Synthesis gas on demand

Patent metadata

Field	Value
Publication number	US-12410054-B2
Application number	US-202017637539-A
Country	US
Kind code	B2
Filing date	Sep 24, 2020
Priority date	Oct 1, 2019
Publication date	Sep 9, 2025
Grant date	Sep 9, 2025

Abstract

A method is provided for rapidly switching a metal-catalysed steam methane reforming reaction of a feed gas from a first steady-state reaction condition (A) to a second steady-state reaction condition (B) or vice-versa. After applying a given voltage and/or feed gas flow, the system can work towards a thermal equilibration to reach steady state without any additional operator input.

First claim

The invention claimed is:

1. A method for rapidly switching a metal-catalysed steam methane reforming reaction of a feed gas comprising hydrocarbons in a reactor system from a first steady-state reaction condition (A) to a second steady-state reaction condition (B) or vice-versa;
wherein said reactor system comprises a pressure shell housing a structured catalyst arranged to catalyze steam reforming of a feed gas comprising hydrocarbons, said structured catalyst comprising a macroscopic structure of an electrically conductive material, said macroscopic structure supporting a ceramic coating, where said ceramic coating supports a catalytically active material and wherein said reactor system is provided with heat insulation between said structured catalyst and said pressure shell, and where a power supply placed outside said pressure shell is arranged to supply electrical power via electrical conductors connecting to said structured catalyst, allowing an electrical current to run through said macroscopic structure, thereby heating at least part of the structured catalyst;
said method comprising the steps of:
in said first steady-state reaction condition (A):
supplying said feed gas to the reactor system in a first total flow, and
supplying a first electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, thereby allowing a first electrical current to run through said electrically conductive material,

thereby heating at least part of the structured catalyst to a first temperature at which said feed gas is converted to a first product gas mixture over said structured catalyst under said first steady-state reaction conditions (A); and said first product gas is outlet from the reactor system;
and, in said second steady-state reaction condition (B):
supplying said feed gas to the reactor system in a second total flow,
supplying a second electrical power via electrical conductors connecting an electrical power supply placed outside said pressure shell to said structured catalyst, thereby allowing a second electrical current to run through said electrically conductive material,

thereby heating at least part of the structured catalyst to a second temperature; at which said feed gas is converted to a second product gas mixture over said structured catalyst under said second steady-state reaction conditions (B); and said second product gas is outlet from the reactor system;
wherein said second electrical power is higher than said first electrical power; and/or said second total flow is higher than said first total flow.

2. The method according to claim 1 , wherein said at least two conductors are connected to the structured catalyst at a position on the structured catalyst closer to said first end of said structured catalyst than to said second end of said structured catalyst, and wherein the structured catalyst is constructed to direct an electrical current to run from one conductor substantially to the second end of the structured catalyst and return to a second of said at least two conductors.

3. The method according to claim 1 , wherein the ratio of total gas feed flow in said first reaction condition A to said second reaction condition B (A:B) is at least 1:10.

4. The method according to claim 1 , wherein the product gas outlet temperature from the structured catalyst in reaction condition B is between 50° C. to 800° C. higher than the product gas outlet temperature from the structured catalyst in reaction condition A.

5. The method according to claim 1 , wherein the switch between reaction condition A and B includes a gradual change of the total gas feed flow from said first total flow to said second total flow and simultaneous gradual change of the applied electrical potential over said electrically conductive material from said first to said second electrical power.

6. The method according to claim 1 , wherein the product gas outlet temperature from the structured catalyst in reaction condition B is no more than 50° C. higher than the product gas outlet temperature from the structured catalyst in reaction condition A.

7. The method according to claim 1 , wherein a proportional-integral-derivative (PID) controller controls the electrical potential based on feedback reading of the process value of product gas outlet temperature from the structured catalyst.

8. The method according to claim 1 , wherein the product gas outlet temperature from the structured catalyst is measured directly beneath or on the most downstream surface of the structured catalyst.

9. The method according to claim 1 , wherein the switch between reaction condition A and B takes place over a period of less than 3 hours.

10. The method according to claim 1 , wherein the switch between reaction condition A and B involves supplying a second electrical power to the structured catalyst.

11. The method according to claim 1 , wherein the switch between reaction condition A and B comprises a transition state between said reaction conditions A and B; said transition state comprising a first period in which the electrical power is switched off, followed by a second period in which said second electrical power of condition B is supplied to the structured catalyst.

12. The method according to claim 1 , wherein the switch between reaction condition A and B comprises a transition state between said reaction conditions A and B; said transition state comprising a first period in which a third electrical power is supplied to the structured catalyst, followed by a second period in which said second electrical power of condition B is supplied to the structured catalyst, said third electrical power being higher than the second electrical power.

Assignees

• Haldor Topsoe As

Inventors

• Mortensen Peter Mølgaard
• Larsen Kasper Emil
• Aasberg-Petersen Kim

Classifications

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B2203/085

  by electric heating · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• B01J2219/00135

  Electric resistance heaters · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title