Adhesive sheet and laminate
US-2023119700-A1 · Apr 20, 2023 · US
US12416835B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12416835-B2 |
| Application number | US-202118031773-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 28, 2021 |
| Priority date | Oct 29, 2020 |
| Publication date | Sep 16, 2025 |
| Grant date | Sep 16, 2025 |
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An optical device is disclosed herein. In some embodiments, an optical device includes a first outer substrate, a second outer substrate, a liquid crystal element positioned between the first outer substrate and the second outer substrate, a first intermediate layer between the first outer substrate and the liquid crystal element, and a second intermediate layer between the second outer substrate and the liquid crystal element, wherein a sum of total thicknesses of the first and second intermediate layers is 800 μm or more, and wherein the liquid crystal element includes a first base layer, a second base layer, a liquid crystal layer between the first base layer and the second base layer, a pressure-sensitive adhesive layer between the first base layer and the liquid crystal layer, and a spacer to maintain a gap between the first and second base layers.
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The invention claimed is: 1. An optical device, comprising: a first outer substrate; a second outer substrate; a liquid crystal element positioned between the first outer substrate and the second outer substrate; a first intermediate layer positioned between the first outer substrate and the liquid crystal element; and a second intermediate layer positioned between the second outer substrate and the liquid crystal element, wherein the liquid crystal element comprises: a first base layer; a first electrode layer formed on an inner surface of the first base layer; a second base layer; a liquid crystal layer positioned between the first base layer and the second base layer, wherein the liquid crystal layer comprises a liquid crystal compound and a dichroic dye; a pressure-sensitive adhesive layer positioned between the first base layer and the liquid crystal layer and present on an inner surface of the first electrode layer; and a spacer, wherein the spacer maintains a gap between the first and second base layers, wherein the first outer substrate is bonded via the first intermediate layer to a first side of the liquid crystal element, the second outer substrate is bonded via the second intermediate layer to a second side of the liquid crystal element, and a sum of total thicknesses of the first and second intermediate layers is 1,100 μm or more, and wherein the pressure-sensitive adhesive layer has a storage elastic modulus at a temperature of 25° C. and a frequency of 6 rad/sec of 0.01 MPa to 1 MPa and is a liquid crystal orientational pressure-sensitive adhesive layer that imparts vertical orientation force or horizontal orientation force to an adjacent liquid crystal compound, wherein each of the first and second intermediate layers have a storage elastic modulus in a range of 2 MPa to 100 MPa. 2. The optical device according to claim 1 , wherein the first outer substrate and the second outer substrate are each a glass substrate. 3. The optical device according to claim 1 , wherein the optical device does not have polarizers between the first outer substrate and the liquid crystal element and between the second outer substrate and the liquid crystal element. 4. The optical device according to claim 1 , wherein the optical device further comprises one or more polarizers, wherein the one or more polarizers are positioned in at least one of between the first outer substrate and the liquid crystal element or between the second outer substrate and the liquid crystal element. 5. The optical device according to claim 1 , wherein the liquid crystal layer is capable of switching between a first orientation state and a second orientation state different from the first orientation state when external energy is applied. 6. The optical device according to claim 1 , wherein the dichroic dye is present in an amount of 0.2 wt % to 10 wt %, based on the total weight of the liquid crystal layer. 7. The optical device according to claim 1 , wherein the spacer is a patterned spacer. 8. The optical device according to claim 1 , wherein a ratio of an area (B) of the spacer to an area (A) of the second base layer is in a range of 5% to 50%. 9. The optical device according to claim 1 , wherein the liquid crystal element further comprises a second electrode layer formed on an inner surface of the second base layer, and wherein the spacer is present on an inner surface of the second electrode layer. 10. The optical device according to claim 9 , wherein the liquid crystal element further comprises: an alignment film present on the inner surface of the second electrode layer, where the inner surface of the first electrode layer does not have an alignment film formed thereon. 11. The optical device according to claim 1 , wherein each of the first and second intermediate layers have a thickness in a range of 400 μm to 3,000 μm. 12. The optical device according to claim 1 , wherein each of the first and second intermediate layers have a Young's modulus in a range of 0.1 MPa to 100 MPa. 13. The optical device according to claim 1 , wherein each of the first and second intermediate layers have a coefficient of thermal expansion of 2,000 ppm/K or less. 14. The optical device according to claim 1 , wherein each of the first and second intermediate layers are a thermoplastic polyurethane adhesive layer, a polyamide adhesive layer, a polyester adhesive layer, an EVA (ethylene vinyl acetate) adhesive layer, an acrylic adhesive layer, a silicone adhesive layer, or a polyolefin adhesive layer. 15. An automobile, comprising: a vehicle body having an opening formed therein; and the optical device of claim 1 mounted in the opening.
Adhesive materials or arrangements · CPC title
pleochroic · CPC title
characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering · CPC title
adjustable in transparency · CPC title
Rigid substrates, e.g. inorganic substrates · CPC title
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