Production method for isocyanate compound
US-2022002234-A1 · Jan 6, 2022 · US
US12421121B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12421121-B2 |
| Application number | US-202017639751-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 2, 2020 |
| Priority date | Sep 5, 2019 |
| Publication date | Sep 23, 2025 |
| Grant date | Sep 23, 2025 |
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The objective of the present invention is to provide a method for producing a halogenated carbonyl safely and efficiently. The method for producing a halogenated carbonyl according to the present invention is characterized in comprising the step of applying ultrasound to a composition containing a C 1-4 halogenated hydrocarbon having one or more halogeno groups selected from the group consisting of chloro, bromo and iodo in the presence of oxygen to decompose the C 1-4 halogenated hydrocarbon.
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The invention claimed is: 1. A method for producing a halogenated carbonyl, the method comprising the step of applying ultrasound to a composition containing a C 1-4 halogenated hydrocarbon having one or more halogeno groups selected from the group consisting of chloro, bromo and iodo under a stream of a gas containing oxygen or with supplying a gas containing oxygen into the composition by bubbling to decompose the C 1-4 halogenated hydrocarbon with or without irradiating a high energy light having a peak wavelength included in a range of 180 nm or more and 280 nm or less. 2. The method according to claim 1 , wherein the high energy light having a peak wavelength included in a range of 180 nm or more and 280 nm or less is irradiated to the composition. 3. The method according to claim 1 , wherein a frequency of the ultrasound is 20 kHz or more and 100 kHz or less. 4. The method according to claim 1 , wherein power of the ultrasound applied to the composition is 0.05 W/cm 2 or more and 10 W/cm 2 or less per a surface area of the composition to which the ultrasound is applied. 5. The method according to claim 1 , wherein a C 1-2 polyhalogenated hydrocarbon is used as the C 1-4 halogenated hydrocarbon. 6. The method according to claim 1 , wherein a mixture of dichloromethane and tetrachloromethane is used as the C 1-4 halogenated hydrocarbon. 7. The method according to claim 2 , wherein a C 1-2 polyhalogenated hydrocarbon is used as the C 1-4 halogenated hydrocarbon. 8. The method according to claim 2 , wherein a mixture of dichloromethane and tetrachloromethane is used as the C 1-4 halogenated hydrocarbon.
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