Alkali-stable nanofiltration composite membrane and method of manufacture thereof

Patent metadata

Field	Value
Publication number	US-12427486-B2
Application number	US-201917253653-A
Country	US
Kind code	B2
Filing date	Jun 24, 2019
Priority date	Jun 27, 2018
Publication date	Sep 30, 2025
Grant date	Sep 30, 2025

Abstract

Embodiments of the present invention relate to a nanofiltration composite membrane for use to purify water, the methods for preparing said nanofiltration composite membranes and to the nanofiltration composite membranes prepared accordingly.

First claim

What is claimed is:

1. A process for preparation of a nanofiltration composite membrane, comprising steps of:
a.) solving at least one polymer selected from the group consisting of polysulfone polymer, polyether polymer and mixtures thereof and at least one polyvinyl pyrrolidone polymer in at least one aprotic solvent to prepare a casting solution; and
b.) casting the casting solution of step a.) on a non-woven fabric to prepare a casted non-woven fabric; and
c.) bringing the casted non-woven fabric of step b.) into contact with a polar non-solvent to prepare a casted non-woven fabric membrane; and
d.) bringing the casted non-woven fabric membrane of step c.) into contact with at least one radical polymerization initiator; and
e.) washing the casted non-woven fabric membrane of step d.) with a non-solvent; and
f.) cross-linking the casted non-woven fabric membrane of step e.) to prepare said nanofiltration composite membrane;
wherein the nanofiltration composite membrane has an average molecular weight cut-off between 200 g/mol to 1000 g/mol.

2. The process according to claim 1 , wherein the polysulfone polymer is a polysulfone containing a following unit (I):

and n is 45 to 230.

3. The process according to claim 1 , wherein the polyether polymer is selected from the group consisting of polyethylene glycol, polypropylene glycol and mixtures of such polymers.

4. The process according to claim 1 , wherein a total amount of polymer used in step a.) is 10% weight to 22% weight based on an amount of the casting solution.

5. The process according to claim 1 , wherein the at least one polyvinyl pyrrolidone polymer contains a following chemical unit (II):

and m is 110 to 1100.

6. The process according to claim 1 , wherein an amount of the at least one polyvinyl pyrrolidone polymer used in the casting solution is 1% weight to 10% weight based upon a weight of the casting solution.

7. The process according to claim 1 , wherein the non-woven fabric in step b.) is selected from the group consisting of polyethylene, polypropylene, polymethylpentene and mixtures thereof.

8. The process according to claim 1 , wherein a weight per unit area of the non-woven fabric is 70 to 100 g/m 2 .

9. The process according to claim 1 , wherein the at least one aprotic solvent in step a.) is selected from the group consisting of N-methyl pyrrolidone, dimethyl formamide, dimethyl sulfoxide and dimethyl acetamide or mixtures thereof.

10. The process according to claim 1 , wherein step c.) will be conducted at a temperature of 3° C. to 6° C.

11. The process according claim 1 , wherein after step d.) has been performed step f.) is performed at a temperature of 80° C. to 110° C.

12. The process according to claim 11 , wherein step f.) will be performed in 1 to 20 minutes.

13. The process according to claim 1 , wherein the nanofiltration composite membrane has the average molecular weight cut-off between 500 g/mol to 1000 g/mol.

14. The process according to claim 1 , wherein a total amount of polymer used in step a.) is 17% weight to 21% weight based on an amount of the casting solution.

15. A process for preparation of a nanofiltration composite membrane, comprising steps of:
a.) solving at least one polymer selected from the group consisting of polysulfone polymer, polyether polymer and mixtures thereof and at least one polyvinyl pyrrolidone polymer in at least one aprotic solvent to prepare a casting solution; and
b.) casting the casting solution of step a.) on a non-woven fabric to prepare a casted non-woven fabric; and
c.) bringing the casted non-woven fabric of step b.) into contact with a polar non-solvent to prepare a casted non-woven fabric membrane; and
d.) bringing the casted non-woven fabric membrane of step c.) into contact with at least one radical polymerization initiator; and
e.) washing the casted non-woven fabric membrane of step d.) with a non-solvent; and
f.) cross-linking the casted non-woven fabric membrane of step e.) to prepare said nanofiltration composite membrane;

wherein a weight per unit area of the non-woven fabric is 70 to 100 g/m 2 .

16. A process for preparation of a nanofiltration composite membrane, comprising steps of:
a.) solving at least one polymer selected from the group consisting of polysulfone polymer, polyether polymer and mixtures thereof and at least one polyvinyl pyrrolidone polymer in at least one aprotic solvent to prepare a casting solution; and
b.) casting the casting solution of step a.) on a non-woven fabric to prepare a casted non-woven fabric; and
c.) bringing the casted non-woven fabric of step b.) into contact with a polar non-solvent to prepare a casted non-woven fabric membrane; and
d.) bringing the casted non-woven fabric membrane of step c.) into contact with at least one radical polymerization initiator; and
e.) washing the casted non-woven fabric membrane of step d.) with a non-solvent; and
f.) cross-linking the casted non-woven fabric membrane of step e.) to prepare said nanofiltration composite membrane;

wherein a total amount of polymer used in step a.) is 10% weight to 22% weight based on an amount of the casting solution.

Assignees

• Bl Technologies Inc

Inventors

• Karina Zedda
• Schellenberg Carsten
• Richter Judith

Classifications

• B01D69/1214

  Chemically bonded layers, e.g. cross-linking · CPC title

• B01D2323/081

  Heating · CPC title

• B01D67/00165

  Composition of the coagulation baths · CPC title

• B01D71/441

  Polyvinylpyrrolidone · CPC title

• B01D2325/34

  Molecular weight or degree of polymerisation · CPC title