Preparation method of Ni-Rich ternary precursor and use thereof

Patent metadata

Field	Value
Publication number	US-12428312-B2
Application number	US-202318374003-A
Country	US
Kind code	B2
Filing date	Sep 28, 2023
Priority date	Apr 1, 2021
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

The present disclosure discloses a preparation method of a Ni-Rich ternary precursor and use thereof. The preparation method includes the following steps: under specified conditions, feeding an alkali liquor and a metal salt solution simultaneously for a precipitation reaction to obtain particles with D50 of 7.0 μm to 15.0 μm; continuously feeding a seed crystal, and after D10 of the particles is adjusted to 2.0 μm to 7.0 μm, stopping feeding the seed crystal; continuously feeding the alkali liquor and the metal salt solution, and collecting an overflow material; and when a particle size grows to D50 of 7.0 μm to 15.0 μm once again, repeating the above operation of adding a seed crystal, and continuously collecting an overflow material; and washing, drying, and sieving the collected materials to obtain the Ni-Rich ternary precursor.

First claim

The invention claimed is:

1. A preparation method of a Ni-Rich ternary precursor, comprising the following steps:
S1: preparing a nickel salt, a cobalt salt, and a manganese salt into a metal salt solution;
S2: in an inert atmosphere, heating and feeding ammonia water, feeding an alkali liquor to adjust a pH, and feeding the alkali liquor and the metal salt solution simultaneously for a precipitation reaction to obtain particles with D 50 of 7.0 μm to 15.0 μm;
S3: continuously feeding a seed crystal, and after D 10 of the particles is adjusted to 2.0 μm to 7.0 μm, stopping feeding the seed crystal; continuously feeding the alkali liquor and the metal salt solution, and collecting an overflow material; and when a particle size grows to D 50 of 7.0 μm to 15.0 μm once again, repeating an operation of feeding the seed crystal, and continuously collecting an overflow material; and
S4: washing, drying, and sieving all of the overflow materials collected in step S3 to obtain the Ni-Rich ternary precursor;
in S2, the pH is adjusted to 11.0 to 13.0, after the pH is adjusted, the seed crystal is first added, and then the alkali liquor and the metal salt solution are simultaneously fed for the precipitation reaction; and the seed crystal has a particle size of 2.0 μm to 7.0 μm;
in S4, the Ni-Rich ternary precursor has a particle size D 10 of 2.0 μm to 5.0 μm, a particle size D 50 of 7.0 μm to 15.0 μm, and a particle size D 90 of 12.0 μm to 20.0 μm; and the Ni-Rich ternary precursor has a tap density of 2.12 g/cm 3 to 2.15 g/cm 3 .

2. The preparation method according to claim 1 , further comprising a preparation process of the seed crystal: adding water to a seed crystal reactor, introducing an inert gas, and starting stirring and heating; feeding ammonia water, feeding an alkali liquor to adjust a pH, and feeding the alkali liquor and the metal salt solution simultaneously for a precipitation reaction; and continuing feeding the alkali liquor and the metal salt solution, and after a particle size of the seed crystal grows to 2.0 μm to 7.0 μm, stopping feeding the alkali liquor and the metal salt solution to obtain the seed crystal.

3. The preparation method according to claim 1 , wherein in S4, the Ni-Rich ternary precursor has a general structural formula of Ni x Co y Mn 1-x-y (OH) 2 , wherein 0.6<x<1, 0<y<0.4, and x+y<1.

4. The preparation method according to claim 1 , wherein in S2, continuous stirring is conducted during a whole process of the precipitation reaction at a speed of 150 rpm to 250 rpm.

5. The preparation method according to claim 1 , wherein in S2, the heating is conducted at 50° C. to 80° C.

Assignees

• Guangdong Brunp Recycling Technology Co Ltd
• Hunan Brunp Recycling Tech Co Ltd
• Hunan Brunp Ev Recycling Co Ltd

Inventors

• Li Weiquan
• Li Changdong
• Liu Genghao
• Ruan Dingshan
• Lin Hongjia

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• C01P2006/90

  Other properties not specified above · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01G53/82 Primary

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title