Moisture cureable polymer for flexible cables

Patent metadata

Field	Value
Publication number	US-12404392-B2
Application number	US-202017599053-A
Country	US
Kind code	B2
Filing date	Apr 29, 2020
Priority date	Apr 30, 2019
Publication date	Sep 2, 2025
Grant date	Sep 2, 2025

Abstract

The invention relates to the use of a polyethylene composition comprising one or more ethylene copolymer(s) wherein the ethylene copolymer is a terpolymer containing monomer units with polar groups and monomer units with hydrolysable silane groups, wherein the monomer units with polar groups are present in an amount of more than 5 mol. % based on the total polyethylene composition, and a silanol condensation catalyst in an amount of 0.0001 to 5 wt. %, based on the total polyethylene composition for improving the adhesion between a layer of a cable comprising the polyethylene composition and a polyurethane resin.

First claim

The invention claimed is:

1. A method, comprising:
adhering a layer of a cable comprising a polyethylene composition to a polyurethane cast resin at a cable joint;
wherein the polyethylene composition comprises:
a) one or more ethylene copolymer(s) wherein the ethylene copolymer is a terpolymer containing monomer units with polar groups and monomer units with hydrolysable silane groups, wherein the monomer units with polar groups are present in an amount of more than 5 mol. % based on the total polyethylene composition, and
b) a silanol condensation catalyst in an amount of 0.0001 to 5 wt. %, based on the total polyethylene composition
wherein the monomer units with polar groups are methyl acrylate and/or methyl methacrylate and wherein the polyurethane resin and the layer comprising the polyethylene composition adhere with an adhesion strength greater than 10 N/mm.

2. The method of claim 1 , wherein the monomer units with polar groups are present in an amount of not more than 25 mol. % based on the total polyethylene composition.

3. The method of claim 1 , wherein the monomer units with hydrolysable silane groups comprise vinyl trimethoxy silane, vinyl bismethoxyethoxy silane, vinyl gamma-(meth)acryl-oxypropyltrimethoxy silane, triethoxy silane, gamma(meth)acryloxypropyltriethoxy silane, vinyl triacetoxy silane and mixtures thereof.

4. The method of claim 1 , wherein the monomer units with hydrolysable groups are present in an amount of 0.001 wt. % to 15 wt. % based on the total polyethylene composition.

5. The method of claim 1 , wherein the silanol condensation catalyst b) comprises a sulphonic acid based catalyst or a tin based catalyst.

6. The method of claim 5 , wherein the sulphonic acid based catalyst comprises dodecyl benzene sulphonic acid, tetrapropyl benzene sulphonic acid, alkylated naphthalene sulphonic acid, arylalkyl sulphonic acid, alkylated aryl disulphonic acid or mixtures thereof.

7. The method of claim 5 , wherein the polyethylene composition further comprises c) a scorch retardant additive.

8. The method of claim 7 , wherein the scorch retardant additive c) is present in an amount of 0.0003 mole/1000 g polyethylene composition to 0.6 mole/1000 g polyethylene composition.

9. The method of claim 7 , wherein the scorch retardant additive c) comprises an alkoxy silane.

10. The method of claim 7 , wherein the polyethylene composition has an MFR2 (2.16 kg, 190° C.) of 0.1 to 50 g/10 min measured according to ISO 1133.

11. The method of claim 7 , wherein the layer is an insulation layer or a sheath layer.

12. The method of claim 7 , wherein the cable further comprises a skin layer.

13. A method for connecting electrical conductors of two cables, each cable having an insulation layer, the method comprising
1) Stripping off part of the insulation layer at the end of each cable;
2) joining the stripped end of one cable with the stripped end of the other cable by adhering the insulation layer to a polyurethane resin;
wherein the insulation layer comprises a polyethylene composition and wherein the polyethylene composition comprises:
c) one or more ethylene copolymer(s) wherein the ethylene copolymer is a terpolymer containing monomer units with polar groups and monomer units with hydrolysable silane groups, wherein the monomer units with polar groups are present in an amount of more than 5 mol. % based on the total polyethylene composition, and
d) a silanol condensation catalyst in an amount of 0.0001 to 5 wt. %, based on the total polyethylene composition
wherein the monomer units with polar groups are methyl acrylate and/or methyl methacrylate, and wherein the polyurethane resin and the insulation layer adhere with an adhesion strength greater than 10 N/mm.

Assignees

• Borealis Ag

Inventors

• Fossum Kjell
• Hellstrom Stefan
• Sultan Bernt-Ake

Classifications

• C08L23/0869

  with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters · CPC title

• H01B3/448

  from other vinyl compounds · CPC title

• C08F230/085

  the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes · CPC title

• H01B3/447

  from acrylic compounds · CPC title

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title