Partially translucent photovoltaic window and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-12419189-B2
Application number	US-202117794360-A
Country	US
Kind code	B2
Filing date	Jan 26, 2021
Priority date	Jan 27, 2020
Publication date	Sep 16, 2025
Grant date	Sep 16, 2025

Abstract

A partially translucent photovoltaic window is provided herein that comprises a photovoltaic module enclosed between a first window pane and a second window pane. The photovoltaic module comprises a stack with at least a first electrode layer, a second electrode layer and a perovskite photovoltaic layer sandwiched between the electrode layers. The photovoltaic window further comprises between the first window pane and the photovoltaic module as well as between the second window pane and the photovoltaic module a respective intermediate layer comprising a lead getter material.

First claim

The invention claimed is:

1. A partially translucent photovoltaic window, comprising:
a first window pane;
a second window pane; and
a photovoltaic module enclosed between the first window pane and the second window pane,
wherein the photovoltaic module comprises a stack including:
a first electrode layer,
a second electrode layer, and
a perovskite photovoltaic layer between the first electrode layer and the second electrode layer;

wherein the photovoltaic window further comprises, between the first window pane and the photovoltaic module and between the second window pane and the photovoltaic module, respective intermediate layers,
wherein each of the respective intermediate layers comprise a lead getter material that is configured to scavenge lead compounds dissolved in water and to convert the lead compounds into a non-soluble substance,
wherein the perovskite photovoltaic layer has:
an absorption with a substantially uniform distribution over the visible light spectrum, and
a relatively high absorption for radiation having a wavelength greater than 700 nm as compared to an absorption for radiation in the visible spectrum.

2. The partially translucent photovoltaic window according to claim 1 , wherein at least one of the respective intermediate layers is an elastic polymer, having the lead getter material dispersed therein.

3. The partially translucent photovoltaic window according to claim 2 , wherein the elastic polymer is an adhesive.

4. The partially translucent photovoltaic window according to claim 1 , wherein the lead getter material comprises phosphor and/or sulphur.

5. The partially translucent photovoltaic window according to claim 1 , wherein the photovoltaic window is transparent.

6. A building comprising one or more of the partially translucent photovoltaic window according to claim 5 .

7. The partially translucent photovoltaic window according to claim 2 , wherein the lead getter material comprises phosphor and/or sulphur.

8. A building comprising one or more of the partially translucent photovoltaic window according to claim 1 .

9. A building comprising one or more partially translucent photovoltaic window according to claim 2 .

10. The partially translucent photovoltaic window according to claim 1 , wherein the first electrode layer and the second electrode layer are each provided with at least one electrode layer type taken from the group consisting of:
at least one type of translucent electrically conductive layer made of a material type taken from the group consisting of:
an organic material type taken from the group consisting of polyaniline, polythiophene, polypyrrole and doped polymers; and
an inorganic material selected from the group consisting of ITO (Indium Tin Oxide), IZO (Indium Zinc Oxide), ATO (Antimony Tin Oxide), Tin Oxide, Nickel-Tungsten-Oxide, Indium doped Zinc Oxide, and Magnesium-Indium-Oxide; and

a metal layer having a thickness of at most 7 nm.

11. The partially translucent photovoltaic window according to claim 1 that is non-transparent.

12. The partially translucent photovoltaic window according to claim 1 , further comprising:
a further electro-optical layer stack for electrically controlling a transparency of the partially translucent photovoltaic window to enter a transparent state.

13. The partially translucent photovoltaic window according to claim 1 , further comprising:
a further electro-optical layer stack for electrically controlling a transparency of the partially translucent photovoltaic window to enter an opaque state.

14. The partially translucent photovoltaic window according to claim 1 , further comprising:
a further electro-optical layer stack for electrically controlling a transparency of the partially translucent photovoltaic window to enter an intermediate state.

Assignees

• TNO

Inventors

• Andriessen Hieronymus Antonius Josephus Maria
• Galagan Yulia
• Fledderus Henri
• Lifka Herbert

Classifications

• H10F19/80

  Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells · CPC title

• H10K30/40

  comprising a p-i-n structure, e.g. having a perovskite absorber between p-type and n-type charge transport layers · CPC title

• H10K50/846

  comprising getter material or desiccants · CPC title

• H02S20/26 Primary

  Building materials integrated with PV modules, e.g. façade elements (H02S20/25 takes precedence) · CPC title

• H10K85/50 Primary

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title