Fluorolactone and method for producing same

Patent metadata

Field	Value
Publication number	US-12410150-B2
Application number	US-202117398257-A
Country	US
Kind code	B2
Filing date	Aug 10, 2021
Priority date	Feb 12, 2019
Publication date	Sep 9, 2025
Grant date	Sep 9, 2025

Abstract

The present disclosure provides, for example, a method that can produce a fluorolactone compound from hexafluoropropylene oxide or the like in a single step. The present disclosure relates to a method for producing a compound represented by formula (1):

wherein two R 1 are the same and each is a fluorine atom or a fluoroalkyl group,
the method comprising step A of reacting a compound represented by formula (2):

wherein R 1 is as defined above, with a compound (3) represented by formula (3-1) or the like:

wherein R 31 , R 32 , and R 33 are the same or different and each is a hydrogen atom or a C 1-10 alkyl group, or two of them are optionally linked to each other to form a ring optionally having one or more substituents,

in the presence of a fluorine compound (4) represented by formula (4-1) or the like:

MH n F m   (4-1)

wherein M is a metal atom, n is 0 or 1, and the sum of the valence number of M and n is m, and

an organic solvent, provided that the compound represented by formula (3) is excluded from the organic solvent.

First claim

The invention claimed is:

1. A composition comprising a compound represented by formula (5):

wherein R 1 is a fluorine atom or a fluoroalkyl group, and 0.00001 to 0.1 parts by mass of CsF based on 100 parts by mass of the compound represented by formula (5), and further comprising, based on 100 parts by mass of the compound represented by formula (5), 0.00001 to 1 part by mass of a compound represented by formula (9):

wherein two R 1 are as defined above, and/or 0.00001 to 1 part by mass of a compound represented by formula (10):

wherein two R 1 are as defined above.

2. The composition according to claim 1 , wherein the compound represented by formula (9) is contained in an amount of 0.00001 to 0.5 parts by mass, and/or the compound represented by formula (10) is contained in an amount of 0.00001 to 0.5 parts by mass, based on 100 parts by mass of the compound represented by formula (5).

Assignees

• Daikin Ind Ltd

Inventors

• Hosokawa Moe
• Hayashi Koutarou
• Yamamoto Yoshihiro
• Yamauchi Akiyoshi
• Kishikawa Yosuke
• Suzuki Yuuki
• Ogata Akitoshi
• Matsuura Makoto

Classifications

• C07D317/42 Primary

  Halogen atoms or nitro radicals · CPC title

• C07D319/12 Primary

  not condensed with other rings · CPC title