Reinforced polypropylene material and preparation method thereof

Patent metadata

Field	Value
Publication number	US-12428528-B2
Application number	US-202017916800-A
Country	US
Kind code	B2
Filing date	Nov 19, 2020
Priority date	Apr 20, 2020
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

Disclosed is a reinforced polypropylene material, comprising in parts by weight: a, 10-90 parts of polypropylene resin, b, 0.5-25 parts of compatilizer, c, 5-60 parts of reinforced fibers and d, 0.1-20 parts of low-hardness toner. The reinforced fibers comprise a component I, a component II and a component III, where the component I is composed of reinforced fibers with a length of 0.1-0.6 mm and accounts for 35-50% of number of reinforced fibers, the component II is composed of reinforced fibers with a length of 0.7-1.3 mm and accounts for 35-45% of number of reinforced fibers, and component III is composed of reinforced fibers with a length of 1.4-2.0 mm and accounts for 5-20% of number of reinforced fibers. The present invention, by adjusting the length and the content distribution of the reinforced fibers in the reinforced polypropylene material formula, greatly preserves the maintained length of the reinforced fibers in the reinforced polypropylene material, and by combining a specific amount of low hardness toner and a specific amount of compatilizer, the low-temperature resilience and the long-term weatherability performance of the resulting reinforced polypropylene material are significantly improved.

First claim

What is claimed is:

1. A reinforced polypropylene material, wherein the material comprises the following components in parts by weight:
a, 10 to 90 parts of a polypropylene resin;
b, 0.5 to 25 parts of a compatibilizer;
c, 5 to 60 parts of reinforcing fibers;
d, 0.1 to 20 parts of low-hardness colorant powder;
wherein the reinforcing fibers comprise a component I, a component II and a component III:
the component I is composed of reinforcing fibers with a length of 0.1 mm to 0.6 mm, accounting for 35% to 50% of the number of reinforcing fibers;
the component II is composed of reinforcing fibers with a length of 0.7 mm to 1.3 mm, accounting for 35% to 45% of the number of reinforcing fibers; and
the component III is composed of reinforcing fibers with a length of 1.4 mm to 2.0 mm, accounting for 5% to 20% of the number of reinforcing fibers,
wherein the low-hardness colorant powder has a Moh's hardness less than 6.

2. The reinforced polypropylene material according to claim 1 , wherein the component I in the reinforcing fibers accounts for 38% to 45% of the number of reinforcing fibers.

3. The reinforced polypropylene material according to claim 1 , wherein the component II in the reinforcing fibers accounts for 37% to 42% of the number of reinforcing fibers.

4. The reinforced polypropylene material according to claim 1 , wherein the component III in the reinforcing fibers accounts for 8% to 15% of the number of reinforcing fibers.

5. The reinforced polypropylene material according to claim 1 , wherein the reinforcing fibers are selected from the group consisting of one or more of glass fibers, quartz fibers, and basalt fibers; the reinforcing fibers have a diameter of 5 to 20 microns.

6. The reinforced polypropylene material according to claim 1 , wherein the low-hardness colorant powder has the Moh's hardness of 0.1 to 4.

7. The reinforced polypropylene material according to claim 1 , wherein the low-hardness colorant powder is selected from the group consisting of one or more of zinc white, zinc sulfide, barium white, antimony white, lithopone, lead white, calcium carbonate, talc powder, kaolin, barium sulfate, and titanium dioxide.

8. The reinforced polypropylene material according to claim 1 , wherein the polypropylene resin is selected from the group consisting of one or more of homo-polypropylene (PP-H), block copolymerized polypropylene (PP-B) and random copolymerized polypropylene (PP-R).

9. The reinforced polypropylene material according to claim 1 , wherein the compatibilizer is a graft polymer of polar monomer and polypropylene, wherein the polar monomer is selected from the group consisting of one or a mixture of derivatives of maleic anhydrides, acrylic acids and acrylates.

10. A preparation method for the reinforced polypropylene material according to claim 1 , wherein the method comprises the following steps:
weighing each component according to the formula contents, and uniformly mixing all components except for the reinforcing fibers to form a mixture, then adding the mixture to a primary feeding system of a double-screw extruder; meanwhile adding the reinforcing fibers to a side feeding system of the double-screw extruder, and then melt-blending, extruding and pelleting by the double-screw extruder to obtain the reinforced polypropylene material.

11. The preparation method for the reinforced polypropylene material according to claim 10 , wherein feeding position of the side feeding system of the double-screw extruder can be adjusted, wherein the reinforcing fibers can be added to the screw at the first section to the tenth section, and added after the die head of the extruder, followed by directly combining with a polypropylene melt.

12. The preparation method for the reinforced polypropylene material according to claim 10 , wherein temperature of the first section to the second section of the double-screw extruder ranges from 120° C. to 160° C., temperature of the third section to the fifth section ranges from 180° C. to 300° C., temperature of the fifth section to the tenth section ranges from 180° C. to 300° C., and a screw speed is 300 rpm to 600 rpm.

13. A preparation method for the reinforced polypropylene material according to claim 2 , wherein the method comprises the following steps:
weighing each component according to the formula contents, and uniformly mixing all components except for the reinforcing fibers to form a mixture, then adding the mixture to a primary feeding system of a double-screw extruder; meanwhile adding the reinforcing fibers to a side feeding system of the double-screw extruder, and then melt-blending, extruding and pelleting by the double-screw extruder to obtain the reinforced polypropylene material.

14. A preparation method for the reinforced polypropylene material according to claim 3 , wherein the method comprises the following steps:
weighing each component according to the formula contents, and uniformly mixing all components except for the reinforcing fibers to form a mixture, then adding the mixture to a primary feeding system of a double-screw extruder; meanwhile adding the reinforcing fibers to a side feeding system of the double-screw extruder, and then melt-blending, extruding and pelleting by the double-screw extruder to obtain the reinforced polypropylene material.

15. A preparation method for the reinforced polypropylene material according to claim 4 , wherein the method comprises the following steps:
weighing each component according to the formula contents, and uniformly mixing all components except for the reinforcing fibers to form a mixture, then adding the mixture to a primary feeding system of a double-screw extruder; meanwhile adding the reinforcing fibers to a side feeding system of the double-screw extruder, and then melt-blending, extruding and pelleting by the double-screw extruder to obtain the reinforced polypropylene material.

16. A preparation method for the reinforced polypropylene material according to claim 5 , wherein the method comprises the following steps:
weighing each component according to the formula contents, and uniformly mixing all components except for the reinforcing fibers to form a mixture, then adding the mixture to a primary feeding system of a double-screw extruder; meanwhile adding the reinforcing fibers to a side feeding system of the double-screw extruder, and then melt-blending, extruding and pelleting by the double-screw extruder to obtain the reinforced polypropylene material.

17. A preparation method for the reinforced polypropylene material according to claim 6 , wherein the method comprises the following steps:
weighing each component according to the formula contents, and uniformly mixing all components except for the reinforcing fibers to form a mixture, then adding the mixture to a primary feeding system of a double-screw extruder; meanwhile adding the reinforcing fibers to a side feeding system of the double-screw extruder, and then melt-blending, extruding and pelleting by the double-screw extruder to obtain the reinforced polypropylene material.

18. A preparation method for the reinforced polypropylene material according to claim 7 , wherein the method comprises the following steps:
weighing each component according to the formula contents, and uniformly mixing all components except for the reinforcing fibers to form a mixture, then adding the mixture to a primary feeding system of a double-screw extruder; meanwhile adding the reinforcing fibers to a side feeding system of the double-screw extruder, and then melt-blending, extruding

Assignees

• Kingfa Science & Technology Co

Inventors

• Lu Zhanquan
• Huang Xianbo
• Ye Nanbiao
• Cheng Shuwen
• Guan Annan
• Liu Lewen
• Yang Xiaoyun

Classifications

• C08K2003/2296

  of zinc · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title

• C08K7/14

  Glass · CPC title

• C08K7/10

  Silicon-containing compounds · CPC title

• C08K3/2279

  of antimony · CPC title