CDR reactor having multilayered catalyst layer arrangement for preventing catalyst deactivation

Patent metadata

Field	Value
Publication number	US-12397275-B2
Application number	US-201917296152-A
Country	US
Kind code	B2
Filing date	Nov 22, 2019
Priority date	Nov 23, 2018
Publication date	Aug 26, 2025
Grant date	Aug 26, 2025

Abstract

Proposed is a carbon dioxide reforming (CDR) reactor having a multilayered catalyst layer arrangement for preventing catalyst deactivation, wherein, in the reactor in which a CDR reaction for reacting methane (CH 4 ) with carbon dioxide (CO 2 ) to reform the methane into a synthesis gas including carbon monoxide (CO) and hydrogen (H 2 ) is performed, in order to prevent a case where an endothermic reaction between a catalyst and heated reactant gas supplied to the reactor gradually causes the temperature of the reactant gas to decrease and the catalyst is deactivated by cokes generated due to the decrease in temperature of the reactant gas, CDR catalysts in the reactor are arranged in multiple layers in a multilayered structure to allow the reactant gas temperature that has decreased due to the endothermic reaction to be restored in spaces between the catalyst layers.

First claim

The invention claimed is:

1. A CDR (carbon dioxide reaction) reactor, comprising:
a reactor housing including a reactant gas inlet formed at a first side thereof and allowing introduction of reactant gas including methane and carbon dioxide, an outlet formed at a second side thereof and allowing discharge of unreacted gas and reaction products, and a heating means provided in a housing wall at a position between the reactant gas inlet and the outlet and heating the reactant gas inside the reactor housing; and
a catalytic reaction part provided inside the reactor housing and having a structure in which CDR catalyst layers are arranged in multiple layers in a direction from the reactant gas inlet toward the outlet,
wherein in order to prevent a temperature of the reactant gas in the reactor from decreasing to equal to or less than 750° C., while maintaining a final conversion rate of the reactant gas based on methane in a single reactor equal to or greater than 90%, the catalytic reaction part is configured such that the CDR catalyst layers are arranged in multiple layers so as to be spaced apart from each other at a predetermined interval, and a temperature restoration section having an empty space with a length equal to the predetermined interval is formed between each of the catalyst layers, wherein in the temperature restoration section, the reactant gas having a decreased temperature due to an endothermic reaction while passing through each of the catalyst layers is reheated by the heating means,
the catalytic reaction part is configured such that, when a region in which the thicknesses of 2 catalyst layers, separated by the temperature restoration section, are equal exists, the lengths of the temperature restoration sections in that region, in the direction from the reactant gas inlet toward the outlet, are either the same or decreased, and decrease at least once,
the catalytic reaction part is configured such that, when a region in which the lengths of 2 temperature restoration sections, separated by the catalyst layer, are equal exists, the thicknesses of the CDR catalyst layers in that region, in the direction from the reactant gas inlet toward the outlet, are either the same or increased, and increase at least once,
each of the CDR catalyst layers is coated with a catalyst having a monolithic structure of ceramic material,
the CDR catalyst layers include at least first, second, third, and fourth CDR catalyst layers in sequence, with the first catalyst layer being closest to the reactant gas inlet, and
for at least the first, second, and third CDR catalyst layers, the immediately-following downstream temperature restoration section has a length that is greater than or equal to four times the thickness of the corresponding CDR catalyst layer.

2. The CDR reactor of claim 1 , wherein the catalyst comprises nickel, cobalt, ruthenium, and zirconium.

3. The CDR reactor of claim 2 , wherein arrangement of the catalytic reaction part is such that the CDR catalyst layers are arranged in multiple layers so as to be spaced apart from each other at the predetermined interval in order to prevent the temperature of the reactant gas from decreasing to equal to or less than 800° C., and the interval between each of the catalyst layers becomes the temperature restoration section where the temperature of the reactant gas is restored to an initial temperature.

4. The CDR reactor of claim 1 , wherein the catalytic reaction part is configured such that a catalyst layer with which the reactant gas firstly comes into contact is spaced apart from the reactant gas inlet to allow the reactant gas to be preheated to a reaction temperature.

5. The CDR reactor of claim 4 , wherein arrangement of the catalytic reaction part is such that the CDR catalyst layers are arranged in multiple layers so as to be spaced apart from each other at the predetermined interval in order to prevent the temperature of the reactant gas from decreasing to equal to or less than 800° C., and the interval between each of the catalyst layers becomes the temperature restoration section where the temperature of the reactant gas is restored to an initial temperature.

6. The CDR reactor of claim 1 , wherein arrangement of the catalytic reaction part is such that the CDR catalyst layers are arranged in multiple layers so as to be spaced apart from each other at the predetermined interval in order to prevent the temperature of the reactant gas from decreasing to equal to or less than 800° C., and the interval between each of the catalyst layers becomes the temperature restoration section where the temperature of the reactant gas is restored to an initial temperature.

7. The CDR reactor of claim 1 , wherein arrangement of the catalytic reaction part is such that the CDR catalyst layers are arranged in multiple layers so as to be spaced apart from each other at the predetermined interval in order to prevent the temperature of the reactant gas from decreasing to equal to or less than 800° C., and the interval between each of the catalyst layers becomes the temperature restoration section where the temperature of the reactant gas is restored to an initial temperature.

8. The CDR reactor of claim 1 , wherein:
the CDR reactor is configured such that an endothermic reaction of the reactant gas occurs therein,
a plurality of temperature restoration sections are arranged between a first CDR catalyst layer that is closest to the reactant gas inlet and a second CDR catalyst layer that is closest to the outlet,
the plurality of temperature restoration sections between the first and second CDR catalyst layers includes a first temperature restoration section and a second temperature restoration section, the first temperature restoration being closer to the reactant gas inlet than the second temperature restoration section, and
the second temperature restoration section is longer than the first temperature restoration section.

9. A carbon dioxide reforming method of methane using a multilayered catalyst layer arrangement for preventing catalyst deactivation, the carbon dioxide reforming method comprising:
supplying reactant gas into a reactor housing, the reactor including a reactant gas inlet formed at a first side thereof and allowing introduction of the reactant gas including methane and carbon dioxide, an outlet formed at a second side thereof and allowing discharge of unreacted gas.

10. The carbon dioxide reforming method of claim 9 , wherein the performing of the CDR reaction is performed in each of the CDR catalyst layers, each CDR catalyst layer comprising a catalyst having a monolithic structure including nickel, cobalt, ruthenium, and zirconium.

11. The carbon dioxide reforming method of claim 9 , wherein in the performing of the CDR reaction, the CDR catalyst layers are arranged in multiple layers so as to be spaced apart from each other at the predetermined interval in order to prevent the temperature of the reactant gas from decreasing to equal to or less than 800° C., and the interval between each of the catalyst layers becomes a temperature restoration section where the temperature of the reactant gas is restored to an initial temperature.

12. The carbon dioxide reforming method of claim 9 , wherein:
the reactor housing is configured such that an endothermic reaction of the reactant gas occurs therein,
a plurality of temperature restoration sections are arranged between a first CDR catalyst layer that is closest to the reactant gas inlet and a second CDR catalyst layer that is closest to the outlet,
the plurality of temperature restoration sections between the first and second CDR catalyst layers includes a first temperature res

Assignees

• Korea Res Inst Chemical Tech

Inventors

• Chang Tae Sun
• Heo Iljeong
• Park Jung Hyun
• Kim Beom Sik
• Park Ji Hoon
• Lee Jin Hee

Classifications

• B01J35/19

  Catalysts containing parts with different compositions · CPC title

• C01B2203/0805

  Methods of heating the process for making hydrogen or synthesis gas · CPC title

• C01B2203/0238

  the reforming step being a carbon dioxide reforming step · CPC title

• C01B3/40

  characterised by the catalyst · CPC title

• B01J23/755

  Nickel · CPC title