Method for recycling polyester fabric

Patent metadata

Field	Value
Publication number	US-12404384-B2
Application number	US-202217862369-A
Country	US
Kind code	B2
Filing date	Jul 11, 2022
Priority date	Sep 13, 2021
Publication date	Sep 2, 2025
Grant date	Sep 2, 2025

Abstract

A method for recycling a polyester fabric is provided. The method includes providing a polyester fabric that is dyed and has dye and water repellent attached thereon, providing a composite solvent containing water and acetic acid mixed with each other, performing an extraction operation including infiltrating the polyester fabric with the composite solvent and extracting the dye and the water repellent, and carrying out a liquid state polycondensation reaction on the polyester fabric so that an intrinsic viscosity of the polyester fabric is increased and residual impurities of the polyester fabric are further removed.

First claim

What is claimed is:

1. A method for recycling a polyester fabric, comprising:
providing a polyester fabric that is dyed and has dye and water repellent attached thereon;
providing a composite solvent consisting of water and acetic acid mixed with each other, wherein the composite solvent is prepared by mixing 10 to 30 parts by weight of the water with 70 to 90 parts by weight of the acetic acid;
performing an extraction operation including infiltrating the polyester fabric with the composite solvent and extracting the dye and the water repellent to remove the dye and the water repellent from a material of the polyester fabric so that the polyester fabric is restored and has an L value that is not less than 60 and a water repellent content that is not more than 500 ppm; and
carrying out a liquid state polycondensation reaction on the polyester fabric so that an intrinsic viscosity of the polyester fabric is increased and residual impurities of the polyester fabric are further removed.

2. The method according to claim 1 , wherein in the extraction operation, the intrinsic viscosity of the polyester fabric is decreased, and a magnitude of decrease thereof is not more than 10%, and wherein in the liquid state polycondensation reaction, the intrinsic viscosity of the polyester fabric is increased, and an magnitude of increase thereof is within a range from 15% to 40%.

3. The method according to claim 1 , wherein in the liquid state polycondensation reaction, the residual impurities of the polyester fabric are at least one of solid impurities and low-boiling organics.

4. The method according to claim 1 , wherein the polyester fabric has a glass transition temperature, wherein in the extraction operation, the composite solvent is heated to an extraction temperature to infiltrate the polyester fabric and extract the dye and the water repellent, and wherein the extraction temperature of the composite solvent is greater than the glass transition temperature of the polyester fabric.

5. The method according to claim 4 , wherein the glass transition temperature of the polyester fabric is not more than 80° C., and the composite solvent is heated to the extraction temperature that is within a range from 80° C. to 130° C. to infiltrate the polyester fabric and extract the dye and the water repellent.

6. The method according to claim 1 , wherein in the extraction operation, an amount of the composite solvent that is used is within a range from 8 times to 30 times that of the polyester fabric, an extraction time of the composite solvent to the polyester fabric is within a range from 0.5 hours to 3.0 hours, and a number of extractions of the composite solvent to the polyester fabric is within a range from 1 time to 6 times.

7. The method according to claim 1 , wherein in the polyester fabric, the water repellent has a polymer network cross-linked structure, and the water repellent is at least one material selected from a group consisting of a water repellent containing silicon, a water repellent containing fluorine, a water repellent containing fluorine and silicon, and a water-based polyurethane (PU) water repellent, and wherein in the extraction operation, the dye and the water repellent are removed by the acetic acid of the composite solvent.

8. The method according to claim 1 , wherein, after the extraction operation and before the liquid state polycondensation reaction, the method further comprises:
performing a filtering operation including filtering the composite solvent and the polyester fabric by using a filter so as to separate the composite solvent and the polyester fabric from each other; and
performing a drying operation including drying the polyester fabric to remove a residual composite solvent of the polyester fabric.

9. The method according to claim 1 , wherein the liquid state polycondensation reaction is carried out on the polyester fabric under a liquid polycondensation pressure that is within a range from 0.01 torrs to 1.00 torr and at a liquid polycondensation temperature that is within a range from 220° C. to 280° C., and then the polyester fabric is filtered through a filter with a filter mesh size that is not more than 5 μm, so that the residual impurities of the polyester fabric are further removed, and wherein, after the liquid state polycondensation reaction, a content of the water repellent of the polyester fabric is not more than 100 ppm.

10. The method according to claim 1 , wherein, after the liquid state polycondensation reaction, the method further comprises performing a melt granulation operation on the polyester fabric by using a melt granulator so that the polyester fabric is formed into recycled polyester pellets.

Assignees

• Nan Ya Plastics Corp

Inventors

• Liao Te-Chao
• Chuang Jung-Jen
• Huang zhang-jian
• Tseng Yu-Ti

Classifications

• D06P5/04

  with organic compounds · CPC title

• B29K2067/00

  Use of polyesters {or derivatives thereof}, as moulding material · CPC title

• D10B2331/04

  polyesters, e.g. polyethylene terephthalate [PET] · CPC title

• C08J2367/00

  Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers · CPC title

• B29B2017/0293

  Dissolving the materials in gases or liquids · CPC title