Adaptive control of BTX removal in sulfur recovery units

Patent metadata

Field	Value
Publication number	US-12415725-B2
Application number	US-202217974256-A
Country	US
Kind code	B2
Filing date	Oct 26, 2022
Priority date	Oct 26, 2022
Publication date	Sep 16, 2025
Grant date	Sep 16, 2025

Abstract

A system includes an outlet flowline from an activated carbon bed, a bypass flowline, a furnace, and a control system. The outlet flowline is configured to flow an acid gas stream out of the activated carbon bed after the activated carbon bed has removed benzene, toluene, and xylene from the acid gas stream. The bypass flowline includes a bypass valve and provides an alternative flow path for the acid gas stream exiting the activated carbon bed. The furnace includes a burner configured to combust at least a portion of the acid gas stream. The control system includes a temperature sensor and a controller. The temperature sensor is configured to measure a furnace temperature. The controller is configured to reduce a percent opening of the bypass valve based on the measured furnace temperature.

First claim

What is claimed is:

1. A system comprising:
an acid gas stream comprising hydrogen sulfide, benzene, toluene, and xylene;
an outlet pipe manifold;
a plurality of activated carbon beds, each activated carbon bed configured to remove benzene, toluene, and xylene from the acid gas stream in response to contacting the acid gas stream, the plurality of activated carbon beds in a parallel flow configuration;
for each activated carbon bed:
an outlet flowline connecting the respective activated carbon bed to the outlet pipe manifold, the outlet flowline comprising an outlet valve configured to control flow of the acid gas stream exiting the respective activated carbon bed through the outlet flowline;
a bypass flowline connected to the outlet flowline, the bypass flowline having an inner diameter that is smaller in comparison to an inner diameter of the outlet flowline, the bypass flowline providing an alternative flow path for the acid gas stream exiting the respective activated carbon bed around the outlet flowline, the bypass flowline comprising a bypass valve configured to control flow of the acid gas stream exiting the respective activated carbon bed through the bypass flowline;

a furnace in fluid communication with the outlet pipe manifold and configured to receive the acid gas stream from the outlet pipe manifold, the furnace comprising a burner configured to combust at least a portion of the acid gas stream in the presence of oxygen;
a control system comprising a temperature sensor coupled to the furnace, the control system communicatively coupled to each bypass valve, the temperature sensor configured to measure a furnace temperature of the furnace, wherein the control system is configured to adjust a percent opening of at least one of the bypass valves based on the furnace temperature measured by the temperature sensor.

2. The system of claim 1 , wherein the temperature sensor is configured to transmit the measured furnace temperature, and the control system comprises a controller communicatively coupled to the temperature sensor and to each bypass valve, the controller comprising:
one or more processors; and
a non-transitory computer-readable storage medium coupled to the one or more processors and storing programming instructions for execution by the one or more processors, the programming instructions instructing the one or more processors to perform operations comprising:
receiving the measured furnace temperature from the temperature sensor;
determining a difference between the measured furnace temperature and a specified setpoint temperature; and
transmitting a close signal to at least one of the bypass valves to reduce the percent opening of the respective bypass valve in response to determining that the difference between the measured furnace temperature and the specified setpoint temperature is equal to or greater than 10 degrees Fahrenheit (° F.) differential.

3. The system of claim 2 , wherein for each 10° F. differential in the difference between the measured furnace temperature and the specified setpoint temperature, the controller is configured to reduce the percent opening of the respective bypass valve by 10% down to a minimum percent opening of 50%.

4. The system of claim 3 , wherein the specified setpoint temperature is about 1,950° F.

5. The system of claim 4 , wherein for each activated carbon bed, a ratio of the inner diameter of the bypass flowline to the inner diameter of the outlet flowline is in a range of from 6:32 to 10:28.

6. The system of claim 5 , wherein for each outlet flowline, a ratio of the inner diameter of the respective outlet flowline to an inner diameter of the outlet pipe manifold is in a range of from 28:44 to 32:40.

7. The system of claim 6 , comprising a preheater installed on the outlet pipe manifold upstream of the furnace, the preheater configured to heat the acid gas stream prior to the acid gas stream entering the furnace.

8. The system of claim 7 , comprising a main bypass flowline connected to the outlet pipe manifold and the furnace, the main bypass flowline providing an alternative flow path for the acid gas stream to bypass the preheater and the burner, the main bypass flowline comprising a main bypass valve configured to control flow of the acid gas stream through the main bypass flowline.

9. A system comprising:
an outlet flowline from an activated carbon bed, the outlet flowline configured to flow an acid gas stream out of the activated carbon bed after the activated carbon bed has removed benzene, toluene, and xylene from the acid gas stream;
a bypass flowline connected to the outlet flowline, the bypass flowline having an inner diameter that is smaller in comparison to an inner diameter of the outlet flowline, the bypass flowline providing an alternative flow path for the acid gas stream exiting the activated carbon bed around the outlet flowline, the bypass flowline comprising a bypass valve configured to control flow of the acid gas stream exiting the activated carbon bed through the bypass flowline;
a furnace configured to receive the acid gas stream from at least one of the outlet flowline or the bypass flowline, the furnace comprising a burner configured to combust at least a portion of the acid gas stream in the presence of oxygen;
a control system comprising:
a temperature sensor coupled to the furnace, the temperature sensor configured to measure a furnace temperature of the furnace and transmit the measured furnace temperature; and
a controller communicatively coupled to the temperature sensor and to the bypass valve, the controller configured to:
receive the measured furnace temperature from the temperature sensor;
determine a difference between the measured furnace temperature and a specified setpoint temperature; and
reduce a percent opening of the bypass valve in response to determining that the difference between the measured furnace temperature and the specified setpoint temperature is equal to or greater than 10 degrees Fahrenheit (° F.) differential.

10. The system of claim 9 , wherein for each 10° F. differential in the difference between the measured furnace temperature and the specified setpoint temperature, the controller is configured to reduce the percent opening of the bypass valve by 10% down to a minimum percent opening of 50%.

11. The system of claim 10 , wherein the specified setpoint temperature is about 1,950° F.

12. The system of claim 11 , wherein a ratio of the inner diameter of the bypass flowline to the inner diameter of the outlet flowline is in a range of from 6:32 to 10:28.

13. The system of claim 12 , wherein a ratio of the inner diameter of the outlet flowline to an inner diameter of the outlet pipe manifold is in a range of from 28:44 to 32:40.

14. The system of claim 13 , comprising a preheater installed on the outlet pipe manifold upstream of the furnace, the preheater configured to heat the acid gas stream prior to the acid gas stream entering the furnace.

15. The system of claim 14 , comprising a main bypass flowline connected to the outlet pipe manifold and the furnace, the main bypass flowline providing an alternative flow path for the acid gas stream to bypass the preheater and the burner, the main bypass flowline comprising a main bypass valve configured to control flow of the acid gas stream through the main bypass flowline.

16. A method comprising:
flowing an acid gas stream to an activated carbon bed, the acid gas stream comprising hydrogen sulfide, benzene, toluene, and xylene;
removing, by the activated carbon bed, benzene, toluene, and xylene from the acid gas s

Assignees

• Saudi Arabian Oil Co

Inventors

• Aboghoniem Tarek D
• Albader Abdullah A
• Almulla Abdullraheem U

Classifications

• C01B17/0413

  characterised by the combustion step · CPC title

• B01D2259/40003

  Methods relating to valve switching · CPC title

• B01D2257/7027

  Aromatic hydrocarbons · CPC title

• B01D2253/102

  Carbon · CPC title

• B01D53/0454

  Controlling adsorption (controlling temperature swing adsorption B01D53/0462, controlling pressure swing adsorption B01D53/047) · CPC title