Application of cyclodextrins (cds) for remediation of perfluoroalkyl substances (pfass)
US-2018282530-A1 · Oct 4, 2018 · US
US12410071B1 · US · B1
| Field | Value |
|---|---|
| Publication number | US-12410071-B1 |
| Application number | US-202117505516-A |
| Country | US |
| Kind code | B1 |
| Filing date | Oct 19, 2021 |
| Priority date | Oct 19, 2020 |
| Publication date | Sep 9, 2025 |
| Grant date | Sep 9, 2025 |
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A system and method for removing PFAS from residual waste streams generated during the processing of landfill liquids prior to disposal are provided. An example of a landfill liquid is leachate. Landfill leachate can contain dissolved or entrained environmentally harmful substances such as PFAS and other emerging contaminant micro-constituents that may enter the environment if not properly treated. The presently disclosed system and method can improve the removal of PFAS and other emerging contaminant micro-constituents in landfill leachate and/or landfill impacted liquids including stormwater and contaminated groundwater.
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What is claimed is: 1. A method of removing per- and poly-fluoroalkyl substances (PFAS) from a leachate stream, the method comprising: introducing the leachate stream comprising per- and poly-fluoroalkyl substances into a primary treatment module, wherein the primary treatment module comprises a solids removal vessel that is configured to remove solids from the leachate stream using membrane filtration and produce an effluent stream; and passing the effluent stream directly from the solids removal vessel into a secondary treatment module comprising an adsorptive organic/clay based material and configured to adsorb microconstituents from the effluent stream, wherein there is no removal of total organic carbon (TOC) in a TOC removal vessel prior to adsorption occurring in the secondary treatment module, and wherein the secondary treatment module produces a treated leachate stream that is substantially devoid of per- and poly-fluoroalkyl substances. 2. The method of claim 1 , wherein the membrane filtration is at least one of nano-filtration and micro-filtration. 3. The method of claim 1 , wherein the secondary treatment module further comprises an ion exchange media resin treatment. 4. A method of removing per- and poly-fluoroalkyl substances (PFAS) from a leachate stream, the method comprising: introducing the leachate stream comprising per- and poly-fluoroalkyl substances into a primary treatment module consisting essentially of a solids removal vessel that is configured to remove solids from the leachate stream using membrane filtration and produce an effluent stream; and introducing the effluent stream directly into a secondary treatment module comprising an adsorptive organic/clay based material and configured to adsorb microconstituents from the effluent stream, wherein the secondary treatment module produces a treated leachate stream that is substantially devoid of per- and poly-fluoroalkyl substances. 5. The method of claim 4 , wherein the membrane filtration is at least one of nano-filtration and micro-filtration. 6. The method of claim 4 , wherein the secondary treatment module further comprises an ion exchange media resin treatment. 7. A method of removing per- and poly-fluoroalkyl substances (PFAS) from a leachate stream, the method comprising: storing leachate comprising per- and poly-fluoroalkyl substances in a storage vessel; introducing leachate from the storage vessel directly into a primary treatment module using the leachate stream, wherein the primary treatment module consists essentially of a solids removal vessel that is configured to remove solids from the leachate stream using membrane filtration and produce an effluent stream; and passing the effluent stream directly from the primary treatment module into a secondary treatment module comprising an adsorptive organic/clay based material and configured to adsorb microconstituents from the effluent stream, wherein the secondary treatment module produces a treated leachate stream that is substantially devoid of per- and poly-fluoroalkyl substances. 8. The method of claim 7 , wherein the membrane filtration is at least one of nano-filtration and micro-filtration. 9. The method of claim 7 , wherein the secondary treatment module further comprises an ion exchange media resin treatment. 10. A method of removing per- and poly-fluoroalkyl substances (PFAS) from a leachate stream, the method comprising: storing leachate comprising per- and poly-fluoroalkyl substances in a storage vessel; introducing leachate from the storage vessel directly into a solids removal vessel using the leachate stream, wherein the solids removal vessel is configured to remove solids from the leachate stream using membrane filtration to produce an effluent stream; and passing the effluent stream directly from the solids removal vessel into an adsorption treatment vessel configured to adsorb microconstituents from the effluent stream using an adsorptive organic/clay based material, wherein the adsorption treatment vessel produces a treated leachate stream that is substantially devoid of per- and poly-fluoroalkyl substances. 11. The method of claim 10 , wherein the membrane filtration is at least one of nano-filtration and micro-filtration. 12. The method of claim 10 , further comprising passing the treated leachate stream through an ion exchange media resin treatment.
by reverse osmosis · CPC title
Multistage treatment of water, waste water or sewage · CPC title
using coal, charred products, or inorganic mixtures containing them · CPC title
by ion-exchange (ion-exchange in general B01J) · CPC title
by ultrafiltration or microfiltration · CPC title
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