Aqueous binder composition

Patent metadata

Field	Value
Publication number	US-12410349-B2
Application number	US-201917282128-A
Country	US
Kind code	B2
Filing date	Oct 7, 2019
Priority date	Oct 5, 2018
Publication date	Sep 9, 2025
Grant date	Sep 9, 2025

Abstract

The invention is directed to an aqueous binder composition for mineral fibers.

First claim

The invention claimed is:

1. A mineral fiber product, wherein the product comprises mineral fibers in contact with a binder resulting from curing an aqueous binder composition which comprises:
a component (i) in the form of one or more oxidized lignins;
a component (ii) in the form of one or more cross-linkers;
a component (iii) in the form of one or more plasticizers.

2. The mineral fiber product of claim 1 , wherein
component (i) is in the form of one or more oxidized lignins, the lignins being selected from kraft

lignins, soda lignins, lignosulfonate lignins, organosolv lignins, lignins from biorefining processes of lignocellulosic feedstocks, or any mixture thereof.

3. The mineral fiber product of claim 1 , wherein component (i) is in the form of one or more oxidized kraft lignins.

4. The mineral fiber product of claim 1 , wherein component (i) is in the form of one or more oxidized soda lignins.

5. The mineral fiber product of claim 1 , wherein component (i) is in the form of one or more ammonia-oxidized lignins.

6. The mineral fiber product of claim 5 , wherein the ammonia-oxidized lignin comprises one or more compounds selected from ammonia, amines, or any salts thereof.

7. The mineral fiber product of claim 1 , wherein component (i) has a carboxylic acid group content of from 0.05 to 10 mmol/g, based on a dry weight of component (i).

8. The mineral fiber product of claim 1 , wherein component (i) has an average carboxylic acid group content of more than 1.5 groups per macromolecule of component (i).

9. The mineral fiber product of claim 1 , wherein component (ii) is in the form of one or more cross-linkers selected from β-hydroxyalkylamide-cross-linkers and oxazoline-cross-linkers.

10. The mineral fiber product of claim 1 , wherein component (ii) comprises one or more cross-linkers selected from multifunctional organic amines.

11. The mineral fiber product of claim 1 , wherein component (ii) comprises one or more flexible oligomers or polymers or an epoxidized oil based on a fatty acid triglyceride.

12. The mineral fiber product of claim 1 , wherein component (ii) comprises a molecule having 3 or more epoxy groups.

13. The mineral fiber product of claim 1 , wherein component (ii) is present in a concentration of from 1 to 40 wt.-%, based on a dry weight of component (i).

14. The mineral fiber product of claim 1 , wherein component (iii) comprises one or more plasticizers selected from polyethylene glycols, polyethylene glycol ethers, polyethers, hydrogenated sugars, phthalates and/or acids, acrylic polymers, polyvinyl alcohol, polyurethane dispersions, ethylene carbonate, propylene carbonate, lactones, lactams, lactides, acrylic based polymers with free carboxy groups and/or polyurethane dispersions with free carboxy groups.

15. The mineral fiber product of claim 1 , wherein component (iii) comprises one or more plasticizers having a boiling point of from 100° C. to 280° C.

16. The mineral fiber product of claim 1 , wherein component (iii) comprises one or more polyethylene glycols having an average molecular weight of from 150 to 50,000 g/mol.

17. The mineral fiber product of claim 1 , wherein component (iii) is present in a concentration of from 0.5 to 50 wt.-%, based on a dry weight of component (i).

18. The mineral fiber product of claim 1 , wherein the binder composition consists essentially of
a component (i) in the form of one or more oxidized lignins;
a component (ii) in the form of one or more cross-linkers;
a component (iii) in the form of one or more plasticizers;
a component (iv) in the form of one or more coupling agents;
optionally a component in the form of one or more compounds selected from ammonia, amines, or any salts thereof;
optionally a component in the form of urea;
optionally a component in the form of one or more reactive or non-reactive silicones;
optionally a hydrocarbon oil;
optionally one or more surface active agents;
water.

19. A method of producing a bonded mineral fiber product, wherein the method comprises contacting mineral fibers with an aqueous binder composition and curing the binder composition, the binder composition comprising:
a component (i) in the form of one or more oxidized lignins;
a component (ii) in the form of one or more cross-linkers;
a component (iii) in the form of one or more plasticizers.

20. An aqueous binder composition, wherein the composition in its cured state is capable of binding mineral fibers to afford a bonded mineral fiber product, and comprises:
a component (i) in the form of one or more oxidized lignins;
a component (ii) in the form of one or more cross-linkers;
a component (iii) in the form of one or more plasticizers.

21. The mineral fiber product of claim 1 , wherein component (iii) comprises one or more polyethylene glycols.

22. The mineral fiber product of claim 1 , wherein component (i) is in the form of one or more oxidized lignins, the lignins being selected from kraft lignins, soda lignins, organosolv lignins, lignins from Biorefining processes of lignocellulosic feedstocks, or any mixture thereof.

23. The mineral fiber product of claim 1 , wherein component (ii) is in the form of one or more cross-linkers selected from β-hydroxyalkylamide-cross-linkers and/or oxazoline-cross-linkers, one or more flexible oligomers or polymers, an epoxidized oil based on a fatty acid triglyceride, and a molecule having 3 or more epoxy groups, and component (iii) is in the form of one or more plasticizers comprising one or more polyethylene glycols.

24. The mineral fiber product of claim 23 , wherein component (iii) comprises one or more polyethylene glycols having an average molecular weight of 150 to 50,000 g/mol.

25. The mineral fiber product of claim 23 , wherein component (ii) is in the form of one or more cross-linkers selected from β-hydroxyalkylamide-cross-linkers and/or oxazoline-cross-linkers.

26. The mineral fiber product of claim 23 , wherein component (i) is in the form of one or more oxidized lignins, the lignins being selected from kraft lignins, soda lignins, organosolv lignins, lignins from Biorefining processes of lignocellulosic feedstocks, or any mixture thereof.

27. The mineral fiber product of claim 23 , wherein component (i) is in the form of one or more oxidized kraft lignins or one or more oxidized soda lignins.

28. The mineral fiber product of claim 1 , wherein component (ii) is in the form of one or more cross-linkers selected from β-hydroxyalkylamide-cross-linkers and/or oxazoline-cross-linkers, and component (iii) is in the form of one or more plasticizers comprising one or more polyethylene glycols having an average molecular weight of 150 to 50,000 g/mol.

Assignees

• Rockwool Int
• Rockwool As

Inventors

• Johansson Dorte Bartnik
• Johannsen Ib
• Kilsgaard Bjørn Sjøgren
• Nikolic Miroslav

Classifications

• D04H1/64

  the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions · CPC title

• D04H1/587

  characterised by the bonding agents used · CPC title

• D04H1/4209

  Inorganic fibres · CPC title

• C07G1/00

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title

• C03C25/36

  Epoxy resins · CPC title