Use of dispersion adhesives for foam bonding

Patent metadata

Field	Value
Publication number	US-12428583-B2
Application number	US-202017778884-A
Country	US
Kind code	B2
Filing date	Dec 3, 2020
Priority date	Dec 10, 2019
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

The invention relates to the use of an aqueous dispersion containing at least one polyurethane-polyurea polymer formed from (a) at least one difunctional polyester polyol having a number-average molecular weight of 400 to 5000 g/mol, (b) at least one difunctional polyol component having a number-average molecular weight of 762 to 399 g/mol, c) at least one diisocyanate and (d) at least one chain extender optionally having at least one ionic group, for the bonding of at least two substrates by application of the aqueous dispersion to at least one of the substrates to be bonded, subsequent drying of the dispersion present on the at least one substrate in order to obtain at least one adhesive layer, and contacting of the at least one adhesive layer with a further substrate or with an adhesive layer present on a further substrate at a pressure of from 0.1 to 5 bar(a) and a temperature of less than 40° C., wherein the polyurethane-polyurea polymer after the drying has a glass transition temperature Tg of from −65 to 10° C. and a melting point of from 40 to 80° C., to a corresponding process for joining at least two substrates, and to an adhesive composite obtained in this way and comprising at least two substrates and an adhesive layer present between every two substrates.

First claim

The invention claimed is:

1. A method for connecting at least two substrates, comprising:
(A) providing an aqueous dispersion comprising at least one polyurethane-polyurea polymer that after drying has a glass transition temperature Tg of −65 to 10° C. and a melting temperature of 40 to 80° C., formed from
(a) at least one difunctional polyester polyol having a number-average molecular weight of 400 to 5000 g/mol,
(b) at least one difunctional polyol component having a number-average molecular weight of 62 to 399 g/mol,
(c) at least one diisocyanate, and
(d) at least one chain extender, optionally containing at least one ionic group,

(B) applying the aqueous dispersion from step (A) to at least one of the substrates,
(C) drying the at least one dispersion present from step (B) so as to obtain at least one adhesive layer, and
(D) bringing the at least one adhesive layer into contact with a further substrate or with an adhesive layer present on a further substrate at a pressure of 0.2 to 3 bar (a) and a temperature of less than 40° C.;
wherein the polyurethane-polyurea polymer after drying has an enthalpy of fusion ≥ 5 J/g, as measured by DSC in accordance with DIN 65467 at a heating rate of 20 K/min.

2. The method as claimed in claim 1 , wherein component (a) comprises difunctional aliphatic polyester polyols based on succinic acid, methylsuccinic acid, glutaric acid, adipic acid, maleic acid, or a combination thereof and propane-1,3-diol, butane-1,4-diol, hexane-1,6-diol, or a combination thereof.

3. The method as claimed in claim 1 , wherein component (a) comprises difunctional aromatic polyester polyols (a) based on o-phthalic acid and/or o-phthalic anhydride and butane-1,4-diol and/or hexane-1,6-diol.

4. The method as claimed in claim 1 , wherein component (c) comprises tetramethylene diisocyanate, methylpentamethylene diisocyanate, hexamethylene diisocyanate, dodecamethylene diisocyanate, 1,4-diisocyanatocyclohexane, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane, 4,4′-diisocyanatodicyclohexylmethane, 4,4′-diisocyanato-2,2-dicyclohexylpropane, 4,4′-diisocyanatodicyclohexylmethane (H12MDI), tolylene 2,4-diisocyanate and/or tolylene 2,6-diisocyanate (TDI), diphenylmethane 2,2′-diisocyanate, diphenylmethane 2,4′-diisocyanate and/or diphenylmethane 4,4′-diisocyanate (MDI), or mixtures thereof.

5. The method as claimed in claim 1 , wherein the aqueous polyurethane-polyurea dispersion has a solids content of from 20% to 60% by weight.

6. The method as claimed in claim 1 , wherein—in each case based on the weight of solid—≥30% by weight of the at least one polyurethane-polyurea polymer is present on the substrate surface to a maximum penetration depth of not more than 1 mm.

7. The method as claimed in claim 1 , wherein the aqueous dispersion is applied in an amount (wet) of 20 to 180 g/m 2 .

8. The method as claimed in claim 1 , wherein the aqueous dispersion is applied in an amount (solid) of 10 to 90 g/m 2 .

9. The method as claimed in claim 1 , wherein at least one substrate is a foam substrate or a porous material.

10. The method as claimed in claim 1 , wherein component (d) comprises amine chain extenders having at least one ionic group.

11. An adhesive composite comprising at least two substrates and an adhesive layer present between in each case two substrates, obtained by the method as claimed in claim 1 .

12. The method of claim 9 , wherein the foam substrate or the porous material has a bulk density of less than 200 g/l.

13. The method of claim 10 , wherein component (d) comprises a diamino compound additionally bearing a sulfonate and/or a carboxylate group.

14. The method of claim 10 , wherein component (d) comprises a sodium or potassium salt of N-(2-aminoethyl)-2-aminoethanesulfonic acid, of N-(3-aminopropyl)-2-aminoethanesulfonic acid, of N-(3-aminopropyl)-3-aminopropanesulfonic acid, of N-(2-aminoethyl)-3-aminopropanesulfonic acid, of an analogous carboxylic acid, or mixtures thereof.

15. The method of claim 9 , wherein the substrate is a polyurethane foam substrate.

16. The method of claim 1 , wherein the pressure in step (D) is 0.25 to 2 bar (a).

17. The method of claim 1 , wherein the pressure in step (D) is 0.3 to 1.5 bar (a).

18. The method of claim 1 , wherein the polyurethane-polyurea polymer after drying has an enthalpy of fusion ≥10 J/g, as measured by DSC in accordance with DIN 65467 at a heating rate of 20 K/min.

19. The method of claim 1 , wherein the polyurethane-polyurea polymer after drying has an enthalpy of fusion ≥20 J/g, as measured by DSC in accordance with DIN 65467 at a heating rate of 20 K/min.

20. The method of claim 1 , wherein the polyurethane-polyurea polymer after drying has an enthalpy of fusion ≥40 J/g, as measured by DSC in accordance with DIN 65467 at a heating rate of 20 K/min.

Assignees

• Covestro Deutschland Ag

Inventors

• Achten Dirk
• Arndt Wolfgang
• Liberati Robert
• Thiebes Christoph
• Kueker Peter
• Kraus Harald

Classifications

• C08G18/4238

  derived from dicarboxylic acids and dialcohols · CPC title

• C08G18/3206

  aliphatic · CPC title

• C08G18/0804

  Manufacture of polymers containing ionic or ionogenic groups · CPC title

• B32B2266/0278

  Polyurethane · CPC title

• B32B27/40

  comprising polyurethanes · CPC title