Perovskite solar cell, preparation method therefor and power consuming device

Patent metadata

Field	Value
Publication number	US-12402467-B2
Application number	US-202318313394-A
Country	US
Kind code	B2
Filing date	May 8, 2023
Priority date	Dec 31, 2021
Publication date	Aug 26, 2025
Grant date	Aug 26, 2025

Abstract

A perovskite solar cell, a preparation method therefor and a power consuming device are provided. In some embodiments, the perovskite solar cell of the present application has, in order, a back electrode, a hole transport layer, an interface passivation layer, a perovskite layer, an interface passivation layer, an electron transport layer, and conductive glass, wherein the HOMO energy level of an interface between the perovskite layer and the interface passivation layer is 0.01-0.4 eV, and the energy band gap between the HOMO energy level and the LUMO energy level is 0.01-0.4 eV; and the interface passivation layer contains: an organic amine salt of a biphenyl compound and/or an organic amine salt of an acene compound. In the perovskite solar cell according to the present application, by passivating the perovskite layer therein with an organic amine salt of a biphenyl compound or acene compound, the VBM of the perovskite layer is improved, facilitating the extraction of holes, and the transport efficiency of carriers is improved, so that the efficiency and stability of the perovskite solar cell can be greatly improved.

First claim

The invention claimed is:

1. A perovskite solar cell, wherein,
the perovskite solar cell has, in order, a back electrode, a hole transport layer, an interface passivation layer, a perovskite layer, an electron transport layer, and conductive glass,
wherein a HOMO energy level difference at an interface between the perovskite layer and the interface passivation layer is 0.01-0.4 eV, and an energy band gap of the interface passivation layer between the HOMO energy level and a LUMO energy level is 1.356-1.689 eV; and
the interface passivation layer comprises an interface passivation material selected from: a biphenyl compound, an organic amine salt of a biphenyl compound, an acene compound, and an organic amine salt of an acene compound.

2. The perovskite solar cell according to claim 1 , wherein
The biphenyl compound or the organic amine salt of the biphenyl compound has one or more selected from biphenyl, o-terphenyl, m-terphenyl and p-terphenyl, as a parent nucleus.

3. The perovskite solar cell according to claim 1 , wherein
the acene compound or the organic amine salt of the acene compound has one or more selected from naphthalene, anthracene, phenanthrene, tetracene and pentacene, as a parent nucleus.

4. The perovskite solar cell according to claim 1 , wherein
the biphenyl compound, the organic amine salt of the biphenyl compound, the acene compound, or the organic amine salt of the acene compound further has an electron-donating group, an electron-withdrawing group, and an alkylamine group, wherein,
the electron-donating group is one or more selected from a superstrong electron-donating group, a strong electron-donating group, a medium electron-donating group, and a weak electron-donating group, wherein,
the superstrong electron-donating group is oxo,
the strong electron-donating group is dialkylamino, alkylamino, amino, hydroxyl, or alkoxy, wherein the alkyl has a carbon atom number 1-10,
the medium electron-donating group is an amide group or acyloxy, and
the weak electron-donating group is alkyl, carboxymethyl, or phenyl; and
the electron-withdrawing group is one or more selected from a strong electron-withdrawing group, a medium electron-withdrawing group, and a weak electron-withdrawing group, wherein,
the strong electron-withdrawing group is tertiary amino, nitro, or trihalomethyl,
the medium electron-withdrawing group is cyano or a sulfonic acid group, and
the weak electron-withdrawing group is acyl or carboxyl.

5. The perovskite solar cell according to claim 1 , wherein
the organic amine salt of the biphenyl compound, or the organic amine salt of the acene compound further has a cation moiety and an anionic moiety, the cation moiety is one or more selected from an alkyl acid containing at least one of O, S, P, N, F, I, Br, or Cl, a sulfonate ion, a nitrate ion, an acetate ion, a phosphate ion, a fluoride ion, an iodide ion, a bromide ion, and a chloride ion.

6. The perovskite solar cell according to claim 5 , wherein the anionic moiety is the alkyl acid containing at least one of O, S, P, N, F, I, Br or Cl, and the alkyl acid is at least one of oleic acid and alkyl sulfonic acid.

7. The perovskite solar cell according to claim 5 , wherein the anionic moiety is selected from fluoride ion, iodide ion, bromide ion, and chloride ion.

8. The perovskite solar cell according to claim 1 , wherein the interface passivation material is selected from naphthylethylamine, anthrylethylamine, and 2-methoxynaphthalene ethylamine hydroiodide.

9. The perovskite solar cell according to claim 8 , wherein the interface passivation material is naphthylethylamine.

10. The perovskite solar cell according to claim 8 , wherein the interface passivation material is 2-methoxynaphthalene ethylamine hydroiodide.

11. The perovskite solar cell according to claim 8 , wherein the interface passivation material is anthrylethylamine.

12. A power consuming device, wherein
the power consuming device has the perovskite solar cell according to claim 1 , and the perovskite solar cell is used as a power source or energy storage unit of the power consuming device.

Assignees

• Contemporary Amperex Technology Hong Kong Ltd

Inventors

• Liang Weifeng
• Sun Juanjuan
• Tu Bao
• Chen Changsong
• Guo Yongsheng
• Chen Guodong

Classifications

• H10K85/50

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• H10K85/111

  comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene · CPC title

• H10K30/82

  Transparent electrodes, e.g. indium tin oxide [ITO] electrodes · CPC title

• H10K71/40

  Thermal treatment, e.g. annealing in the presence of a solvent vapour · CPC title

• H10K2101/30

  Highest occupied molecular orbital [HOMO], lowest unoccupied molecular orbital [LUMO] or Fermi energy values · CPC title