is used in production of a product gas containing carbon monoxide, the reducing agent being brought into contact with a raw material gas containing carbon dioxide to reduce the carbon dioxide to produce the product gas.

10. The reducing agent according to claim 9 , wherein the oxidized reducing agent is reduced by being brought into contact with a reducing gas containing hydrogen.

11. The reducing agent according to claim 10 , wherein the reducing agent is used separately in reaction steps of a reduction reaction of carbon dioxide and a reduction reaction of the oxidized reducing agent.

12. A method for producing a gas, the method comprising reducing carbon dioxide by bringing the reducing agent described in claim 1 into contact with a raw material gas containing the carbon dioxide, to produce a product gas containing carbon monoxide.

Assignees

• Sekisui Chemical Co Ltd

Inventors

• Takizawa Koji
• MUKHERJEE Fiona
• Shinmei Kenichi
• YAGIHASHI Noritoshi
• Sakurai Risa

Classifications

• C01F17/32

  oxide or hydroxide being the only anion, e.g. NaCeO2 or MgxCayEuO · CPC title

• B01J38/10

  using elemental hydrogen · CPC title

• B01J23/92

  of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 · CPC title

• B01J23/745

  Iron · CPC title

• C01B32/40 Primary

  Carbon monoxide · CPC title