Process for dyeing and foaming thermoplastic polyurethane
US-2020063338-A1 · Feb 27, 2020 · US
US12416054B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12416054-B2 |
| Application number | US-202017607188-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 29, 2020 |
| Priority date | Apr 29, 2019 |
| Publication date | Sep 16, 2025 |
| Grant date | Sep 16, 2025 |
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An apparatus includes a process chamber, a controllable compressor for pressurizing a fluid, a pressure reducing member, an inlet for a processing agent and a controller. The process chamber is a pressure chamber. The controllable compressor pressurizes a fluid and introduces the pressurized fluid into the process chamber from a source. Further the controllable compressor controls a predefined pressure in the process chamber to reach a supercritical state of the fluid. An inlet for a processing agent facilitates introduction of the processing agent into the process chamber prior to, during, or subsequent to pressurization of the fluid. The pressure reducing member reduces the pressure of the fluid at least to reach a gaseous state subsequent to processing the leather object such that the time for reduction of pressure exceeds a predefined reduction period or the reduction of pressure does not exceed a predefined leather pressure reduction gradient.
Opening claim text (preview).
The invention claimed is: 1. An apparatus for processing of leather objects, said leather objects being pre-treated at least by a tanning process, said apparatus comprising: a process chamber, a controllable compressor for pressurizing a fluid, a pressure reducing member, an inlet for a processing agent, and a controller, wherein: said process chamber is configured in a form of a pressure chamber, said controllable compressor for: pressurizing the fluid is configured for introducing pressurized fluid into the process chamber from a source of said fluid, controlled by the controller, and providing a predefined pressure in the process chamber in order to reach a supercritical state of said fluid, said inlet for the processing agent is configured for facilitating introduction of said processing agent into the process chamber prior to, during, or subsequent to pressurization of the fluid, said pressure reducing member is configured for, controlled by the controller, reducing the pressure of the pressurized fluid at least to reach a gaseous state subsequent to processing of said leather object such that a time for reduction of the pressure exceeds a predefined reduction period of between 5 min. to 2 hours. 2. The apparatus according to claim 1 , wherein the apparatus is configured for pressurizing the pressurized fluid in the process chamber to reach the supercritical state, controlled by the controller, such that: the time for increasing the pressure exceeds a predefined increase period, or the increase of the pressure does not exceed a predefined leather pressure increase gradient. 3. The apparatus according to claim 1 , wherein said process chamber comprises a closeable member for inletting and outletting leather objects. 4. The apparatus according to claim 1 , wherein said pressure reducing member is controlled in dependence of time and/or at least one pressure sensor variable. 5. The apparatus according to claim 1 , wherein the apparatus further comprising a separator connected to an outlet of said pressure reducing member, said separator being configured for separating processing agent residue from the fluid. 6. The apparatus according to claim 5 , wherein said apparatus comprising a pipe for recycling fluid from the separator to a storage container operating as a fluid source for the apparatus. 7. The apparatus according to claim 6 , wherein the controllable compressor is a first compressor, and wherein said apparatus further comprises a second compressor for pumping the fluid from the separator to the storage container. 8. The apparatus according to claim 1 , wherein said inlet for the processing agent comprises one of: an inlet direct to the process chamber, an inlet to the fluid being pressurized to be introduced into the process chamber, and an inlet combined with an inlet for skin, hide, or leather objects into the process chamber. 9. The apparatus according to claim 1 , wherein the predefined pressure in the process chamber in order to reach the supercritical state of said fluid is at least 70 bar. 10. The apparatus according to claim 1 , wherein the apparatus further comprises temperature control apparatus, controlled by the controller, for maintaining a temperature of the pressurized fluid, which is in the supercritical state in the process chamber, in a temperature range of between 30 to 120 degrees Celsius. 11. The apparatus according to claim 1 , wherein the apparatus further is configured for reducing the pressure of the pressurized fluid in the process chamber to a level corresponding to ambient pressure subsequent to processing of said leather object. 12. The apparatus according to claim 1 , wherein the apparatus is configured such that the time for increasing the pressure to reach the supercritical state exceeds a predefined increase period of 5 min. 13. The apparatus according to claim 1 , wherein said apparatus is configured for controlling the pressure and temperature of the fluid in the supercritical state to achieve and/or maintain a desired density of the fluid in the supercritical state. 14. The apparatus according to claim 1 , wherein the time, during which the leather object is subjected to the processing agent in the pressurized fluid in the supercritical state, is at least 1 min. 15. An apparatus for processing of leather objects, said leather objects being pre-treated at least by a tanning process, said apparatus comprising: a process chamber; a controllable compressor for pressurizing a fluid; a pressure reducing member; an inlet for a processing agent; and a controller, wherein: said process chamber is configured in a form of a pressure chamber, said controllable compressor for: pressurizing the fluid is configured for introducing pressurized fluid into the process chamber from a source of said fluid, controlled by the controller, and providing a predefined pressure in the process chamber in order to reach a supercritical state of said fluid, said inlet for the processing agent is configured for facilitating introduction of said processing agent into the process chamber prior to, during, or subsequent to pressurization of the fluid, said pressure reducing member is configured for, controlled by the controller, reducing the pressure of the pressurized fluid at least to reach a gaseous state subsequent to processing of said leather object such that the reduction of the pressure does not exceed a predefined leather pressure reduction gradient of 10 bar/min. 16. An apparatus for processing of leather objects, said leather objects being pre-treated at least by a tanning process, said apparatus comprising: a process chamber; a controllable compressor for pressurizing a fluid; a pressure reducing member; an inlet for a processing agent; and a controller, wherein: said process chamber is configured in a form of a pressure chamber, said controllable compressor for: pressurizing the fluid is configured for introducing pressurized fluid into the process chamber from a source of said fluid, controlled by the controller, and providing a predefined pressure in the process chamber in order to reach a supercritical state of said fluid, said inlet for the processing agent is configured for facilitating introduction of said processing agent into the process chamber prior to, during, or subsequent to pressurization of the fluid, said pressure reducing member is configured for, controlled by the controller, reducing the pressure of the pressurized fluid at least to reach a gaseous state subsequent to processing of said leather object such that: a time for reduction of the pressure exceeds a predefined reduction period, or the reduction of the pressure does not exceed a predefined leather pressure reduction gradient, and the apparatus is configured such that an increase of the pressure does not exceed a predefined leather pressure increase gradient of 20 bar/min.
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