Abrasion-resistant, stable and flame-resistant superhydrophobic/superoleophobic coating, and preparation and application thereof

Patent metadata

Field	Value
Publication number	US-12415205-B2
Application number	US-202217998164-A
Country	US
Kind code	B2
Filing date	May 20, 2022
Priority date	May 31, 2021
Publication date	Sep 16, 2025
Grant date	Sep 16, 2025

Abstract

Provided are an abrasion-resistant, stable and flame-resistant superhydrophobic/superoleophobic coating, and a preparation and application thereof, belonging to the field of new materials; the preparation includes: taking a superhydrophobic/superoleophobic suspension as a top-layer spraying solution; dispersing epoxy resin in a solvent, and adding a fluorine-containing curing agent and a flame retardant for reaction to obtain a bottom-layer spraying solution; and first spraying the bottom-layer spraying solution to a surface of a substrate, then spraying the top-layer spraying solution, and drying the surface to obtain a bilayer abrasion-resistant superhydrophobic flame-resistant coating; the superhydrophobic/superoleophobic suspension contains multi-level micro nano structural particles, a fluorine-containing curing agent and fluorinated epoxy resin; the prepared single-layer coating and bilayer structure (BLC) have hydrophobicity, flame resistance, good mechanical properties and excellent corrosion resistance performance.

First claim

What is claimed is:

1. A preparation method for a superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material, comprising:
spraying a superhydrophobic/superoleophobic suspension onto a surface of a horizontally placed substrate with a spray gun at a distance of 15 cm in a vertical direction, and then drying the surface in an oven at 120° C. for 6 h; and finally obtaining the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material, wherein
a preparation method for the superhydrophobic/superoleophobic suspension comprises the following steps:
S1, dispersing 15 nm SiO 2 , 50 nm SiO 2 and 25 μm α-cellulose in a mixed solution containing anhydrous ethanol and ammonia, and performing ultrasonic treatment for 30 min;
S2, dropwise adding tetraethyl orthosilicate and perfluorooctane trimethoxy silane to the solution formed in step S1, and stirring the same for 6 h in a water bath at 60° C. to obtain solution A;
S3, dissolving bisphenol A epoxy resin in the anhydrous ethanol solution, and performing ultrasonic oscillation for 30 min to obtain solution B;
S4, adding solution B to solution A in the water bath at 60° C.; after full mixing, quickly injecting the tetraethyl orthosilicate and the perfluorooctane trimethoxy silane into the suspension; and stirring the same at 60° C. for 2 h to obtain solution C, a volume ratio of solution B to solution A being solution A:solution B=8:1;
S5, adding a fluorine-containing curing agent into anhydrous ethanol, and dissolving the fluorine-containing curing agent with ultrasonic waves to obtain solution D; and
S6, adding solution D into solution C, and stirring the same for 20 min; and after full mixing, adding a flame retardant, and stirring the same to obtain a final uniform solution, a volume ratio of solution D to solution C being solution C:solution D=48:5, and the flame retardant being 9,10-dihydro-9-oxa-10-phosphophenanthrene-10-oxide (DOOP);
a preparation method for the fluorine-containing curing agent comprises the following steps:
1) Respectively dissolving heptafluorobutyric acid and 3-(2-aminoethylamino) propyltrimethoxysilane in deionized water;
2) Dropwise adding the heptafluorobutyric acid solution to the 3-(2-aminoethylamino) propyltrimethoxysilane solution; and
3) after the dropwise adding is completed, heating the solution to obtain light yellow colloid which is a fluorine-containing curing agent.

2. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein the substrate is glass, PU foam or a PVC film.

3. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein in step 3), the reaction was performed by heating at 100° C.

4. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein in step S1, in the mixed solution of absolute ethanol and ammonia water, a volume ratio of the absolute ethanol to the ammonia water is (1-5):1.

5. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 4 , wherein in step S1, the volume ratio of the anhydrous ethanol to the ammonia water is 3:1.

6. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein in step S1, a mass ratio of the 15 nm SiO 2 , 50 nm SiO 2 and 25 μm α-cellulose is 1:1:2.

7. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein in step S2, a volume ratio of the tetraethyl orthosilicate to the perfluorooctane trimethoxy silane is 2:1.

8. The preparation method for a superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein in step S4, a volume ratio of the tetraethyl orthosilicate to the perfluorooctane trimethoxy silane is 1:1.

9. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein in step S6, the amount of the DOPO is 1-6% of the total mass of the raw materials.

10. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein the amount of 15 nm SiO 2 is 25% of the total mass of the 15 nm SiO 2 , the 50 nm SiO 2 and the 25 μm α-cellulose, and the content of the DOPO is 6%.

11. The preparation method for the superhydrophobic/superoleophobic flame-resistant and abrasion-resistant coating material according to claim 1 , wherein a mass ratio of the bisphenol A epoxy resin to the fluorine-containing curing agent is 1:1.066.

Assignees

• Univ Qilu Technology
• Zhuhai Tairan Tech Co Ltd

Inventors

• Liu Libin
• Ban Qing
• Jiang Haihui
• Ji Xingxiang
• Tao Furong
• Gai Ligang
• Zhang Hailong
• Bu Xinyu

Classifications

• C09D183/06

  containing silicon bound to oxygen-containing groups (C09D183/12 takes precedence) · CPC title

• C09D163/00

  Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title

• C09D5/18 Primary

  Fireproof paints {including high temperature resistant paints} · CPC title

• B05D2602/00

  Organic fillers · CPC title

• B05D2601/22

  Silica · CPC title