Granules of MGDA and (meth)acrylic acid homo- or co-polymer; process for making the same

Patent metadata

Field	Value
Publication number	US-12415971-B2
Application number	US-202017784573-A
Country	US
Kind code	B2
Filing date	Dec 1, 2020
Priority date	Dec 11, 2019
Publication date	Sep 16, 2025
Grant date	Sep 16, 2025

Abstract

A process for making a granule containing (A) at least one chelating agent selected from alkali metal salts of methyl glycine diacetic acid (MGDA) and of iminodisuccinic acid (IDS), and, optionally, (B) at least one homo- or copolymer of (meth) acrylic acid, partially or fully neutralized with alkali, the process including the steps of (a) providing an aqueous solution or slurry containing chelating agent (A) and, if applicable, (co) polymer (B), (b) removing most of the water by spray granulation in a fluidized bed, (c) treating the resultant granule in a vessel of which at least one part rotates around a horizontal axis and wherein the vessel is selected from paddle mixers, free-fall mixers and plough share mixers.

First claim

The invention claimed is:

1. A process for making a granule comprising
(A) at least one chelating agent comprising one or more alkali metal salts of methyl glycine diacetic acid (MGDA), and, optionally,
(B) at least one homo-or copolymer of (meth) acrylic acid, partially or fully neutralized with alkali, said process comprising the steps of
(a) providing an aqueous solution or slurry containing chelating agent (A) and, if applicable, (co) polymer (B),
(b) removing most of said water by spray granulation in a fluidized bed, thereby obtaining a granule,
(c) treating the resultant granule from step (b) with air or an inert gas in a vessel of which at least one part rotates around a horizontal axis and wherein said vessel is a paddle mixer, free-fall mixer, or plough share mixer.

2. The process according to claim 1 , wherein in step (b), a gas with an inlet temperature of at least 125° C. is used.

3. The process according to claim 1 , wherein the weight ratio of chelating agent (A) and (co) polymer (B) is in the range of from 1,000:1 to 7.5:1.

4. The process according to claim 1 , wherein step (b) is performed with a two-fluid nozzle.

5. The process according to claim 1 , wherein step (c) is performed over a period of 1 minute to 5 hours.

6. The process according to claim 1 , wherein step (c) is performed in a free-fall mixer.

7. The process according to claim 1 , wherein step (c) is followed by a step (d) including the removal of fines.

8. The process according to claim 1 , wherein (co) polymer (B) is selected from copolymers of (meth) acrylic acid and a comonomer bearing at least one sulfonic acid group per molecule.

9. The process according to claim 8 , wherein the comonomer bearing at least one sulfonic acid group per molecule is 2-acrylamido-2-methylpropanesulfonic acid.

Assignees

• Basf Se

Inventors

• Schoenherr Michael
• Schmidt Kati
• Haus Johannes Felix
• Mueller Michael Klemens
• Jaekel Frank
• Reinoso Garcia Marta
• Klock Volker

Classifications

• C11D11/02

  Preparation in the form of powder by spray drying · CPC title

• C11D3/378

  (Co)polymerised monomers containing sulfur, e.g. sulfonate · CPC title

• C11D1/52

  Carboxylic amides, alkylolamides or imides {or their condensation products with alkylene oxides} · CPC title

• C11D11/0088

  the liquefied ingredients being sprayed or adsorbed onto solid particles · CPC title

• C11D11/0082

  one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads · CPC title