Sheet-like material
US-11441033-B2 · Sep 13, 2022 · US
US12410316B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12410316-B2 |
| Application number | US-202017773009-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 10, 2020 |
| Priority date | Oct 28, 2019 |
| Publication date | Sep 9, 2025 |
| Grant date | Sep 9, 2025 |
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A water-containing urethane resin composition that is produced using a biomass raw material and excellent in oleic acid resistance, texture, and liquid mixture stability. A urethane resin composition including: a urethane resin (A) having an anionic group and a nonionic group and produced using as a raw material a polycarbonate polyol (a1) produced using biomass-derived decanediol as a raw material; a nonionic emulsifier (B); and water (C). A leather sheet in which a coagulated product of the urethane resin composition is present in a fibrous substrate. Both the urethane resin (A) and the nonionic emulsifier (B) preferably have an oxyethylene group and an oxypropylene group.
Opening claim text (preview).
The invention claimed is: 1. A urethane resin composition, comprising: a urethane resin (A) having an anionic group and a nonionic group and produced using as a raw material a polycarbonate polyol (a1) produced using biomass-derived decanediol as a raw material; a nonionic emulsifier (B); and water (C). 2. The urethane resin composition according to claim 1 , wherein the nonionic emulsifier (B) has an oxyethylene group and an oxypropylene group. 3. The urethane resin composition according to claim 1 , wherein the polycarbonate polyol (a1) is produced further using butanediol as a raw material. 4. The urethane resin composition according to claim 3 , wherein a molar ratio [(C4)/(C10)] of the butanediol (C4) to the biomass-derived decanediol (C10) in the polycarbonate polyol (a1) is within a range of 5/95 to 95/5. 5. The urethane resin composition according to claim 1 , wherein the nonionic group in the urethane resin (A) includes an oxyethylene group and an oxypropylene group. 6. The urethane resin composition according to claim 5 , wherein the oxyethylene group and the oxypropylene group are supplied from a polyol having an oxyethylene group and an oxypropylene group. 7. A leather sheet, comprising a coagulated product of the urethane resin composition according to claim 1 present in a fibrous substrate.
characterised by the macromolecular diols used · CPC title
Cyclic ethers having no atoms other than carbon and hydrogen outside the ring · CPC title
saturated · CPC title
containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups · CPC title
Polycarbonates · CPC title
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