Pressure sensitive adhesive particle, cartridge, apparatus for producing printed material, method for producing printed material, printed material, sheet for producing printed material, and method for producing sheet for producing printed material

Patent metadata

Field	Value
Publication number	US-12420519-B2
Application number	US-202117501031-A
Country	US
Kind code	B2
Filing date	Oct 14, 2021
Priority date	Jan 19, 2021
Publication date	Sep 23, 2025
Grant date	Sep 23, 2025

Abstract

A pressure sensitive adhesive particle includes a styrene resin that contains, as polymerization components, styrene and a vinyl monomer other than styrene; and a (meth)acrylate resin that contains, as polymerization components, at least two (meth)acrylates that account for 90 mass % or more of all polymerization components of the (meth)acrylate resin, in which the pressure sensitive adhesive particle has a sea phase that contains the styrene resin, and island phases that are dispersed in the sea phase and contain the (meth)acrylate resin, the pressure sensitive adhesive particle has at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30° C. or more, and in a cross section of the pressure sensitive adhesive particle, an area ratio of the island phases is 30% or more and 85% or less.

First claim

What is claimed is:

1. A pressure sensitive adhesive particle comprising:
a styrene resin that contains, as polymerization components, styrene and a vinyl monomer other than styrene; and
a (meth)acrylate resin that consists of, as polymerization components, a first alkyl(meth)acrylate and a second alkyl(meth)acrylate, and a mass ratio between the first alkyl(meth)acrylate and the second alkyl(meth)acrylate in the (meth)acrylate resin is from 80:20 to 20:80,
wherein:

a volume-average particle diameter (D50 v) of the pressure sensitive adhesive base particle is from 6 μm to 12 μm;
the pressure sensitive adhesive particle has a core that contains the styrene resin and the (meth)acrylate resin, and a shell layer that covers the core; the core has a sea phase that contains the styrene resin, and island phases that are dispersed in the sea phase and contain the (meth)acrylate resin;
the pressure sensitive adhesive particle has at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30° C. or more; and
in a cross section of the pressure sensitive adhesive particle, an area ratio of the island phases is 30% or more and 85% or less.

2. The pressure sensitive adhesive particle according to claim 1 , wherein, in the cross section of the pressure sensitive adhesive particle, the area ratio of the island phases is 35% or more and 80% or less.

3. The pressure sensitive adhesive particle according to claim 1 , wherein the island phases have an average diameter of 200 nm or more and 500 nm or less.

4. The pressure sensitive adhesive particle according to claim 1 , wherein, in the cross section of the pressure sensitive adhesive particle, an average number of the island phases per pressure sensitive adhesive particle is 20 or more and 4000 or less.

5. The pressure sensitive adhesive particle according to claim 4 , wherein, in the cross section of the pressure sensitive adhesive particle, the average number of the island phases per pressure sensitive adhesive particle is 35 or more and 2000 or less.

6. The pressure sensitive adhesive particle according to claim 1 , wherein, in the cross section of the pressure sensitive adhesive particle, the island phases satisfy requirements (1) and (2) below:
Requirement (1): An area ratio As1(%) of the island phases in a first region and an area ratio As2(%) of the island phases in a second region have a relationship of 0.70≤As2/As1≤1.20
Requirement (2): The area ratio As1(%) of the island phases in the first region and an area ratio As3(%) of the island phases in a third region have a relationship of 0.70≤As3/As1≤1.20, and
wherein the first region, the second region, and the third region are regions in a cross section of the pressure sensitive adhesive particle and are formed by dividing a portion that spans from a position 550 nm deep from a surface to a center of gravity equally into three parts that respectively correspond to the first region, the second region, and the third region in order of proximity to the center of gravity.

7. The pressure sensitive adhesive particle according to claim 1 , wherein a total concentration of Al, Mg, and Ca contained in the pressure sensitive adhesive particle satisfies requirement (3) below:
Requirement (3): When a volume-average particle diameter of the pressure sensitive adhesive particle is represented by D (μm), a total concentration Mes (%) of Al, Mg, and Ca as measured by energy-dispersive X-ray spectroscopy at an acceleration voltage of 0.6×D+0.9 (kV) and a total concentration Met (%) of Al, Mg, and Ca as measured by energy-dispersive X-ray spectroscopy at an acceleration voltage of 1.8×D+4.9 (kV) have a relationship of 0.15≤Mes/Met<0.60.

8. The pressure sensitive adhesive particle according to claim 1 , wherein a concentration of Al contained in the pressure sensitive adhesive particle satisfies requirement (4) below:
Requirement (4): When a volume-average particle diameter of the pressure sensitive adhesive particle is represented by D (μm), an Al concentration Als (%) as measured by energy-dispersive X-ray spectroscopy at an acceleration voltage of 0.6×D+0.9 (kV) and an Al concentration Alt (%) as measured by energy-dispersive X-ray spectroscopy at an acceleration voltage of 1.8×D+4.9 (kV) have a relationship of 0.15≤Als/Alt<0.60.

9. The pressure sensitive adhesive particle according to claim 1 , wherein the shell layer contains the styrene resin.

10. A cartridge detachably attachable to an apparatus for producing a printed material, the cartridge comprising:
the pressure sensitive adhesive particle according to claim 1 .

11. An apparatus for producing a printed material, the apparatus comprising:
an applying unit that stores the pressure sensitive adhesive particle according to claim 1 and applies the pressure sensitive adhesive particle to a recording medium; and
a pressure bonding unit that folds the recording medium and pressure-bonds the folded recording medium or that stacks another recording medium on the recording medium and pressure-bonds the stacked recording media.

12. The apparatus for producing a printed material according to claim 11 , further comprising a color image forming unit that forms a color image on the recording medium by using a coloring material.

13. A method for producing a printed material, the method comprising:
applying the pressure sensitive adhesive particle according to claim 1 to a recording medium; and
folding the recording medium and pressure-bonding the folded recording medium, or stacking another recording medium on the recording medium and pressure-bonding the stacked recording media.

14. The method for producing a printed material according to claim 13 , the method further comprising forming a color image on the recording medium by using a coloring material.

15. A printed material comprising:
a folded recording medium having opposing surfaces bonded with the pressure sensitive adhesive particle according to claim 1 .

16. A printed material comprising:
a plurality of recording media stacked on top of each other, wherein opposing surfaces of the recording media are bonded with the pressure sensitive adhesive particle according to claim 1 .

17. A sheet for producing a printed material, the sheet comprising:
a substrate; and
the pressure sensitive adhesive particle according to claim 1 applied to the substrate.

18. A method for producing a sheet for producing a printed material, the method comprising:
applying the pressure sensitive adhesive particle according to claim 1 to a substrate.

19. A pressure sensitive adhesive particle comprising:
a styrene resin that contains, as polymerization components, styrene and a vinyl monomer other than styrene; and
a (meth)acrylate resin that consists of, as polymerization components, a first alkyl(meth)acrylate and a second alkyl(meth)acrylate, and a mass ratio between the first alkyl(meth)acrylate and the second alkyl (meth)acrylate in the (meth)acrylate resin is from 80:20 to 20:80,
wherein:

a weight-average molecular weight of the (meth)acrylate resin is from 50,000 to 200,000;
the pressure sensitive adhesive particle has a core that contains the styrene resin and the (meth)acrylate resin, and a shell layer that covers the core; the core has a sea phase that contains the styrene resin, and island phases that are dispersed in the sea phase and contain the (meth)acrylate resin;
the pressure sensitive adhesive particle has at least two glass transition

Assignees

• Fujifilm Business Innovation Corp

Inventors

• Yamanaka Kiyohiro
• Yamasaki Sumiaki
• Kamiwaki Satoshi

Classifications

• C09J2433/00

  Presence of (meth)acrylic polymer · CPC title

• C09J2425/00

  Presence of styrenic polymer · CPC title

• C09J2203/102

  in the form of dowels, anchors or cartridges · CPC title

• B65H37/06

  for folding · CPC title

• B65H37/04

  for securing together articles or webs, e.g. by adhesive, stitching or stapling (adhering replacement to expiring web during change of web roll B65H19/18) · CPC title