IR-transparent sensor and camera system for motor vehicles

Patent metadata

Field	Value
Publication number	US-12399256-B2
Application number	US-201917287716-A
Country	US
Kind code	B2
Filing date	Oct 11, 2019
Priority date	Oct 23, 2018
Publication date	Aug 26, 2025
Grant date	Aug 26, 2025

Abstract

A sensor system comprises a LiDAR unit, a camera for visible light and a cover through which light arrives at the LiDAR unit and the camera. The cover comprises a layer containing dyes.
The light transmission of the cover in the range from 380 nm to 780 nm is 3% to 25% and in the range from 380 nm to 1100 nm is 40% or more. The attenuation of the LiDAR signal by the cover is such that at least 65% of the original signal intensity reaches the LiDAR detector.
The layer containing dyes contains a composition comprising i) at least 70% by weight of a transparent thermoplastic polymer, ii) at least one green and/or red dye and iii) at least one red and/or violet dye.
The product of the sum of the weight % fractions of dyes ii) and iii) and the thickness of the layer containing dyes is 0.041 to 0.12 wt % mm.
Finally, the composition contains 0% to 0.0005% by weight of IR absorbers.

First claim

The invention claimed is:

1. A sensor system comprising
a LiDAR unit having a transmitter for laser light having a wavelength of 800 nm to 1600 nm and a receiver for light having a wavelength of 800 nm to 1600 nm;
a camera for visible light having a wavelength of 380 nm to 780 nm and
a cover arranged such that IR light transmitted by the LiDAR unit and received thereby and visible light received by the camera passes through the cover, wherein the cover comprises a layer containing dyes,
wherein
the cover has a light transmission Ty in the range from 380 to 780 nm of >3% to <25% determined according to DIN ISO 13468-2:2006 (D65, 10°),
the cover has a transmission for light in the range of 380 nm to 1100 nm of >40% determined according to DIN ISO 13468-2:2006 (D65, 10°),
the cover attenuates the LiDAR signal only to the extent that the signal intensity of the IR light transmitted by the LiDAR unit and re-received thereby (determined by reflection from a smooth surface painted with TiO 2 -containing white paint at a distance of 3.2 m) is >65% of a reference intensity determined without the cover and in that
the layer containing dyes comprises a thermoplastic composition comprising the following components:
i) at least 70 wt % based on the total weight of the composition of a transparent thermoplastic polymer;
ii) at least one green and/or blue colourant;
iii) at least one red and/or violet colourant;
wherein the product of the sum of the weight percent fractions (based on the total weight of the composition) of the colourants ii) and iii) and the thickness of the layer containing dyes is >0.041 wt % mm to <0.12 wt % mm
and wherein the composition contains 0 to <0.0005 wt % based on the total weight of the composition of infrared absorbers.

2. The system as claimed in claim 1 , wherein the component ii) is selected from the group consisting of the formulae (1), (2a-c), (3), (4a), (4b), (5a), (5b), (6), (7), (8), and mixtures thereof and the component iii) is selected from the group consisting of the formulae (9), (10), (11), (12), (13), (14a), (14b), (15), and mixtures thereof:

wherein
Rc and Rd independently of one another represent a linear or branched alkyl radical or halogen, n independently of the respective Rc, Rd, Ra and Rb represents a natural number between 0 and 3

where the radicals R(5-20) independently of one another are selected from the group consisting of hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl, neopentyl, hexyl, thexyl, fluoro, chloro, bromo, sulfone, CN, and M is selected from the group consisting of aluminum, nickel, cobalt, iron, zinc, copper, and manganese,

wherein
R1 and R2 independently of one another represent a linear or branched alkyl radical or halogen,
n is a natural number between 0 and 4,

wherein R is selected from the group consisting of H and p-methylphenylamine radical,

wherein
Ra and Rb independently of one another represent a linear or branched alkyl radical or halogen, n independently of the respective Ra and Rb represents a natural number between 0 and 3,

3. The system as claimed in claim 2 , wherein the thermoplastic composition of the layer containing dyes comprises the following components:
at least 99 wt % based on the total weight of the composition of aromatic polycarbonate having a melt volume rate MVR of 15 to 20 cm 3 /(10 min) determined according to ISO 1133-1:2012-03 (300° C., 1.2 kg);
colourants of formula (2a), (2b) and/or (2c);
colourants of formula (5b) where M=Cu and R(5-20)=H;
colourants of formula (10);
wherein the sum of the colourants employed in total is ≥0.017 wt % to ≤0.057 wt % based on the total weight of the composition.

4. The system as claimed in claim 1 , wherein the thermoplastic composition of the layer containing dyes comprises a yellow and/or orange-coloured dye of formulae (16), (17), (18), (19), (20) or a mixture of at least two thereof:

5. The system as claimed in claim 1 , wherein the cover further comprises a layer of an aromatic polycarbonate which does not contain green, blue, red and/or violet colourants.

6. A vehicle comprising a system as claimed in claim 1 .

7. The system as claimed in claim 6 , wherein the topcoat layer contains an organomodified silane or a reaction product thereof.

8. The system as claimed in claim 6 , wherein an adhesion promoter layer is present between the topcoat layer and the layer containing dyes.

9. The system as claimed in claim 6 , wherein the topcoat used in the topcoat layer is a UV-curable topcoat.

10. The system as claimed in claim 6 , wherein a further layer is present on the side of the layer containing dyes that is opposite the topcoat layer.

11. The system as claimed in claim 10 , wherein the further layer is an antireflection layer, an anti-condensation layer, an anti-dust layer, a media resistance layer or a scratch resistance layer or a combination thereof.

12. The system as claimed in claim 1 , wherein in the cover the layer containing dyes has a thickness of >0.15 mm to <5 mm.

13. The system as claimed in claim 1 , wherein the cover comprises a plurality of layers containing dyes which may be identical or different.

14. The system as claimed in claim 1 , wherein the cover further comprises a layer of an aromatic polycarbonate which does not contain green, blue, red and/or violet colourants.

15. A vehicle comprising a system as claimed in claim 1 .

Assignees

• Covestro Deutschland Ag

Inventors

• Grosser Ulrich
• Meyer Alexander
• Pfingst Thomas
• Capellen Peter
• Oser Rafael
• Hagen Rainer
• Sadler Tobias
• Taravella Vincenzo
• Crotti Andrea
• Scotuzzi Stefania

Classifications

• H04N23/52

  Elements optimising image sensor operation, e.g. for electromagnetic interference [EMI] protection or temperature control by heat transfer or cooling elements · CPC title

• C08K5/3465

  condensed with carbocyclic rings · CPC title

• C08K5/3417

  condensed with carbocyclic rings · CPC title

• C08K5/18

  with aromatically bound amino groups · CPC title

• C08K5/0091

  Complexes with metal-heteroatom-bonds · CPC title