Process for capturing CO2 and process for continuously regenerating solvent

Patent metadata

Field	Value
Publication number	US-12434185-B2
Application number	US-201917414647-A
Country	US
Kind code	B2
Filing date	Dec 17, 2019
Priority date	Dec 20, 2018
Publication date	Oct 7, 2025
Grant date	Oct 7, 2025

Abstract

The present invention describes a process for capturing CO2 using an optimized mixture of water and alcohols with alkali hydroxides, such as KOH and NaOH, for absorption of CO2 from gaseous mixtures. The process shows high efficiency and low volatility and corrosivity rate of the solvent, in addition to allowing cost reduction for installation and maintenance of reactors and reducing solvent loss. The present invention also describes a process for regenerating solvent or its reuse, carried out by chemical precipitation, continuously and not in batch, through the reaction with alkaline earth oxides, such as CaO and MgO, and/or alkaline earth hydroxides, such as Ca(OH)2 and Mg(OH)2, for the formation of carbonates, such as CaCO3 and MgCO3, which can be discarded in nature without any environmental issue or can be used commercially in industry or agriculture.

First claim

The invention claimed is:

1. A process for capturing CO 2 , characterized by using alkaline chemical solvent, water, and alcohols, comprising the following steps:
(a) preparing a hydroalcoholic solution consisting of water and at least one alcohol at a concentration of 2.5%-75% v/v;
(b) preparing a mixture consisting of the hydroalcoholic solution obtained in step (a) and at least one alkali hydroxide, wherein the concentration of alkali hydroxide in the mixture is 0.5 mol/L to 2 mol/L;
(c) placing the mixture obtained in step (b) in direct contact with a gas mixture containing CO 2 , thus promoting the separation of CO 2 from the gas mixture containing CO 2 .

2. The process for capturing CO 2 according to claim 1 , wherein in step (a the at least one alcohol is selected from the group consisting of methanol, ethanol, isopropanol, tert-butanol, glycerol, and ethylene glycol.

3. The process for capturing according to claim 1 , wherein in step (b) the at least one alkali hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide, and lithium hydroxide.

4. The process for capturing according to claim 1 , wherein the at least one alcohol in the hydroalcoholic solution is present at a concentration of 10% v/v.

5. The process for capturing according to claim 1 , wherein in step (b) the concentration of alkali hydroxide in the mixture is 1 mol/L.

6. The process for capturing according to claim 1 , wherein step (c) is performed between 10° C. and 85° C.

7. The process for capturing according to claim 1 , wherein the process is carried out in a chemical absorption reactor under pressure between 1 atm to 10 atm.

Assignees

• Univ Minas Gerais
• Petroleo Brasileiro Sa Petrobras
• Fund Amparo Pesquisa Estado Minas Gerais Fapemig
• Fca Fiat Chrysler Automoveis Brasil Ltda

Inventors

• Belchior Jadson Claudio
• Voga Pereira Geison
• De Carvalho Pinto Plinio Cesar
• Vieira Batista Thais
• Caffaro Vicentini Pedro
• Neves Loureiro Luciana

Classifications

• B01D2257/504

  Carbon dioxide · CPC title

• B01D2252/504

  Mixtures of two or more absorbents · CPC title

• B01D2252/202

  Alcohols or their derivatives · CPC title

• B01D2252/103

  Water · CPC title

• B01D2251/604

  Hydroxides · CPC title