Preparation of ion exchange membranes from polyolefins and polycyclic olefins

US12410289B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-12410289-B2
Application numberUS-201917282512-A
CountryUS
Kind codeB2
Filing dateOct 7, 2019
Priority dateOct 5, 2018
Publication dateSep 9, 2025
Grant dateSep 9, 2025

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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Abstract

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Ion exchange membranes for use in electrochemical energy conversion and storage applications include copolymers having a backbone produced from an olefin, such as ethylene, and a cyclic olefin, such as norbornene. Haloalkyl side chains with terminal halide groups are connected to the polymer backbone via Friedel-Crafts alkylation. The halide groups are then replaced with ionic groups via substitution. The ion exchange membrane material can then be cast or impregnated into a reinforcing mesh to form cation exchange membrane or anion exchange membranes. Rigidity of the ion exchange membranes can be controlled by varying the ratio of olefin to cyclic olefin in the polymer backbone.

First claim

Opening claim text (preview).

What is claimed is: 1. An ion exchange membrane material comprising a polymer according to Formula II: wherein m+n=1, x≥2, Ak is a hydrocarbyl group, and R3 is an ionic group, a polar group, or combinations thereof. 2. The ion exchange membrane material according to claim 1 , wherein R3 includes one or more ammonium groups, one or more multication hydrocarbyl chains, one or more spiro-type ammonium groups, one or more sulfonate groups, one or more phosphonate groups, one or more carboxylate groups, one or more alcohols, one or more amines, or combinations thereof. 3. The ion exchange membrane material according to claim 1 , wherein m is between about 0.1 and about 0.5.

Assignees

Inventors

Classifications

  • Fuel cells · CPC title

  • with aliphatic cyclic olefins · CPC title

  • grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

  • Metallocene catalysts · CPC title

  • with non-conjugated dienes, e.g. EPT rubbers · CPC title

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What does patent US12410289B2 cover?
Ion exchange membranes for use in electrochemical energy conversion and storage applications include copolymers having a backbone produced from an olefin, such as ethylene, and a cyclic olefin, such as norbornene. Haloalkyl side chains with terminal halide groups are connected to the polymer backbone via Friedel-Crafts alkylation. The halide groups are then replaced with ionic groups via substi…
Who is the assignee on this patent?
Rensselaer Polytech Inst
What technology area does this patent fall under?
Primary CPC classification C08J5/2243. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Sep 09 2025 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 1 related publication on this page (citations in our corpus or others sharing the same primary CPC).