Method and an apparatus for forming a lignin fraction, a lignin composition and its use

Patent metadata

Field	Value
Publication number	US-12428440-B2
Application number	US-202117359513-A
Country	US
Kind code	B2
Filing date	Jun 26, 2021
Priority date	May 29, 2015
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

The invention relates to a method and an apparatus for forming a lignin fraction from crude lignin which has been processed by means of a treatment step selected from enzymatic treatment, treatment with ionic liquid and their combinations. The method comprises treating the crude lignin ( 1 ) by a lignin liberation in at least one lignin liberation step ( 3 ), and separating a lignin fraction ( 6 ) in at least one separation step ( 5 ). Further, the invention relates to a lignin composition and its use.

First claim

The invention claimed is:

1. A method for forming a lignin fraction from crude lignin which has been processed using enzymatic treatment, treatment with ionic liquid, or the combination thereof, wherein the method comprises:
treating the crude lignin by a lignin liberation in at least one lignin liberation step to form two solid phases, the crude lignin having a glucan content of 3-70% by weight, analyzed as glucose; and
separating a lignin fraction and a lignocellulose fraction in at least one solid-solid separation step after the lignin liberation.

2. The method according to claim 1 , wherein the crude lignin is liberated using a hydrothermal treatment.

3. The method according to claim 1 , wherein the crude lignin is liberated using a dilute acid hydrolysis.

4. The method according to claim 1 , wherein temperature is 130-400° C. during the lignin liberation.

5. The method according to claim 1 , wherein below 70% of glucan is dissolved during the lignin liberation.

6. The method according to claim 1 , further comprising treating the crude lignin by dewatering, washing, filtrating, centrifuging, or a combination thereof in at least one washing and separation step before the lignin liberation.

7. The method according to claim 1 , further comprising separating a lignocellulose fraction in at least one separation step.

8. The method according to claim 7 , further comprising circulating at least a part of the lignocellulose fraction from the separation step to the enzymatic treatment or treatment with ionic liquid.

9. The method according to claim 1 , wherein a stabilizing chemical is added into the treated crude lignin in connection with the at least one separation step.

10. The method according to claim 9 , wherein the stabilizing chemical includes carboxymethyl cellulose (CMC) or guar gum.

11. The method of claim 1 , further comprising forming a lignin composition including the lignin fraction.

12. The method of claim 11 , wherein the lignin composition is configured to be used as a component in a product selected from the group consisting of activated carbon, carbon fiber, lignin composite, binder material, polymers, resins, phenolic component, dispersion agent, feed, food or their combination.

13. The method of claim 11 , wherein the lignin composition is configured to be used as an adsorbent for oil, hydrocarbon composition, or heavy metals.

14. The method of claim 1 , further comprising forming a lignocellulose composition including a lignocellulose fraction.

15. The method of claim 1 , wherein the crude lignin has a glucan content is 5-60% by weight.

16. The method of claim 1 , wherein the crude lignin has a glucan content is 10-60% by weight.

Assignees

• Upm Kymmene Corp

Inventors

• Miettinen Mauno

Classifications

• C08H6/00

  Macromolecular compounds derived from lignin, e.g. tannins, humic acids · CPC title

• B01J31/0277 Primary

  comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature · CPC title

• B01J31/003

  containing enzymes · CPC title

• B01J37/36

  Biochemical methods · CPC title

• C12P7/00

  Preparation of oxygen-containing organic compounds · CPC title