Crystallization method of gypsum

Patent metadata

Field	Value
Publication number	US-12410095-B2
Application number	US-202117790149-A
Country	US
Kind code	B2
Filing date	Oct 29, 2021
Priority date	Sep 2, 2021
Publication date	Sep 9, 2025
Grant date	Sep 9, 2025

Abstract

Wasted gypsum boards are crushed and calcined to gypsum granular solid, and the gypsum granular solid is mixed with water to form gypsum slurry. Gypsum particles are deposited from the gypsum slurry in a crystallization tank. Heated steam is blown into the gypsum slurry at a height from surface of the gypsum slurry and down to upper ⅕ of the gypsum slurry to heat the gypsum slurry and to eliminate foam on the gypsum slurry.

First claim

The invention claimed is:

1. A method of reclaiming gypsum particles from wasted gypsum boards, the method comprising:
crushing and calcining wasted gypsum boards to gypsum granular solid,
mixing the gypsum granular solid with water to form gypsum slurry in a mixing tank,
generating gypsum particles in the gypsum slurry in at least a crystallization tank wherein surfactants from the wasted gypsum boards cause foam on the gypsum slurry, and
blowing heated steam into the gypsum slurry in the crystallization tank at a height between a top surface of the gypsum slurry and ⅕ below the top surface of the gypsum slurry so that the gypsum slurry is heated only by the heated steam, and the foam on the gypsum slurry is eliminated by the heated steam.

2. The method of reclaiming gypsum particles according to claim 1 , wherein the gypsum slurry is maintained at a predetermined temperature without a thermal source, other than the heated steam, provided in said at least a crystallization tank.

3. The method of reclaiming gypsum particles according to claim 1 ,
wherein said at least a crystallization tank comprises plural crystallization tanks in series, the gypsum slurry which is resultant by mixing the gypsum granular solid with water is supplied into a most upstream crystallization tank, the gypsum slurry is moved from an upstream tank to a downstream tank, and the heated steam is only blown into the most upstream crystallization tank.

4. The method of reclaiming gypsum particles according to claim 1 , wherein said heated steam at a point where the heated steam is blown into the gypsum slurry is at 100 to 150 degree Celsius and has 1.2 to 3 atmospheric pressure in absolute pressure.

5. The method of reclaiming gypsum particles according to claim 4 , wherein said heated steam heats the gypsum slurry to a temperature from above room temperature to not higher than 90 degree Celsius.

Assignees

• Tokuyama Corp

Inventors

• Hiranaka Shingo

Classifications

• C01F11/466

  Conversion of one form of calcium sulfate to another · CPC title

• C01F11/468

  Purification of calcium sulfates · CPC title

• B09B3/45 Primary

  Steam treatment, e.g. supercritical water gasification or oxidation · CPC title

• C04B11/262 Primary

  waste gypsum other than phosphogypsum · CPC title