Method for obtaining one or more air products, and air fractionation plant

Patent metadata

Field	Value
Publication number	US-12410974-B2
Application number	US-202118044038-A
Country	US
Kind code	B2
Filing date	Jul 28, 2021
Priority date	Sep 8, 2020
Publication date	Sep 9, 2025
Grant date	Sep 9, 2025

Abstract

A method for obtaining one or more air products, in which method an air fractionation plant is used which has a column system with a pressure column wherein air is fed to the column system and is fractionated in the column system, wherein at least 90% of the total amount of air supplied to the column system is compressed wherein nitrogen-rich gas is extracted from the pressure column, and wherein, at least in a first operating mode, further air is compressed to a pressure level above the base pressure level, is expanded, and is warmed without fractionation in the column system. It is provided that, at least in the first operating mode, a proportion of the nitrogen-rich gas extracted from the pressure column is fed to the further air upstream of the expansion.

First claim

The invention claimed is:

1. A method for obtaining one or more air products, wherein an air fractionation plant is used which has a column system having a pressure column, wherein the pressure column is operated in a pressure range from 4 to 7 bar, wherein air is fed to the column system and fractionated in the column system, wherein at least 90% of the total air supplied to the column system is compressed to a base pressure level which is more than 5 bar above the pressure range at which the pressure column is operated, wherein nitrogen-rich gas is withdrawn from the pressure column, and wherein, at least in a first operating mode, further air is compressed to a pressure level above the base pressure level, is decompressed, and is warmed without fractionation in the column system, wherein, at least in the first operating mode, a portion of the nitrogen-rich gas withdrawn from the pressure column is fed into the further air upstream of the decompression.

2. The method according to claim 1 , wherein the decompression of the further air is carried out in a decompression machine.

3. The method according to claim 1 , wherein, in a second operating mode as well, the further air is compressed to a pressure level above the base pressure level, is decompressed, and is warmed without fractionation in the column system, and wherein, in the second operating mode, none of the nitrogen-rich gas withdrawn from the pressure column is fed into the further air.

4. The method according to claim 3 , wherein, in the third operating mode, no further air is compressed to a pressure level above the base pressure level, decompressed and warmed without fractionation in the column system, and in which, in the third operating mode, a portion of the nitrogen-rich gas withdrawn from the pressure column is decompressed and warmed instead of the further air.

5. The method according to claim 1 , wherein the further air, at the pressure level above the base pressure level, is supplied to the warm side of a main heat exchanger of the air fractionation plant, is then removed from the main heat exchanger at a first intermediate temperature level, is then subjected to a first turbine decompression, is then supplied to the cold side of the main heat exchanger, is then removed from the main heat exchanger at a second intermediate temperature level, is then subjected to a second turbine decompression, is then supplied to the main heat exchanger at a third intermediate temperature level, and is then withdrawn from the warm side of the main heat exchanger.

6. The method according to claim 5 , wherein the portion of the nitrogen-rich gas withdrawn from the pressure column which is fed into the further air is fed to the cold side of the main heat exchanger together with the further air, is subjected to the second turbine decompression, is fed to the main heat exchanger at the third intermediate temperature level, and is withdrawn from the warm side of the main heat exchanger.

7. The method according to claim 5 , wherein the portion of the nitrogen-rich gas withdrawn from the pressure column which is fed to the further air is supplied to the cold side of the main heat exchanger separately from the further air, is withdrawn from the warm side of the main heat exchanger, and is fed to the further air at the second intermediate temperature level and before the second turbine decompression.

8. The method according to claim 5 , wherein the base pressure level is 16 to 24 bar, wherein the pressure level above the base pressure level to which the further air is compressed is 27 to 50 bar, wherein the pressure range in which the pressure column is operated is 4 to 7 bar, wherein the main heat exchanger is operated at a temperature level of 0 to 50° C. on the warm side, and at a temperature level of to −177° C. on the cold side, wherein the first intermediate temperature level is to −90° C., wherein the second intermediate temperature level is to 30° C., wherein the third intermediate temperature level is to −60° C., wherein the first turbine decompression is carried out to a pressure level of 4 to 7 bar, and wherein the second turbine decompression is carried out to a pressure level of 100 to 500 mbar above atmospheric pressure.

9. The method according to claim 5 , wherein the further air is compressed using one or two boosters to the pressure level above the base pressure level, wherein the one booster or at least one of the two boosters is or are driven using at least one of the decompression machines which are used in the first and second turbine decompression.

10. The method according to claim 1 , wherein the column system further comprises a low-pressure column operated in a pressure range from 1 to 1.7 bar, and an argon gas recovery section having at least one further column.

11. The method according to claim 1 , wherein the further air which is compressed to the pressure level above the base pressure level, is decompressed, and is warmed without fractionation in the column system, is compressed to the pressure level above the base pressure level together with air which is fed into the column system.

12. The method according to claim 11 , wherein the air which is fed into the column system and which is compressed together with the further air to the pressure level above the base pressure level is cooled in a first fraction and fed into the column system without being subjected to the first and second decompression, and in a second fraction is separated in liquefied form after the first decompression and fed into the column system.

13. An air fractionation plant comprising a column system having a pressure column, wherein the air fractionation plant is designed to operate the pressure column in a pressure range from 4 to 7 bar, to supply air to the column system, and to fractionate it in the column system, and to compress at least 90% of the total air supplied to the column system to a base pressure level which is more than 5 bar above the pressure range at which the pressure column is operated, to remove nitrogen-rich gas from the pressure column, and, at least in a first operating mode, to compress further air to a pressure level above the base pressure level, to decompress it, and to warm it without fractionation in the column system, wherein the air fractionation plant is designed to feed, at least in the first operating mode, a portion of the nitrogen-rich gas withdrawn from the pressure column to the further air upstream of the decompression.

14. An air fractionation plant having means for carrying out the method features specified in claim 2 .

15. The method according to claim 1 , wherein the decompression of the further air is carried out in a decompression turbine.

Assignees

• Linde Gmbh

Inventors

• Palaniswamy Otte Daniel

Classifications

• F25J2245/42

  the recycled stream being nitrogen · CPC title

• F25J3/04678

  cooled by oxygen enriched liquid from high pressure column bottoms · CPC title

• F25J3/04393

  using multiple or multistage gas work expansion · CPC title

• F25J3/04381

  using work extraction by mechanical coupling of compression and expansion so-called companders · CPC title

• F25J3/04309

  of nitrogen · CPC title