Reinforced flame retardant polycarbonate compositions with improved melt volume rates

Patent metadata

Field	Value
Publication number	US-12404368-B2
Application number	US-202017781741-A
Country	US
Kind code	B2
Filing date	Dec 15, 2020
Priority date	Dec 16, 2019
Publication date	Sep 2, 2025
Grant date	Sep 2, 2025

Abstract

A reinforced polycarbonate composition comprising 50-95 wt % of a poly(aliphatic ester-carbonate); 5-40 wt % of a high heat copolycarbonate comprising high heat carbonate units derived from 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane, N-phenyl phenolphthalein bisphenol, 4,4-(1-phenylethylidene)bisphenol, 4,4-(3,3-dimethyl-2,2-dihydro-1H-indene-1,1-diyl)diphenol, 1,1-bis(4-hydroxyphenyl)cyclododecane, 3,8-dihydroxy-5a,10b-diphenyl-coumarano-2′,3′,2,3-coumarane, or a combination thereof, preferably 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane, N-phenyl phenolphthalein bisphenol, or a combination thereof, and optionally comprising low heat carbonate units; 0.1-0.8 wt % of a C 1-16 alkyl sulfonate salt flame retardant; 0.1-0.8 wt % of an anti-drip agent; 5-35 wt % glass fibers; wherein each amount is based on the total weight of the reinforced polycarbonate composition, which sums to 100 wt %.

First claim

What is claimed is:

1. A reinforced polycarbonate composition comprising
50-95 wt % of a poly(aliphatic ester-carbonate);
5-40 wt % of a high heat copolycarbonate comprising high heat carbonate units derived from 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane, N-phenyl phenolphthalein bisphenol, 4,4′-(1-phenylethylidene)bisphenol, 4,4′-(3,3-dimethyl-2,2-dihydro-1H-indene-1,1-diyl)diphenol, 1,1-bis(4-hydroxyphenyl)cyclododecane, 3,8-dihydroxy-5a, 10b-diphenyl-coumarano-2′,3′,2,3-coumarane, or a combination thereof;
0.1-0.8 wt % of a C 1-16 alkyl sulfonate salt flame retardant;
0.1-0.8 wt % of an anti-drip agent;
5-35 wt % glass fibers;
optionally 0.1-10 wt % of an additive composition,
optionally 1-30 wt% of a polycarbonate different from the poly(aliphatic ester-carbonate), the high heat copolyca rbonate, and the poly(carbonate-siloxane), wherein the polycarbonate has a molecular weight of less than 24,000 grams per mole, as measured via gel permeation chromatography using polystyrene standards and calculated for polycarbonate; and
wherein each amount is based on the total weight of the reinforced polycarbonate composition, which sums to 100 wt %.

2. The reinforced polycarbonate composition according to claim 1 , wherein a ratio of C 1-16 alkyl sulfonate salt flame retardant to anti-drip agent is from 1:4 to 4:1.

3. The reinforced polycarbonate composition according to claim 1 , wherein the poly(aliphatic ester-carbonate) has the formula

wherein m is 4-18, preferably 4-10;
x:y is 99:1-1:99, or 13:87-2:98, or 9:91-2:98, or 8:92-13:87;
R 1 has the formula

wherein:
R a and R b are each independently a halogen, C 1-12 alkoxy, or C 1-12 alkyl,
p and q are each independently integers of 0 to 4;
X a is single bond, —O—, —S—, —S(O)—, —S(O) 2 —, —C(O)—, or a C 1-60 organic group.

4. The reinforced polycarbonate composition according to claim 3 , wherein m is 8 and R 1 is bisphenol A.

5. The reinforced polycarbonate composition according to claim 1 , wherein the poly(aliphatic ester-carbonate) is
a sebacic acid-bisphenol A copolymer having a weight average molecular weight from 18,000-25,000 grams/mole; or
a sebacic acid-bisphenol A copolymer having a weight average molecular weight from 30,000-40,000 grams/mole;
or a combination thereof,
each as measured via gel permeation chromatography using polystyrene standards and calculated for polycarbonate.

6. The reinforced polycarbonate composition of any one of claim 1 , wherein the low heat aromatic carbonate units are present and are derived from low heat aromatic group of the formula

wherein R a and R b are each independently a halogen, C 1-3 alkoxy, or C 1-3 alkyl, c is 0 to 4, and p and q are each independently integers of 0 or 1, X a is single bond, —O—, —S—, —S(O)—, —S(O) 2 —, —C(O)—, or a C 1-6 organic group.

7. The reinforced polycarbonate composition of claim 1 , wherein the C 1-16 alkyl sulfonate salt flame retardant comprises potassium perfluorobutane sulfonate, potassium perfluoroctane sulfonate, tetraethylammonium perfluorohexane sulfonate, or a combination thereof.

8. The reinforced polycarbonate composition of claim 1 ,
wherein the glass fiber is a bonding glass fiber, a non-bonding glass fiber, or a combination thereof, and wherein the glass fiber is a chopped glass fiber, a long glass fiber, a glass filament, a woven glass fiber, or a combination thereof.

9. The reinforced polycarbonate composition of claim 1 , wherein reinforced polycarbonate composition has
a gloss of at least 70 as measured according to ASTM D2457 at 60 degrees;
a bromine or chlorine content, or a combined bromine and chlorine content of less than or equal to 100 parts per million by weight, based on the total parts by weight of reinforced polycarbonate composition;
a Vicat softening temperature of at least 130° C. as measured on 4 mm ISO bars in accordance with the ISO-306 standard at a load of 50 N and a heating rate of 50°/hr;
a UL-94 flame test rating of V0 at a thickness of 1.5 millimeter;
a melt volume rate of at least 8 cubic centimeters per 10 minutes, as determined by ISO 1133;
or a combination thereof.

10. The reinforced polycarbonate composition of claim 1 , wherein the additive composition is present and comprises an impact modifier, a flow modifier, an antioxidant, a heat stabilizer, a light stabilizer, an ultraviolet light stabilizer, an ultraviolet absorbing additive, a plasticizer, a lubricant, a release agent, an antistatic agent, an anti-fog agent, an antimicrobial agent, a colorant, a surface effect additive, a radiation stabilizer, optionally, a flame retardant different from the C 1-16 alkyl sulfonate salt flame retardant, optionally, a filler different from the glass fiber, or a combination thereof.

11. The reinforced polycarbonate composition of claim 1 comprising
50-95 wt % of a sebacic acid-bisphenol A copolymer as the poly(aliphatic ester-carbonate);
5-40 wt % of a high heat copolycarbonate derived from N-phenyl phenolphthalein bisphenol and bisphenol A;
0.1-0.5 wt % of potassium perfluorobutane sulfonate as the C 1-16 alkyl sulfonate salt flame retardant;
0.1-0.5 wt % of a poly(tetrafluoroethylene) encapsulated styrene-acrylonitrile copolymer as the anti-drip agent; and
5-35 wt % of the glass fibers,
wherein
each amount is based on the total weight of the reinforced polycarbonate composition, which sums to 100 weight percent, and
a ratio of the potassium perfluorobutane sulfonate to the poly(tetrafluoroethylene) encapsulated styrene-acrylonitrile copolymer is 1:4 to 3:2.

12. An article of comprising the reinforced polycarbonate composition of claim 1 , wherein the article is an extruded article, a molded article, pultruded article, a thermoformed article, a foamed article, a layer of a multi-layer article, a substrate for a coated article, or a substrate for a metallized article.

13. The article of claim 12 , wherein the article is a housing, a frame, or an enclosure for an electronic, a medical, an automotive, or an electrical device.

14. A method for forming the article of claim 12 , comprising molding, casting, or extruding reinforced polycarbonate composition to provide the article.

15. The reinforced polycarbonate composition of claim 1 , wherein the high heat copolycarbonate comprises high heat carbonate units derived from 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane, N-phenyl phenolphthalein bisphenol, or a combination thereof, and low heat carbonate units.

16. The reinforced polycarbonate composition of claim 1 , wherein the low heat carbonate units are derived from bisphenol A.

17. The reinforced polycarbonate composition of claim 1 , wherein the C 1-16 alkyl sulfonate salt flame retardant comprises potassium perfluorobutane sulfonate.

18. The article of claim 12 , wherein the wherein the article is a molded article.

19. The article of claim 12 , wherein the wherein the article is a molded housing.

20. The article of claim 12 , wherein the article is a computer or business machine housing, a housing for a hand-held electronic device, a component of a lighting fixture or home appliance, a component of a medical application or device, or a component

Assignees

• Shpp Global Tech Bv

Inventors

• Van Der Mee Mark Adrianus Johannes
• Micciche Fabrizio
• Van De Grampel Robert Dirk

Classifications

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08J5/043

  with glass fibres · CPC title

• C08G64/08

  containing atoms other than carbon, hydrogen or oxygen · CPC title

• C08G64/02

  Aliphatic polycarbonates · CPC title

• C08G64/06

  not containing aliphatic unsaturation · CPC title