Monovalent anion selective ion exchange membrane

Patent metadata

Field	Value
Publication number	US-12410290-B2
Application number	US-202017635313-A
Country	US
Kind code	B2
Filing date	Aug 18, 2020
Priority date	Aug 16, 2019
Publication date	Sep 9, 2025
Grant date	Sep 9, 2025

Abstract

Provided are a monovalent anion selective ion exchange membrane and a method of manufacturing the ion exchange membrane. In regard to the monovalent anion selective ion exchange membrane, a surface portion thereof has a high amount ratio of a cation exchange polymer electrolyte, a central portion thereof has a high amount ratio of an anion exchange polymer electrolyte, and an amount ratio of the anion exchange polymer electrolyte with respect to the cation exchange polymer electrolyte continuously increases in the thickness direction thereof from the surface toward the center. Due to this structure, compared to monovalent anions, polyvalent anions may permeate much less through the exchange membrane. Thus, high selectivity for monovalent anions may be obtained.

First claim

The invention claimed is:

1. A monovalent anion selective ion exchange membrane, comprising:
a polymer support having a porous structure; and
an ion exchange polymer electrolyte impregnated in the porous polymer support,
wherein the ion exchange polymer electrolyte includes an anion exchange polymer electrolyte and a cation exchange polymer electrolyte,
a central portion of the porous polymer support is impregnated with the anion exchange polymer electrolyte,
a surface portion of the porous polymer support is impregnated with a cation exchange polymer electrolyte, and
the porous polymer support has a pore volume of 40% to 50%, a pore size of 0.07 μm to 0.1 μm, and a thickness of 8 μm to 30 μm.

2. The monovalent anion selective ion exchange membrane of claim 1 , wherein an amount ratio of the anion exchange polymer electrolyte to the cation exchange polymer electrolyte has a relationship of Equation 1:
A≥B.  [Equation 1]

wherein, in Equation 1,
A is an amount ratio of the anion exchange polymer electrolyte to the cation exchange polymer electrolyte, in the central portion of the porous polymer support,
B is an amount ratio of the anion exchange polymer electrolyte to the cation exchange polymer electrolyte, in the surface portion of the porous polymer support,
the central portion is an area from the surface to a depth of 20% to 80% in the direction from the surface to the center with respect to 100% of the thickness of the porous polymer support, and
the surface portion is an area from the surface to a depth of 0% to 20% in the direction from the surface to the center with respect to 100% of the thickness of the porous polymer support.

3. The monovalent anion selective ion exchange membrane of claim 1 , wherein as being closer to the center from the surface in the thickness direction of the porous polymer support, the amount ratio of the anion exchange polymer electrolyte to the cation exchange polymer electrolyte is increased.

4. The monovalent anion selective ion exchange membrane of claim 1 , wherein an amount of the cation exchange polymer electrolyte is 10 parts by weight to 40 parts by weight based on 100 parts by weight of the anion exchange polymer electrolyte.

5. The monovalent anion selective ion exchange membrane of claim 1 , wherein the cation exchange polymer electrolyte is obtained by crosslinking polymerization of a sulfonic acid-containing electrolyte monomer having an anionic group.

6. The monovalent anion selective ion exchange membrane of claim 5 , wherein the sulfonic acid-containing electrolyte monomer having an anionic group includes a material selected from 2-acrylamide-2-methylpropanesulfonate sodium, vinylsulfonate sodium, vinylsulfonic acid, allyl sulfonate sodium, 2-methyl-2-propene-1-sulfonate sodium, 3-sulfopropyl acrylate sodium, and combinations thereof.

7. The monovalent anion selective ion exchange membrane of claim 1 , wherein the anion exchange polymer electrolyte is obtained by crosslinking polymerization of an electrolyte monomer of a quaternary ammonium salt having a cationic group.

8. The monovalent anion selective ion exchange membrane of claim 7 , wherein the electrolyte monomer of a quaternary ammonium salt having a cationic group includes a material selected from (3-acrylamidopropyl)trimethylammonium chloride, (vinylbenzyl)trimethylammonium chloride, and combinations thereof.

9. The monovalent anion selective ion exchange membrane of claim 1 , wherein a thickness ratio of the monovalent anion selective ion exchange membrane to a thickness of the porous polymer support is 1.0 to 1.03.

10. A method of manufacturing a monovalent anion selective ion exchange membrane, the method comprising:
impregnating a porous polymer support with an anion exchange precursor solution comprising an electrolyte monomer having a cationic group, a crosslinking agent, an initiator, and a solvent;
forming an anion exchange polymer electrolyte in a central portion of the porous polymer support by irradiating light to the porous polymer support to cause a crosslinking reaction of the anion exchange precursor solution;
impregnating the porous polymer support having the anion exchange polymer electrolyte formed therein, with a cation exchange precursor solution including an electrolyte monomer having an anionic group, a crosslinking agent, an initiator, and a solvent; and
forming a cation exchange polymer electrolyte on the surface portion of the porous polymer support by irradiating light to the porous polymer support impregnated with the cation exchange precursor solution, to cause a crosslinking reaction of the cation exchange precursor solution,
wherein the porous polymer support is hydrophilized by a surfactant before being impregnated with the anion exchange precursor solution.

11. The method of claim 10 , wherein the electrolyte monomer having a cationic group is a quaternary ammonium salt electrolyte monomer.

12. The method of claim 10 , wherein the electrolyte monomer having an anionic group is a sulfonic acid-containing electrolyte monomer.

Assignees

• Toray Advanced Mat Korea Inc

Inventors

• Choi Young Woo

Classifications

• B01J41/13

  obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds · CPC title

• B01J41/09

  Organic material · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/227

  Dialytic cells or batteries; Reverse electrodialysis cells or batteries · CPC title

• H01M8/1062

  characterised by the physical properties of the porous support, e.g. its porosity or thickness · CPC title