Mixtures of discrete carbon nanotubes

Patent metadata

Field	Value
Publication number	US-12410057-B2
Application number	US-202117335998-A
Country	US
Kind code	B2
Filing date	Jun 1, 2021
Priority date	Oct 11, 2017
Publication date	Sep 9, 2025
Grant date	Sep 9, 2025

Abstract

Dry liquid concentrates allow carbon nanotubes to be dispersed in various mediums under standard composite processing conditions. The incorporation of carbon nanotubes can enhance the physical properties of the resulting material, such as, for example, improving the anti-corrosive properties of thermosets if present, and/or improving electrical properties of transitional metal oxide composites.

First claim

We claim:

1. A mixture comprising tangled carbon nanotubes and discrete carbon nanotubes, wherein the average particle size of the carbon nanotubes in the mixture is from about 15 to about 85 microns and wherein the amount of tangled carbon nanotubes is from about 20 to about 80 percent based on the total weight of carbon nanotubes in the mixture; and at least one solvent; wherein the mixture further comprises side groups attached to the carbon nanotube exterior surface wherein the side groups comprise a molecular weight greater that 50 daltons.

2. The mixture of claim 1 wherein the amount of tangled carbon nanotubes is from about 25 to about 70 percent based on the total weight of carbon nanotubes in the mixture.

3. The mixture of claim 1 wherein the amount of tangled carbon nanotubes is from about 50 to about 60 percent based on the total weight of carbon nanotubes in the mixture.

4. The mixture of claim 1 wherein the average particle size of the carbon nanotubes in the mixture is from about 25 to about 75 microns.

5. The mixture of claim 1 wherein the average particle size of the carbon nanotubes in the mixture is from about 35 to about 65 microns.

6. The mixture of claim 1 wherein the average particle size of the carbon nanotubes in the mixture is from about 40 to about 60 microns.

7. The mixture of claim 2 wherein more than about 80% of the discrete carbon nanotubes in the mixture have a particle size of less than about 30 microns.

8. The mixture of claim 1 wherein more than about 90% of the discrete carbon nanotubes in the mixture have a particle size of less than about 30 microns.

9. The mixture of claim 1 wherein the solvent is water.

10. The mixture of claim 1 wherein the solvent is selected from the group consisting of xylene, N-methyl-2-pyrrolidone, methyl ethyl ketone, isopropanol, water, and mixtures thereof.

11. The mixture of claim 1 wherein the carbon nanotubes comprise multi-wall carbon nanotubes.

12. The mixture of claim 1 further comprising at least one thermoset.

13. The mixture of claim 1 further comprising a transition metal oxide.

14. The mixture of claim 13 further comprising a binder material selected from the group consisting of thermoplastic materials.

15. The mixture of claim 13 further comprising a binder material selected from the group consisting of thermoplastic materials having at least one of the monomer units of vinylidene fluoride, carboxymethyl cellulose, carboxy ethyl cellulose, acrylic acid, alkylacrylic acid, vinyl alcohol, vinyl acetate, vinylbutyral, sulfonated polystyrene, styrene-butadiene, and styrene-hydrogenated butadiene.

16. The mixture of claim 1 wherein the discrete carbon nanotubes comprise a total amount of oxidized species content of less than about 3 percent relative to total discrete carbon nanotube weight.

17. The mixture of claim 1 further comprising a transition metal oxide selected from the group consisting of lithium nickel manganese cobalt, lithium iron phosphate, and lithium nickel manganese oxide.

18. The mixture of claim 1 further comprising a surfactant.

19. The mixture of claim 18 wherein the surfactant is selected from the class of anionic, cationic, non-ionic and zwitterionic surfactants.

Assignees

• Molecular Rebar Design Llc

Inventors

• Peddini Sateesh Kumar
• Krupp August Charles
• Henderson Nancy
• Swogger Kurt W
• Bosnyak Clive P

Classifications

• C01G53/44

  containing manganese · CPC title

• C01B25/45

  containing plural metal, or metal and ammonium · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C08L15/005

  Hydrogenated nitrile rubber · CPC title

• C08L9/02

  Copolymers with acrylonitrile · CPC title