Gas diffusion electrode and use thereof

Patent metadata

Field	Value
Publication number	US-12424637-B2
Application number	US-202217581218-A
Country	US
Kind code	B2
Filing date	Jan 21, 2022
Priority date	May 7, 2014
Publication date	Sep 23, 2025
Grant date	Sep 23, 2025

Abstract

A gas diffusion electrode may be provided comprising an electron conducting layer with a first side and an opposite second side, wherein the first side is provided with a microstructuring, wherein the gas diffusion electrode additionally has a hydrophobic membrane with a first side and an opposite second side, wherein the second side of the membrane is arranged on the first side of the electron conducting layer. A battery or an accumulator or an electrolyser or a galvanic cell may be provided with a gas diffusion electrode of this type.

First claim

The invention claimed is:

1. A method comprising:
forming a micro-structuring on an electron conducting layer by irradiating the electron conducting layer with laser radiation, the electron conducting layer having a first side and an opposite second side, the micro-structuring formed on the first side of the electron conducting layer, wherein the micro-structuring comprises a plurality of pinecone-shaped projections pointing away from the first side of the electron conducting layer, wherein each of the pinecone-shaped projections has a base diameter, a height, and an aspect ratio of the base diameter to the height within a range from approximately 1:3 to 3:1, wherein the pinecone-shaped projections each has a base with a diameter in a range from approximately 10 μm to approximately 30 μm and a tip having a diameter from approximately 1 μm to approximately 5 μm, and wherein the height of each of the pinecone-shaped projections is the distance between the base and the tip; and
forming a gas diffusion electrode by bringing the hydrophilic first side of the electron conducting layer and a hydrophobic membrane in contact with each other, the hydrophobic membrane having a first side and an opposite second side, wherein the second side of the membrane is arranged on the first side of the electron conducting layer, wherein the electron conducting layer comprises a plurality of electrolyte channels each of which extends from the first side of the electron conducting layer to the second side of the electron conducting layer.

2. The method of claim 1 , wherein the membrane comprises poly-tetrafluoroethylene or is made therefrom, and/or wherein the membrane has a thickness of approximately 10 μm to approximately 100 μm and/or wherein the membrane is gas-permeable.

3. The method of claim 1 , wherein the electron conducting layer comprises titanium and/or nickel and/or gold and/or silver and/or molybdenum and/or tungsten and/or a stainless steel alloy or is made therefrom.

4. The method of claim 1 , wherein the micro-structuring is partially embedded in the hydrophobic membrane.

5. The method of claim 1 , wherein the electrolyte channels each has a diameter from approximately 50 μm to approximately 150 μm.

6. The method of claim 1 , further comprising applying at least one catalyst on the first side of the electron conducting layer, which comprises platinum and/or nickel and/or silver and/or palladium and/or at least one manganese oxide and/or rhodium.

7. The method of claim 6 , wherein the area coating of the catalyst is within a range from approximately 0.05 mg*cm −2 to approximately 0.4 mg*cm −2 .

8. The method of claim 1 , further comprising arranging a separator on the second side of the electron conducting layer.

9. The method of claim 1 further comprising including the gas diffusion electrode in a battery or an accumulator or an electrolyzer or a galvanic cell.

10. The method of claim 1 , wherein the area coating of the catalyst is within a range from approximately 0.1 mg*cm −2 to approximately 0.35 mg*cm −2 .

11. The method of claim 1 , wherein the laser radiation has a pulse term of less than one nanosecond.

12. The method of claim 1 , further comprising exposing the electron conducting layer to a processing gas while irradiating the electron conducting layer with the laser radiation.

Assignees

• Fraunhofer Ges Forschung

Inventors

• Schade Wolfgang
• Gabler Andreas

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M4/92

  Metals of platinum group (H01M4/94 {, H01M4/9058} take precedence) · CPC title

• H01M4/9016

  Oxides, hydroxides or oxygenated metallic salts · CPC title

• H01M4/88

  Processes of manufacture · CPC title