Composition containing a modified hydroxyalkyl cellulose

Patent metadata

Field	Value
Publication number	US-12404477-B2
Application number	US-202017609461-A
Country	US
Kind code	B2
Filing date	Jun 10, 2020
Priority date	Jun 11, 2019
Publication date	Sep 2, 2025
Grant date	Sep 2, 2025

Abstract

Composition containing a modified hydroxyalkyl cellulose and a cationic surfactant, wherein the modified hydroxyalkyl cellulose has a cationic group and a hydrophobic group of a specific formula, each of which is bound to a group resulting from eliminating a hydrogen atom from a hydroxy group of the hydroxyalkyl cellulose; a degree of substitution of the hydroxyalkyl group in the hydroxyalkyl cellulose is 0.1 or more and 3 or less; and a content of the cationic surfactant is more than 1 part by mass and 1,500 parts by mass or less relative to 1 part by mass of the modified hydroxyalkyl cellulose.

First claim

The invention claimed is:

1. A composition, comprising:
a modified hydroxyalkyl cellulose (A); and
a cationic surfactant (B),
wherein:
the modified hydroxyalkyl cellulose (A) has a cationic group and a hydrophobic group represented by a formula (1), each of which is bound to a group resulting from eliminating a hydrogen atom from a hydroxy group of a hydroxyalkyl cellulose;
a degree of substitution of the hydroxyalkyl group in the hydroxyalkyl cellulose is 0.1 or more and 3 or less; and
a content of the cationic surfactant (B) is more than 1 part by mass and 1,500 parts by mass or less relative to 1 part by mass of the modified hydroxyalkyl cellulose (A):
*—Z—R 1   (1)

wherein:
Z represents a single bond or a hydrocarbon group having an oxygen atom;
R 1 represents a hydrocarbon group having 2 or more and 12 or less carbon atoms;
* in formula (1) represents a binding position to a group resulting from eliminating a hydrogen atom from a hydroxy group of the hydroxyalkyl cellulose;
a degree of substitution of the hydrophobic group represented by the formula (1) in the modified hydroxyalkyl cellulose (A) is 0.0001 or more and 1 or less, and
the hydrophobic group represented by the formula (1) is any hydrophobic group represented by formulae (1-1), (1-1′), (1-2), and (1-2′);

wherein:
R 11 's each independently represent an alkylene group having 2 to 4 carbon atoms;
R 1 in formulae (1-1), (1-1′), (1-2), and (1-2′) is synonymous with R 1 in the formula (1);
n1 represents an addition molar number of —R 11 —O—, and n1 is an integer of 0 or more and 30 or less: and
* in formulae (1-1), (1-1′), (1-2), and (1-2′) is synonymous with * in the formula (1).

2. The composition according to claim 1 , wherein a degree of substitution of the cationic group in the modified hydroxyalkyl cellulose (A) is 0.001 or more and 1 or less.

3. The composition according to claim 1 , wherein a degree of substitution of the hydrophobic group represented by the formula (1) in the modified hydroxyalkyl cellulose (A) is 0.015 or more and 0.05 or less.

4. The composition according to claim 1 , wherein a weight average molecular weight of the hydroxyalkyl cellulose is 1,000 or more and 3,000,000 or less.

5. The composition according to claim 1 , wherein the cationic group which the modified hydroxyalkyl cellulose (A) has comprises a quaternary ammonium cation and is represented by a formula (2-1) or a formula (2-2):

wherein:
R 21 to R 23 each independently represent a hydrocarbon group having 1 or more and 4 or less carbon atoms;
X″ represents an anion;
“t” represents an integer of 0 or more and 3 or less; and
* represents a binding position to a group resulting from eliminating a hydrogen atom from a hydroxy group of the hydroxyalkyl cellulose.

6. The composition according to claim 1 , wherein a content of the modified hydroxyalkyl cellulose (A) is 0.00001% by mass or more and 10% by mass or less.

7. The composition according to claim 1 , wherein a content of the cationic surfactant (B) is 0.001% by mass or more and 50% by mass or less.

8. The composition according to claim 1 , wherein the cationic surfactant (B) is a quaternary ammonium salt.

9. A surface treatment agent, comprising the composition according to claim 1 .

10. A finishing agent, comprising the composition according to claim 1 .

11. A surface treatment method, the method comprising:
bringing the composition according to claim 1 into contact with an article.

12. A surface treatment method of fiber product, the method comprising:
bringing the composition according to claim 1 into contact with a fiber product.

13. The composition according to claim 1 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-1).

14. The composition according to claim 1 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-1′).

15. The composition according to claim 1 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-2).

16. The composition according to claim 1 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-2′).

17. The composition according to claim 5 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-1).

18. The composition according to claim 5 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-1′).

19. The composition according to claim 5 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-2).

20. The composition according to claim 5 , wherein the hydrophobic group represented by the formula (1) is the hydrophobic group represented by formulae (1-2′).

Assignees

• Kao Corp

Inventors

• Saito Takanori
• Imori Yoichiro
• Funasaka Satoshi

Classifications

• D06M15/09

  Cellulose ethers · CPC title

• D06M13/46

  Compounds containing quaternary nitrogen atoms (hydrazinium compounds D06M13/338; betaines, sulfo-betaines D06M13/342) · CPC title

• D06L1/12

  using aqueous solvents · CPC title

• C11D1/62 Primary

  Quaternary ammonium compounds · CPC title

• C11D2111/12

  Soft surfaces, e.g. textile · CPC title