Separation of bacl2 from cacl2 brine solution
US-2025353755-A1 · Nov 20, 2025 · US
US12404181B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12404181-B2 |
| Application number | US-202017625594-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 16, 2020 |
| Priority date | Jul 17, 2019 |
| Publication date | Sep 2, 2025 |
| Grant date | Sep 2, 2025 |
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The present invention relates to a process for separating BaCl2 from a CaCl2 brine solution.
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What is claimed is: 1. A method for separating BaCl2 from a CaCl2 brine solution comprising contacting a titanium containing material with a BaCl2 containing CaCl2 brine solution, wherein the titanium containing material comprises TiO2. 2. The method of claim 1 , wherein the titanium containing material is hydrated. 3. The method of claim 1 , wherein the titanium containing material further comprises Ti(OH)4. 4. The method of claim 1 , wherein the titanium containing material comprises granules. 5. The method of claim 1 , wherein the titanium containing material comprises powder. 6. The method of claim 1 , wherein the titanium containing material and the CaCl 2 brine solution are mixed together. 7. The method of claim 1 , wherein the CaCl 2 brine solution is passed through a column packed with the titanium containing material in a granular form. 8. The method of claim 1 , wherein the CaCl 2 brine solution is maintained at a pH from about 3 to about 9. 9. The method of claim 8 , wherein the CaCl 2 brine solution is maintained at a pH from about 5.9 to about 6.9. 10. The method of claim 9 , wherein the CaCl 2 brine solution is maintained at a pH of about 6.5. 11. The method of claim 1 , wherein the CaCl 2 brine solution has a concentration between about 10 wt. % to about 30 wt. % CaCl 2 at ambient temperature, based on the total weight of the brine solution. 12. The method of claim 1 , wherein the CaCl 2 brine solution is contacted with the titanium containing material at a temperature between 10° C. and 75° C. 13. The method of claim 12 , wherein the CaCl 2 brine solution is contacted with the titanium containing material at a temperature between 20° C. and 65° C. 14. The method of claim 1 , wherein the titanium containing material has a surface area above 180 m 2 /g.
Sorbents specially adapted for preparative chromatography · CPC title
Porous sorbents (ion exchange B01J39/00 - B01J41/00) · CPC title
being in the range 100-500 m2/g · CPC title
Particle form · CPC title
comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title
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