Water-based inks for thermoforming applications

Patent metadata

Field	Value
Publication number	US-12428570-B2
Application number	US-201615743009-A
Country	US
Kind code	B2
Filing date	Jul 6, 2016
Priority date	Jul 16, 2015
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

The present invention provides water-based thermoformable printing inks and coatings. The inks and coatings of the invention comprise one or more acrylic emulsions, one or more styrene acrylic emulsions, an adhesion promoter, and water.

First claim

What is claimed is:

1. A thermoformable water-based printing ink or coating composition comprising:
a) 1 wt % to 60 wt % one or more acrylic emulsions;
b) 5 wt % to 15 wt % one or more styrene acrylic emulsions;
c) 0.1 wt % to 10 wt % adhesion promoter;
d) 0 wt % to 5 wt % one or more oxygen-containing water-tolerant solvents, wherein the amount of oxygen-containing water-tolerant solvents is the total of all oxygen-containing water-tolerant solvents combined; and
e) 1 wt % to 20 wt % water; and
f) one or more silicones, in an amount of 0.1 wt % to 5 wt %; wherein the one or more silicones are selected from the group consisting of octamethylcyclotetrasiloxane, polydimethylsiloxane, and combinations thereof.

2. The thermoformable water-based printing ink or coating of claim 1 , comprising 5 wt % to 55 wt % of the one or more acrylic emulsions.

3. The thermoformable water-based printing ink or coating of claim 1 , comprising 5 wt % to 10 wt % of the one or more styrene acrylic emulsions.

4. The thermoformable water-based printing ink or coating of claim 1 , comprising 0.5 wt % to 8 wt % of the adhesion promoter.

5. The thermoformable water-based printing ink or coating of claim 1 , wherein the adhesion promoter is selected from the group consisting of polyolefins, maleated polyolefins, sulfonamides, organic titanates, and combinations thereof.

6. The thermoformable water-based printing ink or coating of claim 1 , further comprising a crosslinker, in an amount of 0.1 wt % to 5 wt %.

7. The thermoformable water-based printing ink or coating of claim 6 , wherein the crosslinker is selected from the group consisting of zinc oxides, zirconium crosslinkers, and combinations thereof.

8. The thermoformable water-based printing ink or coating of claim 1 , further comprising a colorant, in an amount of 0.1 wt % to 70 wt %.

9. The thermoformable water-based printing ink or coating of claim 8 , wherein the colorant is in the form of an acrylic dispersion.

10. The thermoformable water-based printing ink or coating of claim 1 , further comprising a wax, in an amount of 0.1 wt % to 5 wt %.

11. The thermoformable water-based printing ink or coating of claim 10 , wherein the wax is selected from the group consisting of amide wax, erucamide wax, polypropylene wax, paraffin wax, polyethylene wax, polytetrafluoroethylene wax, carnauba wax, and combinations thereof.

12. The thermoformable water-based printing ink or coating of claim 1 , further comprising one or more additives independently selected from the group consisting of defoamers, stabilizers, rheological modifiers, plasticizers, light stabilizers, de-gassing additives, flow promoters, antioxidants, surfactants, and combinations thereof; wherein the one or more additives are present in an amount of 0.1 wt % to 5 wt %.

13. The thermoformable water-based printing ink or coating of claim 1 , wherein the thermoformable water-based printing ink or coating is suitable for use in a flexographic, gravure, lithographic, or screen printing process.

14. The thermoformable water-based printing ink or coating of claim 1 , further comprising polytetrafluoroethylene powder.

15. The thermoformable water-based printing ink or coating of claim 14 , further comprising a silicone compound.

16. The thermoformable water-based printing ink or coating of claim 15 , further comprising zinc oxide crosslinker.

17. The thermoformable water-based printing ink or coating of claim 16 , further comprising defoamer.

Assignees

• Sun Chemical Corp

Inventors

• Lahr Alexander
• Marshall Bruce

Classifications

• C09D133/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C09D125/06

  Polystyrene · CPC title

• C09D11/037

  characterised by the pigment · CPC title

• C09D11/023

  Emulsion inks · CPC title

• C08L83/04

  Polysiloxanes · CPC title