Perovskite layer, fabrication method and use the same

Patent metadata

Field	Value
Publication number	US-12408548-B2
Application number	US-202318499651-A
Country	US
Kind code	B2
Filing date	Nov 1, 2023
Priority date	Nov 1, 2023
Publication date	Sep 2, 2025
Grant date	Sep 2, 2025

Abstract

A perovskite layer for use in a solar cell includes a mixture of a halide perovskite and a sulfonyl naphthoquinone-based compound having a structure of Formula (I). Methods for fabricating the perovskite layer and a solar cell including a first active layer of the perovskite layer are also addressed.

First claim

The invention claimed is:

1. A perovskite layer for use in a solar cell comprising a mixture of a mixed-halide perovskite and a sulfonyl naphthoquinone-based compound with a structure of any one of Formula (II), (III), (IV), (V), (VI), or (VII):

wherein:
R 1 is independently selected from one of OM, OR 4 , and NR 5 R 6 , with M being a cation selected from the group consisting of H + , Na + , K + , Cs + , Rb + , Sr 2+ , Ca 2+ , Ni 2+ , Cu 2+ , Co 2+ , Zn 2+ , Mg 2+ , Ba 2+ , Li + , ammonium ion, and aminum ion;
R 4 , R 5 and R 6 are independently selected from the group consisting of hydrogen, substituted or unsubstituted C1 to C4 alkyl, substituted or unsubstituted C2 to C6 alkenyl, substituted or unsubstituted C2 to C6 alkynyl, halogen, unsubstituted C6 to C10 aryl, —CN, —C(═O)OH, —C(═O)H, —C(═O)R 7 , —OR 7 , —SH, —SR 7 , —NH 2 , —NHR 6 , —N(R 7 ) 2 , —Si(R 7 ) 3 , —OSi(R 7 ) 3 , —S(O)OH and —P(O)(OH) 2 where R 7 is an alkyl or a phenyl, and n being 1-1000;
wherein the sulfonyl naphthoquinone-based compound does not include a porphyrin, and is arranged to suppress halide segregation in the mixed-halide perovskite.

2. The perovskite layer as claimed in claim 1 , wherein the sulfonyl naphthoquinone-based compound of Formula (II) is selected from any one of Formula (VIII), Formula (IX), or Formula (X):

with M being H + , ammonium ion or aminum ion; R 4 being C1 to C4 alkyl; R 5 and R 6 being independently selected from hydrogen and C1 to C4 alkyl.

3. The perovskite layer as claimed in claim 2 , wherein the sulfonyl naphthoquinone-based compound of Formula (VIII) is selected from any one of Formula (VIIIa), (VIIIb), and (VIIIc):

4. The perovskite layer as claimed in claim 2 , wherein the sulfonyl naphthoquinone-based compound comprises a structure of Formula (IXa):

5. The perovskite layer as claimed in claim 2 , wherein the sulfonyl naphthoquinone-based compound comprises a structure of Formula (Xa):

6. The perovskite layer as claimed in claim 1 , wherein the mixed-halide perovskite comprises a crystal grain structure of [A +1 B +2 X −1 3 ], with A +1 being an A-site monovalent cation, B +2 being a B-site divalent cation, and X −1 being a halide anion.

7. The perovskite layer as claimed in claim 6 , wherein the A-site monovalent cation is selected from the group consisting of formamidinium (FA + ), methylammonium (MA + ), ethylammonium (EA + ), guanidinium (GA + ), Cs + , Rb + and a combination thereof; the B-site divalent cation is selected from the group consisting of Pb 2+ , Sn 2+ , Ge 2+ and a combination thereof; and the halide anion is selected from the group consisting of I − , Br − , Cl − and a combination thereof.

8. The perovskite layer as claimed in claim 7 , wherein the mixed-halide perovskite is selected from any one of CsPb 0.5 Sn 0.5 I 3 , FAPbI 3 , MA 0.25 FA 0.75 PbI 2.2 Br 0.6 Cl 0.2 , Cs 0.02 FA 0.96 MA 0.02 PbI 0.99 Cl 0.01 , MAPb 0.92 Sn 0.08 I 3 , (FA 0.95 MA 0.05 ) 0.95 Cs 0.05 Pb(I 0.96 Br 0.04 ) 3 , Rb 0.1 FA 0.8 GA 0.1 Pb 0.6 Ge 0.4 I 3 , and (FA 0.92 MA 0.08 ) 0.9 Cs 0.1 Pb(I 0.92 Br 0.08 ) 3 , and Cs 0.2 FA 0.8 Pb(I 0.6 Br 0.4 ) 3 .

9. The perovskite layer as claimed in claim 6 , wherein the crystal grain structure of [A +1 B +2 X −1 3 ] includes grain boundaries at which the sulfonyl naphthoquinone-based compound accommodates.

10. The perovskite layer as claimed in claim 1 containing about 0.3 mol % to about 1 mol % of the sulfonyl naphthoquinone-based compound.

11. The perovskite layer as claimed in claim 1 further comprising about 3 mol % of MAPbCl 3 and 5 mol % of 4-guanidinobenzoic acid.

12. The perovskite layer as claimed in claim 1 having a thickness of about 260 nm.

13. A solar cell comprising:
a first hole transport layer;
a first electron transport layer; and
a first active layer of the perovskite layer as claimed in claim 1 that is disposed between the first hole transport layer and the first electron transport layer.

14. The solar cell as claimed in claim 13 , wherein the first active layer is in direct contact with the first hole transport layer and the first electron transport layer.

15. The solar cell as claimed in claim 14 , wherein the first hole transport layer is disposed on a transparent conductive layer that is disposed on a transparent substrate and the first electron transport layer is disposed on a first blocking layer that is disposed on a first metal layer.

16. The solar cell as claimed in claim 15 , wherein the first hole transport layer is in direct contact with a transparent conductive layer and the first electron transport layer is in direct contact with the first blocking layer.

17. The solar cell as claimed in claim 15 , wherein the transparent substrate is selected from the group consisting of glass, polymethyl methacrylate (PMMA), polycarbonate (PC), general-purpose polystyrene (GPPS), polyethylene glycol terephthalate (PET), polyethylene naphthalate (PEN), polydimethylsiloxane (PDMS), styrene-ethylene-butylene-styrene (SEBS), ethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate (PETG), acrylonitrile butadiene styrene copolymers (ABS), polypropylene (PP), polyamide (PA), acrylonitrile-styrene copolymer (AS), and a combination thereof.

18. The solar cell as claimed in 15 , wherein the transparent conductive layer is selected from the group consisting of Indium Tin Oxide (ITO), Aluminum Zinc Oxide (AZO), Fluorine Tin Oxide (FTO), graphene, poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), Ag nanowire, Cu nanowire and a combination thereof.

19. The solar cell as claimed in claim 15 , wherein first hole transport layer is selected from the group consisting of poly(triaryl amine) (PTAA), PEDOT:PSS, NiOx, 2,2′,7,7′-Tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene (Spiro-OMeTAD), DC-PA, MoO x and a combination thereof.

20. The solar cell as claimed in claim 15 , wherein the first electron transport layer is selected from the group consisting of PC 61 BM, C 60 , SnO 2 , PNDIT-F3N and a combination thereof.

21. The solar cell as claimed in claim 15 , wherein the first blocking layer is selected from the group consisting of bathocuproine (BCP), bis-C 60 , SnO x , Zr(acac) 2 , MoO x and a combination thereof.

22. The solar cell as claimed in claim 15 , wherein the first metal layer is selected from the group consisting of Ag, Cu, Au, Al, W, Fe, Pt and a combination thereof.

23. The solar cell as claimed in claim 13 comprises a band gap of about 1.81 eV.

24. The solar cell as claimed in claim 13 comprises a power conversion efficiency of about 18.98% to about 19.58%.

25. The solar cell as claimed in claim 13 comprises a power conversion efficiency of 95% of its initial value upon AM1.5G illumination for 500 hours at about 45° C.

26. The solar cell as claimed in claim 15 , further comprising a subcell disposed on and in direct contact

Assignees

• Univ City Hong Kong

Inventors

• Jen Alex Kwan Yue
• Wu Shengfan
• Yan Yichao

Classifications

• H10K85/50

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• C07C211/63

  having quaternised nitrogen atoms bound to acyclic carbon atoms · CPC title

• C07C309/44

  containing doubly-bound oxygen atoms bound to the carbon skeleton · CPC title

• H10K85/215 Primary

  comprising substituents, e.g. PCBM · CPC title

• C07C2603/24

  Anthracenes; Hydrogenated anthracenes · CPC title